Abstract: Compositions comprise an urea herbicide and a N-(benzenesulfonyl) carbamate of the formula ##STR1## in which X and Y are independently selected from the group consisting of hydrogen and methyl;Z is selected from the group consisting of hydrogen, methyl, chloro, and trifluoromethyl; andR' is selected from the group consisting of 1-4 carbon alkyl, 1-4 carbon haloalkyl, 3-6 carbon alkenyl, 3-6 carbon haloalkenyl, 3-6 carbon alkynyl, cyanoethylthioethyl, 2-6 carbon alkoxyalkyl, diethylhydroxylamine, acetoxime, methylthioacetimidate, substituted phenyl, substituted benzyl, and sulfolane.

Abstract: Herbicidally active thiolcarbamates are employed in combination with certain organophosphate compounds having the formula ##STR1## in which R.sub.4 is selected from the group consisting of hydrogen and lower alkyl having from about 1 to about 6 carbon atoms;R.sub.5 is lower alkyl having from about 1 to about 6 carbon atoms;R.sub.6 is lower alkyl having from about 1 to about 6 carbon atoms;X is selected from the group consisting of oxygen or sulfur, andY is selected from the group consisting of oxygen or sulfur.In a typical application, the organophosphate compound is included in sufficient quantity to lessen the rate of soil degradation of the thiolcarbamate. As a result, the herbicidal effectiveness of the thiolcarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.

Abstract: Compositions comprise an urea herbicide and a N-(benzenesulfonyl) carbamate of the formula ##STR1## in which X and Y are independently selected from the group consisting of hydrogen and methyl;Z is selected from the group consisting of hydrogen, methyl, chloro, and trifluoromethyl; andR' is selected from the group consisting of 1-4 carbon alkyl, 1-4 carbon haloalkyl, 3-6 carbon alkenyl, 3-6 carbon haloalkenyl, 3-6 carbon alkynyl, cyanoethylthioethyl, 2-6 carbon alkoxyalkyl, diethylhydroxylamine, acetoxime, methylthioacetimidate, substituted phenyl, substituted benzyl, and sulfolane.

Abstract: Herbicide antidote compounds and herbicidal compositions consisting of an active herbicide compound and an antidote therefor and the methods of use of the antidote compound and compositions wherein the antidote compounds correspond to the formula ##STR1##

Abstract: N-(substituted benzenesulfonyl) carbamates as new compositions of matter useful as active herbicidal antidotes to protect against and decrease crop injury when used with a thiocarbamate herbicide when applied in various methods; improved herbicidal compositions and utility of said compositions to protect against and decrease phytotoxic crop injury when employing thiocarbamate herbicides and a two-part herbicide system comprising a first-part of one or more thiocarbamate herbicide and a second part of an effective antidote therefor compound said antidote compounds of the class N-benzene sulfonyl carbamates having the formula ##STR1## wherein X is hydrogen, bromo, chloro, methoxy, trifluoromethyl, and methyl; n is an integer from 1 to 3 inclusive, provided that when X is bromo, trifluoromethyl, or methoxy, n is 1; and R is selected from alkyl, haloalkyl wherein halo is chloro or fluoro, alkenyl, haloalkenyl and wherein halo is chloro, alkynyl, trifluoroacetamidomethyl, dialkylamino cyanoalkylthioalkyl, phosphon

Abstract: Herbicidally active thiolcarbamates are employed in combination with certain N-methylcarbamoyloxy benzaldehyde imines having the formula ##STR1## in which R.sup.4 is selected from the group consisting of chlorophenyl, chlorophenylthiomethylphenyl, acetoxy, and ##STR2## where R.sup.5 is selected from the group consisting of phenyl, pyridyl, and cyanomethyl, and n is zero or one.In a typical application, the imine is included in sufficient quantity to lessen the rate of soil degradation of the thiolcarbamate. As a result, the herbicidal effectiveness of the thiolcarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.

Abstract: Sulfonylurea compounds have the formula ##STR1## in which R is selected from the group consisting of 1-4 carbon alkyl, phenyl, and methyl substituted phenyl;R.sub.1 is selected from the group consisting of hydrogen and 1-4 carbon alkyl; andR.sub.2 is selected from the group consisting of mono- and polyhalosubstituted phenyl, 3-6 carbon alkynyl, and 2-6 carbon alkoxyalkyl.

Abstract: N-(substituted and unsubstituted benzenesulfonyl) thiocarbamates as new compositions of matter useful as active herbicidal antidotes to protect various crops from injury when used with a thiocarbamate herbicide; improved herbicidal compositions and utility of said compositions employing N-benzenesulfonyl thiocarbamates having the formula ##STR1## wherein X is hydrogen, methyl, chloro, bromo, or methoxy; n is an interger 1 to 3, inclusive; R.sub.1 is hydrogen or methyl; and R.sub.2 is alkyl having from 1 to 4 carbon atoms, inclusive, methylthio-p-chlorobenzenesulfonyl carbamate, benzyl or 4-chlorophenyl; provided that when X is hydrogen and R.sub.1 is methyl, the R.sub.2 is other than ethyl.

Abstract: Soybeans are protected against injury from a herbicidal mixture comprising a thiocarbamate and a triazine by use of certain N-benzenesulfonyl carbamates as herbicide antidotes. The N-benzenesulfonyl carbamates have the general structural formula ##STR1## wherein each of X.sub.1, X.sub.2, X.sub.3, X.sub.4 and X.sub.5 is independently selected from the group consisting of hydrogen, halogen and lower alkyl, with the proviso that when X.sub.3 is lower alkyl, X.sub.1 and X.sub.5 are not both hydrogen; and R is selected from the group consisting of lower alkyl, alkenyl, alkynyl and alkyl and alkenyl radicals substituted with up to five halo atoms.

Abstract: N-(substituted and unsubstituted benzenesulfonyl) thiocarbamates as new compositions of matter useful as active herbicidal antidotes to protect various crops from injury when used with a thiocarbamate herbicide; improved herbicidal compositions and utility of said compositions employing N-benzenesulfonyl thiocarbamates having the formula ##STR1## wherein X is hydrogen, methyl, chloro, bromo, or methoxy; n is an integer 1 to 3, inclusive; R.sub.1 is hydrogen or methyl; and R.sub.2 is alkyl having from 1 to 4 carbon atoms, inclusive, methylthio-p-chlorobenzenesulfonyl carbamate, benzyl or 4-chlorophenyl; provided that when X is hydrogen and R.sub.1 is methyl, the R.sub.2 is other than ethyl.

Abstract: N-(Substituted benzenesulfonyl) carbamates as new compositions of matter useful as active herbicidal antidotes to protect against and decrease crop injury when used with a thiocarbamate herbicide when applied in various methods; improved herbicidal compositions and utility of said compositions to protect against and decrease phytotoxic crop injury when employing thiocarbamate herbicides and a two-part herbicide system comprising a first-part of one or more thiocarbamate herbicide and a second part of an effective antidote therefor compound said antidote compounds of the class N-benzene sulfonyl carbamates having the formula ##STR1## wherein X is hydrogen, bromo, chloro, methoxy, trifluoromethyl, and methyl; n is an integer from 1 to 3 inclusive, provided that when X is bromo, trifluoromethyl, or methoxy, n is 1; and R is selected from alkyl, haloalkyl wherein halo is chloro or fluoro, alkenyl, haloalkenyl and wherein halo is chloro, alkynyl, trifluoroacetamidomethyl, dialkylamino cyanoalkylthioalkyl, phosphon

Abstract: Sulfonylurea compounds have the formula ##STR1## in which R is selected from the group consisting of 1-4 carbon alkyl, phenyl, and methyl substituted phenyl;R.sub.1 is selected from the group consisting of hydrogen and 1-4 carbon alkyl; andR.sub.2 is selected from the group consisting of mono- and polyhalosubstituted phenyl, 3-6 carbon alkynyl, and 2-6 carbon alkoxyalkyl.

Abstract: Certain 1-(3,5-dichlorobenzoyl)-3-phenylpyrazolines which have the structural formula ##STR1## where R is hydrogen, alkyl, alkoxy or halo and their uses as a mildewicide.

Abstract: N-(substituted benzenesulfonyl) carbamates as new compositions of matter useful as active herbicidal antidotes to protect against and decrease crop injury when used with a thiocarbamate herbicide when applied in various methods; improved herbicidal compositions and utility of said compositions to protect against and decrease phytotoxic crop injury when employing thiocarbamate herbicides and a two-part herbicide system comprising a first-part of one or more thiocarbamate herbicide and a second part of an effective antidote therefor compound said antidote compounds of the class N-benzene sulfonyl carbamates having the formula ##STR1## wherein X is hydrogen, bromo, chloro, methoxy, trifluoromethyl, and methyl; n is an integer from 1 to 3 inclusive, provided that when X is bromo, trifluoromethyl, or methoxy, n is 1; and R is selected from alkyl, haloalkyl wherein halo is chloro or fluoro, alkenyl, haloalkenyl and wherein halo is chloro, alkynyl, trifluoroacetamidomethyl, dialkylamino cyanoalkylthioalkyl, phosphon

Abstract: This invention relates to herbicidal active compounds and their use. The compounds of this invention correspond to the formula: ##STR1## wherein R is selected from cyclopropyl, ethyl, furyl, benzyl, methyl, and 3,4-methylenedioxy-benzyl; R.sub.1 is selected from chloro and trifluoromethyl; R.sub.2 is selected from hydrogen, 4-chloro, 4-propargyloxy, and 5-chloro; R.sub.3 is selected from ethyl, chloroethyl, isobutyl, allyl and propargyl.

Abstract: Crops are protected against injury from triazine herbicides by application of certain N-benzenesulfonyl carbamates as herbicide antidotes. The N-benzenesulfonyl carbamates have the general structural formula ##STR1## wherein each of X.sub.1, X.sub.2, X.sub.3, X.sub.4, and X.sub.5 is independently selected from the group consisting of hydrogen, halogen and lower alkyl, with the proviso that when X.sub.3 is lower alkyl, X.sub.1 and X.sub.5 are not both hydrogen; and R is selected from the group consisting of lower alkyl, alkenyl, alkynyl and alkyl and alkenyl radicals substituted with up to five halo atoms.

Abstract: This invention relates to herbicidal active compounds and their use. The compounds of this invention correspond to the formula: ##STR1## wherein R is selected from cyclopropyl, ethyl, furyl, benzyl, methyl, and 3,4-methylenedioxybenzyl; R.sub.1 is selected from chloro and trifluoromethyl; R.sub.2 is selected from hydrogen, 4-chloro, 4-propargyloxy, and 5-chloro; R.sub.3 is selected from ethyl, chloroethyl, isobutyl, allyl and propargyl.

Abstract: This invention relates to herbicidal active compounds and their use. The compounds of this invention correspond to the formula: ##STR1## wherein R is selected from cyclopropyl, ethyl, furyl, benzyl, methyl, and 3,4-methylenedioxybenzyl; R.sub.1 is selected from chloro and trifluoromethyl; R.sub.2 is selected from hydrogen, 4-chloro, 4-propargyloxy, and 5-chloro; R.sub.3 is selected from ethyl, chloroethyl, isobutyl, allyl and propargyl.

Abstract: Substituted sulfoxide and sulfone thiazolidine as new compositions and their utility in herbicidal compositions comprising an active herbicidal compound and an antidote therefor and the methods of use; the new compounds and antidote compounds correspond to compounds having the formula ##STR1## in which R is haloalkyl, alkyl, alkylthio; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently selected from the group consisting of hydrogen, lower alkyl, alkoxyalkyl, and lower alkylol; and n is an integer having the value 1 or 2.

Abstract: Novel herbicidal compounds have the general formula ##STR1## wherein each of R, R.sub.1 and R.sub.2 is a lower alkyl radical.