Abstract: The present disclosure relates to a method of making polyurethane foam, the method comprising providing a polyol mixture comprising polyether polyol and unmodified vegetable oil having a hydroxyl number of less than 10; and reacting isocyanate with the polyol mixture to form a polyurethane foam, wherein the unmodified vegetable oil does not react and does not form part of the polyurethane foam. The present disclosure also relates to polyurethane formed by the method and polyurethane compositions.

Abstract: The present disclosure relates to a method of making polyurethane foam, the method comprising providing a polyol mixture comprising polyether polyol and unmodified vegetable oil having a hydroxyl number of less than 10; and reacting isocyanate with the polyol mixture to form a polyurethane foam, wherein the unmodified vegetable oil does not react and does not form part of the polyurethane foam. The present disclosure also relates to polyurethane formed by the method and polyurethane compositions.

Abstract: The present disclosure relates to a method of making polyurethane foam, the method comprising providing a polyol mixture comprising polyether polyol and unmodified vegetable oil having a hydroxyl number of less than 10; and reacting isocyanate with the polyol mixture to form a polyurethane foam, wherein the unmodified vegetable oil does not react and does not form part of the polyurethane foam. The present disclosure also relates to polyurethane formed by the method and polyurethane compositions.

Abstract: The present disclosure relates to a method of making polyurethane foam, the method comprising providing a polyol mixture comprising polyether polyol and unmodified vegetable oil having a hydroxyl number of less than 10; and reacting isocyanate with the polyol mixture to form a polyurethane foam, wherein the unmodified vegetable oil does not react and does not form part of the polyurethane foam. The present disclosure also relates to polyurethane formed by the method and polyurethane compositions.

Abstract: A method of making a hydroxyl terminated precursor for polyurethane is disclosed. The method comprises heating a vegetable oil-polyol mixture of modified vegetable oil containing about two or more hydroxyl groups per molecule and a polyether polyol having about two or more hydroxyl groups per molecule at a temperature of at least about 25 degrees Celsius and at a pressure of about 1 atmosphere. The mixture has a hydroxyl equivalent ratio of about 1:1 vegetable oil to polyol. The method further comprises mixing for at least about 10 minutes an isocyanate containing about two or more isocyanato groups per molecule at least about 25 degrees Celsius to the vegetable oil-polyol mixture at a molar equivalent ratio of at least 2:1 vegetable oil-polyol mixture to isocyanate to react the isocyanate with the mixture to form the hydroxyl terminated precursor.

Abstract: A method of making an isocyanato terminated precursor for polyurethane is disclosed. The method comprises heating an isocyanate containing about two or more isocyanato groups per molecule at a temperature of up to 80 degrees Celsius and at a pressure of about 1 atmosphere. The method further comprises mixing a modified vegetable oil comprising about two or more hydroxyl groups per molecule with the isocyanate at a molar equivalent ratio of at least 2:1 isocyanate to vegetable oil for a predetermined time period to form the isocyanato terminated precursor.

Abstract: A method of making an isocyanato terminated precursor for polyurethane is disclosed. The method comprises heating an isocyanate containing about two or more isocyanato groups per molecule at a temperature of up to 80 degrees Celsius and at a pressure of about 1 atmosphere. The method further comprises mixing a modified vegetable oil comprising about two or more hydroxyl groups per molecule with the isocyanate at a molar equivalent ratio of at least 2:1 isocyanate to vegetable oil for a predetermined time period to form the isocyanato terminated precursor.

Abstract: A method of making a hydroxyl terminated precursor for polyurethane is disclosed. The method comprises heating a vegetable oil-polyol mixture of modified vegetable oil containing about two or more hydroxyl groups per molecule and a polyether polyol having about two or more hydroxyl groups per molecule at a temperature of at least about 25 degrees Celsius and at a pressure of about 1 atmosphere. The mixture has a hydroxyl equivalent ratio of about 1:1 vegetable oil to polyol. The method further comprises mixing for at least about 10 minutes an isocyanate containing about two or more isocyanato groups per molecule at least about 25 degrees Celsius to the vegetable oil-polyol mixture at a molar equivalent ratio of at least 2:1 vegetable oil-polyol mixture to isocyanate to react the isocyanate with the mixture to form the hydroxyl terminated precursor.

Abstract: A polyurethane sealant is the reaction product of a hydroxy-terminated toluenediisocyanate/polyoxyalkylene polyol prepolymer component, an isocyanate-terminated toluenediisocyanate/polyoxyalkylene polyol activator component, and at least one of a diphenylmethane diisocyanate prepolymer component and a diphenylmethane diisocyanate monomer component. A method for making a sealant including providing a base component containing a hydroxy-terminated toluenediisocyanate/polyoxyalkylene polyol prepolymer, an activator component containing an isocyanate-terminated toluenediisocyanate/polyoxyalkylene polyol, and a modifier component containing at least one of a diphenylmethane diisocyanate prepolymer and a diphenylmethane diisocyanate monomer, and combining the base component, activator component, and modifier component to form a polyurethane reaction product.

Abstract: This invention relates to molded articles comprising micro cellular polyurethane foams, preferably integral skin foams. These exhibit improved properties and are particularly suitable for soling systems in footwear. The present invention also relates to a process for the production of these molded articles. These molded articles comprise the reaction product of (A) an isocyanate comprising a stable, liquid MDI based prepolymer containing an allophanate-modified MDI, with (B) an isocyanate reactive component, in the presence of (C) at least one blowing agent.

Abstract: Allophanate-modified MDI which is a storage stable liquid at 25.degree. C. is produced by reacting a monoisocyanate and an organic material having at least two hydroxyl groups and a molecular weight of from about 60 to about 6,000 to form a urethane. The urethane is then reacted with and isomeric mixture of MDI in an amount such that the product isocyanate will have an NCO content of from about 12 to about 30%. The isomeric mixture of MDI is composed of 4,4'-diphenylmethane diisocyanate containing from 0 to about 60% by weight 2,4'-MDI and less than 6% by weight of the 2,2'-MDI. This allophanate-modified MDI is further reacted with an organic isocyanate-reactive material to produce an allophanate-modified MDI prepolymer containing urethane, urea and/or biuret groups having an NCO content which is generally from about 5 to about 29% by weight. The prepolymers of this invention are particularly useful in reaction injection molding processes because they give molded articles having improved flex modulus.

Abstract: The present invention is directed to an integral skin foam prepared by reacting an isocyanate, an isocyanate reactive component and water as the only blowing agent and to a catalyst useful therein. The catalyst broadly comprises a diorganotin sulfide, a tertiary amine and a tin compound other than a diorganotin sulfide.

Abstract: Disclosed herein are compositions comprising an effective combination of an amine terminated polyether and a urea compound, and melamine/polyol blends containing the same.

Abstract: The present invention relates to a stabilized composition containing a polyol/melamine and an effective stabilizing amount of an amine terminated polyether.

Abstract: The present invention relates to a stabilized composition containing a polyol/melamine and an effective stabilizing amount of an amine terminated polyether.

Abstract: Polyurethane foams of excellent properties are produced by reacting a) one or more polyether polyols, b) a polymethylene poly(phenyl isocyanate) having a methylene-bis(phenyl isocyanate) content of from 70 to 77% by weight, c) melamine, d) a phosphorous containing compound and d) water as the blowing agent. The isocyanate must have a specific 4,4' to 2,4'-isomer ratio and the amounts of melamine and phosphorous must be within narrowly defined limits.