Abstract: A method for marking a printed object is disclosed. For example, the method includes printing a three-dimensional (3D) object via a fused filament fabrication (FFF) printer, receiving a desired color marking to be marked on a surface of the 3D object, and controlling a point energy source to emit energy on a thermal treatment layer of the 3D object in accordance with the desired color marking.

Abstract: The present teachings include powder coating including a plurality of core/shell particles. Each particle of plurality of core/shell particles has a size of from about 3 microns to about 100 microns. Each particle of the plurality of core/shell particles has a core including a cross-linkable crystalline polyester resin having a melting temperature of less than about 150° C. Each particle of the plurality of core/shell particles has a shell including a cross-linkable amorphous polyester resin having a glass transition temperature greater than 40° C. Each particle of the plurality of core/shell particles includes a thermal initiator.

Abstract: A method for printing a flexible printed battery is disclosed. For example, the method includes printing, via a three-dimensional (3D) printer, a first substrate of the flexible thin-film printed battery, printing a first current collector on the first substrate, printing a first layer on the first current collector, printing, via the 3D printer, a second substrate, printing a second current collector on the second substrate, printing a second layer on the second current collector, and coupling the first substrate and the second substrate around a paper separator membrane moistened with an electrolyte that is in contact with the first layer and the second layer.

Abstract: A method for printing a flexible printed battery is disclosed. For example, the method includes printing, via a three-dimensional (3D) printer, a first substrate of the flexible thin-film printed battery, printing a first current collector on the first substrate, printing a first layer on the first current collector, printing, via the 3D printer, a second substrate, printing a second current collector on the second substrate, printing a second layer on the second current collector, and coupling the first substrate and the second substrate around a paper separator membrane moistened with an electrolyte that is in contact with the first layer and the second layer.

Abstract: A toner process including a) mixing reagents comprising at least one amorphous resin, an optional crystalline resin, an optional styrene, acrylate or styrene/acrylate, an optional wax, and an optional colorant to form an emulsion comprising a resin particle; b) adding at least one aggregating agent and aggregating said resin particle to form a nascent toner particle; c) optionally, adding one or more resins to form a shell on said nascent toner particle to yield a core-shell particle; d) adding a first chelating agent and a second chelating agent; wherein said first chelating agent and said second chelating agent are different; e) freezing particle growth to form an aggregated toner particle; f) coalescing said aggregated toner particle to form a toner particle; and g) optionally, collecting said toner particle.

Abstract: A method for printing a flexible printed battery is disclosed. For example, the method includes printing, via a three-dimensional (3D) printer, a first substrate of the flexible thin-film printed battery, printing a first current collector on the first substrate, printing a first layer on the first current collector, printing, via the 3D printer, a second substrate, printing a second current collector on the second substrate, printing a second layer on the second current collector, and coupling the first substrate and the second substrate around a paper separator membrane moistened with an electrolyte that is in contact with the first layer and the second layer.

Abstract: Melt emulsification may be employed to form elastomeric particulates in a narrow size range when nanoparticles and a sulfonate surfactant are included as emulsion stabilizers. Such processes may comprise combining a polyurethane polymer, a sulfonate surfactant, and nanoparticles with a carrier fluid at a heating temperature at or above a melting point or softening temperature of the polyurethane polymer, applying sufficient shear to disperse the polyurethane polymer as liquefied droplets in the presence of the nanoparticles in the carrier fluid at the heating temperature, cooling the carrier fluid at least until elastomeric particulates in a solidified state form, and separating the elastomeric particulates from the carrier fluid. The polyurethane polymer defines a core and an outer surface of the elastomeric particulates, and the nanoparticles are associated with the outer surface. The elastomeric particulates may have a span of about 0.9 or less.

Abstract: Melt emulsification may be employed to form elastomeric particulates in a narrow size range when nanoparticles are included as an emulsion stabilizer. Such processes may comprise combining a polyurethane polymer and nanoparticles with a carrier fluid at a heating temperature at or above a melting point or a softening temperature of the polyurethane polymer, applying sufficient shear to disperse the polyurethane polymer as liquefied droplets in the presence of the nanoparticles in the carrier fluid at the heating temperature, cooling the carrier fluid at least until elastomeric particulates in a solidified state form, and separating the elastomeric particulates from the carrier fluid. In the elastomeric particulates, the polyurethane polymer defines a core and an outer surface of the elastomeric particulates and the nanoparticles are associated with the outer surface. The elastomeric particulates may have a D50 of about 1 ?m to about 1,000 ?m.

Abstract: A method for printing a flexible printed battery is disclosed. For example, the method includes printing, via a three-dimensional (3D) printer, a first substrate of the flexible thin-film printed battery, printing a first current collector on the first substrate, printing a first layer on the first current collector, printing, via the 3D printer, a second substrate, printing a second current collector on the second substrate, printing a second layer on the second current collector, and coupling the first substrate and the second substrate around a paper separator membrane moistened with an electrolyte that is in contact with the first layer and the second layer.

Abstract: A method for producing polysulfone micro-particles for 3D printing disclosed. For example, the method includes creating a mixture of polysulfone by dissolving polysulfone in an organic solvent, creating an aqueous solution of a polymeric stabilizer or a surfactant, adding the mixture of polysulfone to the aqueous solution to create a polysulfone solution, and processing the polysulfone solution to obtain polysulfone micro-particles having a desired particle size, a desired particle size distribution, and a desired shape.

Abstract: Described herein is a method for manufacturing a low gloss toner. The method includes mixing a resin, a colorant and an optional wax in water to form an emulsion. The emulsion is heated in the presence of a polyion coagulant to form a plurality of aggregated particles, wherein the heating is to a temperature of below the glass transition temperature of the resin. Trisodium citrate dihydrate is added to the heated emulsion in amount of from 0.4 weight percent to about 1.0 percent by weight based on of a total weight of reagents while stirring, wherein the trisodium citrate dihydrate. The aggregated particles are heated to a temperature above the glass transition temperature of the resin to form toner particles have a volume average particle diameter of from 4.3 microns to 4.9 microns.

Abstract: A toner composition includes toner particles made from a resin and gadolinium oxysulfide (GOS) particles. A method of making a toner composition including toner particles made from a resin and gadolinium oxysulfide (GOS) particles disposed on the surface of the toner particles, the method including blending toner particles with a surface additive package comprising the GOS particles. A method of making a toner composition including toner particles made from a resin and gadolinium oxysulfide (GOS) particles disposed throughout the toner particles, the method including adding GOS particles during toner particle manufacture.

Abstract: A toner process including a) mixing reagents comprising at least one amorphous resin, an optional crystalline resin, an optional styrene, acrylate or styrene/acrylate, an optional wax, and an optional colorant to form an emulsion comprising a resin particle; b) adding at least one aggregating agent and aggregating said resin particle to form a nascent toner particle; c) optionally, adding one or more resins to form a shell on said nascent toner particle to yield a core-shell particle; d) adding a first chelating agent and a second chelating agent; wherein said first chelating agent and said second chelating agent are different; e) freezing particle growth to form an aggregated toner particle; f) coalescing said aggregated toner particle to form a toner particle; and g) optionally, collecting said toner particle.

Abstract: A composition for use in 3D printing includes an unsaturated polyester resin including an ethylenically unsaturated monomer, a first diol monomer and a second diol monomer.

Abstract: Methods of using a toner as a printable adhesive are provided. In embodiments, a method of adhering substrates is provided which comprises disposing a cold pressure fix toner comprising a phase change material on a first substrate via xerography to form an unfused layer of the cold pressure fix toner on the first substrate; placing a second substrate on the unfused layer of the cold pressure fix toner; and subjecting the cold pressure fix toner to a pressure to form a bonded article comprising the first substrate, an adhesive layer formed from the cold pressure fix toner, and the second substrate. Methods of applying an adhesive to a substrate and bonded articles are also provided.

Abstract: A process for producing unsaturated polyester microparticles comprising: melt-mixing an unsaturated polyester and an oil in an extruder; washing the microparticles with an organic solvent to reduce the amount of oil; and removing the organic solvent to form the microparticles.

Abstract: A process including combining polystyrene and a first solvent to form a polystyrene solution; heating the polystyrene solution; adding a second solvent to the polystyrene solution with optional stirring whereby polystyrene microparticles are formed via microprecipitation; optionally, cooling the formed polystyrene microparticles in solution; and optionally, removing the first solvent and second solvent. A polystyrene microparticle formed by a microprecipitation process, wherein the polystyrene particle has a spherical morphology, a particle diameter of greater than about 10 micrometers, and a weight average molecular weight of from about 38,000 to about 200,000 Daltons. A method of selective laser sintering including providing polystyrene microparticles formed by a microprecipitation process; and exposing the microparticles to a laser to fuse the microparticles.

Abstract: Provided herein is a powder composition comprising a silica-infused crystalline polyester particle for laser sintering comprising at least one crystalline polyester resin and silica nanoparticles present in the particle an amount ranging from about 10 wt % to about 60 wt % relative to the total weight of the particle. Further provided herein are methods of preparing silica-infused crystalline polyester particles.

Abstract: The present disclosure provides toners and toner processes. In embodiments, a toner is provided which comprises a first resin having a weight average molecular weight of no more than about 28,000 and an onset second heat Tg of no more than about 50° C.; a second resin having a weight average molecular weight greater than that of the first resin; and a paraffin wax having a melting point in the range of from about 65° C. to about 95° C.

Abstract: A toner composition including an amorphous polyester resin; a crystalline polyester resin; a styrene acrylate copolymer; an optional wax; and an optional colorant; wherein the amorphous polyester resin comprises a rosin monomer content of from about 10 to about 25 percent rosin monomer based upon the total amount of monomer comprising the amorphous polyester resin. A toner composition including a core and at least one shell disposed thereover. A toner process including contacting an amorphous polyester resin; a crystalline polyester resin; a styrene acrylate copolymer; an optional wax; an optional colorant; and an optional aggregating agent; wherein the amorphous polyester resin comprises a rosin monomer content of from about 10 to about 25 percent rosin monomer heating to form aggregated toner particles; optionally, adding a shell resin to the aggregated toner particles, heating to coalesce the particles; and recovering the toner particles.