Patents by Inventor Edward John Blok

Edward John Blok has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9540510
    Abstract: A stabilized, dynamically vulcanized thermoplastic elastomer composition comprising dispersed dynamically vulcanized particles of at least one first elastomer or rubber comprising halogenated isobutylene-containing elastomer and dispersed particles of at least one second elastomer or rubber comprising at least one functional group capable of reacting with and grafting to a polyamide, the particles of the at least one first and at least one second elastomers dispersed in a continuous thermoplastic polyamide or nylon resin matrix comprising at least one nylon homopolymer, nylon copolymer or mixture thereof, the composition or the at least one first elastomer further comprising at least one stabilizer against degradation induced by exposure to actinic, particularly ultraviolet, radiation.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: January 10, 2017
    Assignees: The Yokohama Rubber Co., Ltd, ExxonMobil Chemical Patents Inc.
    Inventors: Edward John Blok, Bruce Alan Harrington, Yuichi Hara, Shusaku Tomoi
  • Publication number: 20150225561
    Abstract: Disclosed herein is a thermoplastic elastomer composition having improved uv and processability, comprising a post-vulcanized dynamically vulcanized alloy (DVA) and a low molecular weight aromatic amine stabilizer, wherein the DVA comprises an isobutylene elastomeric component dispersed as a domain in a continuous phase comprising at least one thermoplastic resin. A method to produce the thermoplastic elastomer composition is also disclosed.
    Type: Application
    Filed: June 19, 2012
    Publication date: August 13, 2015
    Applicants: The Yokohama Rubber Co., Ltd., Exxonmobil Chemical Patents Inc.
    Inventors: Yuichi Hara, Shun Sato, Edward John Blok, Maria D. Ellul, Anthony J. Dias, Randal Howard Kerstetter, III
  • Publication number: 20120041108
    Abstract: A stabilized, dynamically vulcanized thermoplastic elastomer composition comprising dispersed dynamically vulcanized particles of at least one first elastomer or rubber comprising halogenated isobutylene-containing elastomer and dispersed particles of at least one second elastomer or rubber comprising at least one functional group capable of reacting with and grafting to a polyamide, the particles of the at least one first and at least one second elastomers dispersed in a continuous thermoplastic polyamide or nylon resin matrix comprising at least one nylon homopolymer, nylon copolymer or mixture thereof, the composition or the at least one first elastomer further comprising at least one stabilizer against degradation induced by exposure to actinic, particularly ultraviolet, radiation.
    Type: Application
    Filed: December 17, 2008
    Publication date: February 16, 2012
    Applicant: The Yokohama Rubber Co., Ltd.
    Inventors: Edward John Blok, Bruce Alan Harrington, Yuichi Hara, Shusaku Tomoi
  • Patent number: 7994253
    Abstract: A composition is described in one aspect as comprising one or more propylene-?-olefin terpolymers; wherein the propylene-?-olefin terpolymer(s) possess a melting temperature (Tm) within the range of from less than 105° C., and a heat of fusion (Hf) within the range of from less than 75 J/g; one or more polyolefin(s); and oil; wherein fillers are present, if at all, at a level that maintains a Haze value of 65% or less for the composition. The terpolymer in one embodiment is a polymer comprising at least 65 wt %, by weight of the terpolymer, of propylene-derived units, within the range of from 5 to 35 wt % of ethylene or other ?-olefin and a diene such as ethylidiene norbornene, and in certain embodiments having a Mooney Viscosity (ML(1+4)@125° C.) within the range of from 10 to 50 (ASTM D1646). The compositions can be cured to form transparent or translucent articles such as sheets that are also flexible.
    Type: Grant
    Filed: April 15, 2008
    Date of Patent: August 9, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sunny Jacob, Gary K. Lawrence, Edward John Blok, Ralph E. Raulie
  • Publication number: 20090258209
    Abstract: A composition is described in one aspect as comprising one or more propylene-?-olefin terpolymers; wherein the propylene-?-olefin terpolymer(s) possess a melting temperature (Tm) within the range of from less than 105° C., and a heat of fusion (Hf) within the range of from less than 75 J/g; one or more polyolefin(s); and oil; wherein fillers are present, if at all, at a level that maintains a Haze value of 65% or less for the composition. The terpolymer in one embodiment is a polymer comprising at least 65 wt %, by weight of the terpolymer, of propylene-derived units, within the range of from 5 to 35 wt % of ethylene or other ?-olefin and a diene such as ethylidiene norbornene, and in certain embodiments having a Mooney Viscosity (ML(1+4)@125° C.) within the range of from 10 to 50 (ASTM D1646). The compositions can be cured to form transparent or translucent articles such as sheets that are also flexible.
    Type: Application
    Filed: April 15, 2008
    Publication date: October 15, 2009
    Inventors: Sunny Jacob, Gary K. Lawrence, Edward John Blok, Ralph E. Raulie
  • Patent number: 6988523
    Abstract: This invention discloses a pneumatic tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (a) about 60 phr to about 90 phr of a cis-1,4-polybutadiene rubber, wherein the cis-1,4-polybutadiene rubber has a glass transition temperature which is within the range of about ?104° C. to about ?80° C., (b) about 10 phr to about 40 phr of at least one additional rubbery polymer selected from the group consisting of polyisoprene rubber, polybutadiene rubber, isoprene-butadiene rubber, and styrene-isoprene-butadiene rubber, wherein the additional rubbery polymer has a glass transition temperature which is within the range of about ?30° C. to about ?10° C.
    Type: Grant
    Filed: October 8, 2003
    Date of Patent: January 24, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, David John Zanzig, John Joseph Andre Verthe
  • Publication number: 20040069388
    Abstract: This invention discloses a pneumatic tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (a) about 60 phr to about 90 phr of a cis-1,4-polybutadiene rubber, wherein the cis-1,4-polybutadiene rubber has a glass transition temperature which is within the range of about −104° C. to about −80° C., (b) about 10 phr to about 40 phr of at least one additional rubbery polymer selected from the group consisting of polyisoprene rubber, polybutadiene rubber, isoprene-butadiene rubber, and styrene-isoprene-butadiene rubber, wherein the additional rubbery polymer has a glass transition temperature which is within the range of about −30° C. to about −10° C.
    Type: Application
    Filed: October 8, 2003
    Publication date: April 15, 2004
    Applicant: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, David John Zanzig, John Joseph Andre Verthe
  • Patent number: 6670416
    Abstract: In tire tread formulations, blends of rubbers having low and high glass transition temperatures have significant advantages over blends made with rubbers having intermediate glass transition temperatures. However, blends of rubbers having low and high glass transition temperatures exhibit poor processability. This invention deals with improving the processability of tire tread formulations which are made by blending rubbers having both low and high glass transition temperatures that offer ultra low rolling resistance without sacrificing rolling resistance or tread wear characteristics. This invention more specifically discloses a tire tread rubber composition which is comprised of (a) about 60 phr to about 90 phr of a high cis-1,4-polybutadiene rubber, wherein the high cis-1,4-polybutadiene rubber has a glass transition temperature which is within the range of about −104° C. to about −80° C.
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: December 30, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, David John Zanzig, John Joseph Andre Verthe
  • Patent number: 6581659
    Abstract: This invention relates to a tire having a tread of a cap/base construction wherein the tread cap is composed of trans 1,4-polybutadiene, solution polymerization prepared styrene/butadiene copolymer rubber, cis 1,4-polyisoprene rubber and defined amounts of carbon black and amorphous silica reinforcement.
    Type: Grant
    Filed: October 11, 1999
    Date of Patent: June 24, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: David John Zanzig, Paul Harry Sandstrom, John Joseph Andre Verthe, Edward John Blok, Gregory Martin Holtzapple
  • Patent number: 6562895
    Abstract: The subject invention discloses a liquid isoprene-butadiene rubber (IBR) which is particularly valuable for use in making treads for high performance automobile tires, including race tires, that exhibit superior dry traction characteristics and durability. The isoprene-butadiene rubber of this invention is a liquid at room temperature and is comprised of repeat units which are derived from about 5 weight percent to about 95 weight percent isoprene and from about 5 weight percent to about 95 weight percent 1,3-butadiene, wherein the repeat units derived from isoprene and 1,3-butadiene are in essentially random order. The IBR of this invention also has a low number average molecular weight which is within the range of about 3,000 to about 50,000 and has a glass transition temperature which is within the range of about −50° C. to about 20° C.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: May 13, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Mark Leslie Kralevich, Jr., Paul Harry Sandstrom, Wen-Liang Hsu, Adel Farhan Halasa
  • Patent number: 6525133
    Abstract: A pneumatic tire with a rubber tread which utilized an alpha-methyl styrene oligomer
    Type: Grant
    Filed: March 29, 2000
    Date of Patent: February 25, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, Paul Harry Sandstrom, Mark Leslie Kralevich, Jr., Edward John Blok
  • Patent number: 6429245
    Abstract: The invention relates to a tire with a tread. The tread is composed of at least two defined elastomers having Tg's spaced apart by at least 55° C. to the exclusion of elastomers having Tg's between −30° and −85° C. The tread composition can be reinforced with either carbon black or a combination of carbon black and silica reinforcing fillers.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: August 6, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: William Paul Francik, Edward John Blok, Paul Harry Sandstrom, John Joseph Andre Verthe, David John Zanzig, Adel Farhan Halasa
  • Patent number: 6378582
    Abstract: The present invention relates to a tire tread compound that is highly loaded with silica. This compound offers the advantages of silica compounding without the need for solution SBR. More specifically, the tire tread rubber formulations of this invention offer an excellent combination of traction, treadwear and rolling resistance characteristics. The subject invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (1) 10 phr to 35 phr of high vinyl polybutadiene rubber having a glass transition temperature which is within the range of −40° C. to 10° C., (2) 65 phr to 90 phr of tin-coupled isoprene-butadiene rubber having a glass transition temperature which is within the range of −90° C.
    Type: Grant
    Filed: September 20, 2000
    Date of Patent: April 30, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, Adel Farhan Halasa, Wen-Liang Hsu, Edward John Blok
  • Patent number: 6369255
    Abstract: The present invention relates to titanate compounds of the formula wherein R is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms and x is an integer of from 2 to 8.
    Type: Grant
    Filed: September 30, 1999
    Date of Patent: April 9, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Lawson Gibson Wideman, Paul Harry Sandstrom, Mark Leslie Kralevich, Jr.
  • Patent number: 6357499
    Abstract: The present application relates to polymeric resinous material comprising (1) from 5 to 70 weight percent units derived from limonene; (2) from 5 to 70 weight percent units derived from dicyclopentadiene; (3) from 5 to 45 weight percent units derived from indene; and (4) from 5 to 45 weight percent units derived from tertiary-butyl styrene; wherein the sum of the weight percent units derived from limonene and dicyclopentadiene range from 40 to 75 weight percent units of the resin and the sum of the weight percent units derived from indene and tertiary-butyl styrene range from 25 to 60 weight percent units of the resin.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: March 19, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Mark Leslie Kralevich, Jr., Edward John Blok, Paul Harry Sandstrom, Lawson Gibson Wideman, Joseph Miles Ruscak
  • Patent number: 6350807
    Abstract: The present invention relates to a tire tread compound that is highly loaded with silica. This compound offers the advantages of silica compounding without the need for solution SBR. More specifically, the tire tread rubber formulations of this invention offer an excellent combination of traction, treadwear and rolling resistance characteristics. The subject invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (1) 5 phr to 40 phr of a polyisoprene rubber selected from the group consisting of natural rubber and synthetic polyisoprene, (2) 20 phr to 60 phr of high vinyl polybutadiene rubber having a glass transition temperature which is within the range of −40° C. to 10° C.
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: February 26, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Wen-Liang Hsu, Adel Farhan Halasa, John Joseph Andre Verthe, Raymond Robert DiRossi
  • Patent number: 6348539
    Abstract: This invention relates to a polymeric resin which contains from 35 to 65 percent by weight of polymeric units derived from dicyclopentadiene and from 65 to 35 percent by weight of polymeric units derived from beta-pinene. The polymeric resins are particularly useful in improving traction of the rubber when used in tire treads.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: February 19, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, Mark Leslie Kraleyich, Jr., Edward John Blok, Paul Harry Sandstrom
  • Patent number: 6316567
    Abstract: The present application relates to polymeric resinous material comprising (1) from 5 to 70 weight percent units derived from limonene; (2) from 5 to 70 weight percent units derived from dicyclopentadiene; (3) from 5 to 45 weight percent units derived from indene; and (4) from 5 to 45 weight percent units derived from alpha-methyl styrene; wherein the sum of the weight percent units derived from limonene and dicyclopentadiene range from 40 to 75 weight percent units of the resin and the sum of the weight percent units derived from indene and alpha-methyl styrene range from 25 to 60 weight percent units of the resin.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: November 13, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Mark Leslie Kralevich, Jr., Edward John Blok, Lawson Gibson Wideman, Paul Harry Sandstrom
  • Patent number: 6313206
    Abstract: The present invention relates to titanate compounds of the formula wherein R is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms and x is an integer of from 2 to 8.
    Type: Grant
    Filed: October 1, 1999
    Date of Patent: November 6, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Lawson Gibson Wideman, Paul Harry Sandstrom, Mark Leslie Kralevich, Jr.
  • Patent number: 6300421
    Abstract: The invention relates to preparation of EPDM-based and EPR-based rubber compositions which are vulcanized with peroxide together with a specified combination of sulfur and acrylate co-agents. The invention further relates to articles having at least one component thereof.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: October 9, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Mark Leslie Kralevich, Jr., Paul Harry Sandstrom, Larry Ashley Gordon, James Edward Taucher