Abstract: Compositions and methods for depositing improved zirconium oxide conversion coatings, as well as compositions capable of depositing an adherent zirconium oxide conversion coating on a substrate in the absence of prior cleaning are provided.

Abstract: Compositions and methods for depositing improved zirconium oxide conversion coatings, as well as compositions capable of depositing an adherent zirconium oxide conversion coating on a substrate in the absence of prior cleaning are provided.

Abstract: Autodeposition of a coating containing an epoxy resin is accomplished over a metal substrate that has been coated with a zinc phosphate conversion coating without significant removal of the zinc phosphate conversion coating.

Abstract: Autodeposited coatings useful for protecting metal surfaces and in production of rubber-to-metal composites are obtained by curing adducts based on epoxy resins which are adhered to the metal surface. One or more epoxy resins, such as for example, the combination of a diglycidyl ether of bisphenol A and a flexibilizing epoxy resin, may be prereacted to form an adduct of higher average molecular weight than the starting epoxy resins. Said adduct may then be dispersed in water, with the resulting dispersion being used in an autodeposition bath composition.

Abstract: Autodeposition compositions for polymeric coatings of reduced gloss, good corrosion resistance, and uniform appearance are prepared using a combination of acrylic and epoxy resins.

Abstract: Autodeposition of a coating containing an epoxy resin is accomplished over a metal substrate that has been coated with a zinc phosphate conversion coating without significant removal of the zinc phosphate conversion coating.

Abstract: Autodeposited coatings useful for protecting metal surfaces and in production of rubber-to-metal composites are obtained by curing adducts based on epoxy resins which are adhered to the metal surface. One or more epoxy resins, such as for example, the combination of a diglycidyl ether of bisphenol A and a flexibilizing epoxy resin, may be prereacted to form an adduct of higher average molecular weight than the starting epoxy resins. Said adduct may then be dispersed in water, with the resulting dispersion being used in an autodeposition bath composition.

Abstract: A multilayered coating (10) that is applied to a metal substrate (12). The coating comprises a protective zone of an insoluble crystalline phosphate formed by reaction of the substrate (12) with zinc phosphate. A film (16) of a polymer resin is deposited on the insoluble crystalline phosphate zone (14). In one embodiment, the multilayered coating (10) includes a coat of paint (18) that is applied to the polymer resin (16). A process for applying the multilayered coating to the metal substrate includes the steps of: applying a zinc phosphating solution to at least a portion of the substrate, which converts the surface to a zone of an insoluble crystalline phosphate; rinsing the zone; and autodepositing a film of a polymer resin thereupon.

Abstract: Autodeposition compositions for polymeric coatings of reduced gloss, good corrosion resistance, and uniform appearance are prepared using a combination of acrylic and epoxy resins.

Abstract: Epoxy resins, particularly those based on bisphenol A, can constitute the principal film forming polymer component of a storage stable autodepositable composition wherein the particle size distribution of all the film forming polymers in the composition satisfies certain criteria of size distribution, and an accelerator component which is an acid, oxidizing agent or complexing agent is present in amount sufficient to provide an oxidation-reduction potential at least 100 mV more oxidizing than a standard hydrogen electrode. Such dispersions can conveniently be prepared using a two stage process in which a solution of the film forming polymers is emulsified into water to form a preliminary dispersion and this preliminary dispersion is subjected to at least one particle size refinement stage in which the preliminary dispersion is forced through a narrow aperture.

Abstract: The corrosion resistance, and also often the heat resistance, of a autodeposited coating in which the organic binders are predominantly copolymers of vinylidene chloride containing at least 50% vinylidene chloride can be improved by including another type of organic resin binder in the autodeposition bath in sufficient amount to constitute at least 2 up to as much as about 40% of the total of the PVDC and the other organic resin binder. Results can be further improved by rinsing the uncured autodeposited coating with an aqueous treatment solution that has a pH between 7 and 11 and contains between 0.01 and 5% of anions derived from multifunctional organic acids, preferably anions of 1-hydroxyethylidene-1,1-diphosphonic acid, citric acid, tartaric acid, and/or oxalic acid before drying the coating.

Abstract: The adhesion and/or corrosion resistance of a autodeposited coating can be improved by rinsing the uncured coating with an aqueous treatment solution that has a pH between 7 and 11 and contains between 0.05 and 5 w/o of anions derived from multifunctional organic acids, preferably anions of 1-hydroxyethylidene-1,1-diphosphonic acid, citric acid, tartaric acid, and/or oxalic acid. The method is particularly useful on leaf springs and other metallic objects with surfaces of high carbon and/or shot blasted steel, and is particularly useful in conjunction with an autodeposition bath containing internally stabilized poly {vinylidene chloride} latex, hydrofluoric acid, ferric fluoride, and hydrogen peroxide.

Abstract: The adhesion and/or corrosion resistance of a autodeposited coating can be improved by rinsing the uncured coating with an aqueous treatment solution that has a pH between 7 and 11 and contains between 0.05 and 5 w/o of anions derived from phosphonic acids, preferably anions of 1-hydroxyethylidene-1,1-diphosphonic acid. The method is particularly useful on leaf springs and other metallic objects with surfaces of high carbon and/or shot blasted steel, and is particularly useful in conjunction with an autodeposition bath containing internally stabilized poly (vinylidene chloride) latex, hydrofluoric acid, ferric fluoride, and hydrogen peroxide.