Patents by Inventor Eric Benazzi

Eric Benazzi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6527945
    Abstract: The invention concerns a catalyst comprising at least one matrix, at least one dioctahedral 2:1 phyllosilicate which is optionally synthesised in a fluorine-containing medium and optionally bridged, at least one metal selected from elements from group VIB and/or group VIII of the periodic table, boron and/or silicon, optionally phosphorous, optionally at least one group VIIA element, and optionally at least one group VIIB element. The invention also concerns the use of the catalyst for hydrocracking hydrocarbon-containing feeds.
    Type: Grant
    Filed: May 8, 2001
    Date of Patent: March 4, 2003
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Slavik Kasztelan, Nathalie George-Marchal
  • Patent number: 6524470
    Abstract: A catalyst comprising, in weight % with respect to the total catalyst weight 0.1% to 60% (expressed as the % by weight of oxide) of at least one hydro-dehydrogenating metal selected from the group formed by group VIB and VIII metals; 0.1% to 99% of at least one amorphous or low crystallinity porous matrix; 0.1% to 99.7% of beta zeolite; 0.1% to 20% (expressed as the % by weight of oxide) of at least one promoter element selected from the group formed by boron, silicon and phosphorous; 0 to 20% of at least one halogen; 0 to 20% (expressed as the % by weight of oxide) of at least one group VIIB element, the catalyst being especially useful for cracking hydrocarbon feeds.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: February 25, 2003
    Assignee: Institut Francais du Pétrole
    Inventors: Slavik Kasztelan, Nathalie George-Marchal, Eric Benazzi
  • Publication number: 20030019788
    Abstract: The invention concerns a process for producing middle distillates from an effluent produced by a Fischer-Tropsch unit, comprising optional fractionation to obtain at least one heavy fraction with an initial boiling point in the range 120-200° C., said heavy fraction or said effluent optionally being hydrotreated, then bringing it into contact with a first amorphous hydrocracking/hydroisomerization catalyst that contains at least one noble group VIII metal, the effluent obtained is distilled, then the residual fraction boiling above the middle distillates and/or a portion of the middle distillates is brought into contact with a second amorphous hydrocracking/hydroisomerization catalyst containing at least one noble group VIII metal. The invention also concerns a unit.
    Type: Application
    Filed: July 8, 2002
    Publication date: January 30, 2003
    Applicant: Institut Francais du Petrole
    Inventors: Eric Benazzi, Christophe Gueret
  • Patent number: 6500330
    Abstract: The invention relates to a hydrocracking catalyst comprising at least one amorphous or poorly crystallized matrix of the oxide type, at least one element of group VB, preferably niobium, and at least one zeolite Y not globally dealuminized, at least one promoter element chosen from the group consisting of boron, phosphorus and silicon, optionally at least one element chosen from the elements of group VIB and group VIII, optionally at least one element of group VIIA. The invention also relates to the use of this catalyst for hydrocracking hydrocarbon feeds.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: December 31, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Slavik Kasztelan, Eric Benazzi, Nathalie Marchal-George
  • Publication number: 20020189972
    Abstract: The invention concerns an improved method for making very high quality oil bases optionally with simultaneous production of high quality middle distillates, comprising hydrotreating, hydrocracking preferably on Y or beta zeolite, topping steps. The effluent is subjected to catalytic dewaxing on ZSM-48 zeolite. The method then comprises steps of hydrofinishing to hydrogenate the aromatics, preferably on a catalyst comprising at least a noble metal of group VIII, chlorine and fluorine and steps of vacuum topping. The properties of the oils and middle distillates are enhanced (flow point, viscosity index, aromatic content) resulting even in production of medicinal oils.
    Type: Application
    Filed: July 18, 2002
    Publication date: December 19, 2002
    Inventors: Eric Benazzi, Pierre Marion, Alain Billon, Christophe Gueret, Jean-Claude Hipeaux, Jean Paul Gouzard
  • Publication number: 20020192156
    Abstract: The invention concerns a zeolite with structure type MTT comprising MTT zeolite crystals with a size of less than 5 &mgr;m, at least a portion of the MTT zeolite crystals being in the form of MTT zeolite crystal aggregates, said zeolite being characterized in that the granulometry of the aggregates is such that the dimension Dv,90 is in the range 40 nm to 100 &mgr;m. The invention also concerns the preparation of the zeolite and the use of the zeolite as a catalyst in a process for converting hydrocarbon feeds, and in particular in a process for isomerising straight chain paraffins molecular sieve formed from an MFI, MEL or &bgr; type zeolite by means of the crystallisation temperature It should be noted that these prior art patent applications never mention the specific size of the zeolite crystals and aggregates in combination with particular catalytic properties.
    Type: Application
    Filed: February 21, 2001
    Publication date: December 19, 2002
    Inventors: Loic Rouleau, Frederic Kolenda, Eric Benazzi
  • Patent number: 6491809
    Abstract: Synthetic oil that contains wholly or partly of dialkylbenzenes and/or partially or totally hydrogenated dialkylbenzenes. The synthetic oil according to the invention can also be used as an oil base or oil base additive and comprises at least one dialkylbenzene and/or at least one partially or totally hydrogenated dialkylbenzene and meets the general chemical formula: R1—A—R2 in which R1 and R2 represent alkyl groups and A is a benzene core and/or a cyclohexane core and/or a cyclohexene core and/or a cyclohexadiene core and is characterized in that it contains between 1 and 20% by weight or ortho isomers and in that at least one of the alkyl groups is attached for the most part to group A by carbon 2 of the aliphatic chain. The two alkyl groups are preferably attached for the most part to group A by carbon 2 of the aliphatic chain.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: December 10, 2002
    Assignees: Institut Francais du Petrole, Industrias Venoco C.A.
    Inventors: Patrick Briot, Alain Forestiere, Serge Gautier, Eric Benazzi, Leon Lew
  • Publication number: 20020170847
    Abstract: The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which the feed to be treated is brought into contact with a catalyst comprising at least one dioctahedral 2:1 phyllosilicate, preferably synthesised in a fluoride medium in the presence of the acid HF and/or a further source of fluoride anions, and preferably wherein the interplanar spacing is at least 20×10−10 m (2 nm) and comprising pillars based on at least one oxide of elements from groups IVB, VB, VIB, VIII, IB, IIB, IIA or IVA or any combination of these oxides, preferably selected from the group formed by SiO2, Al2O3, TiO2, ZrO2 and V2O5, or any combination of these latter, and at least one hydrodehydrogenating element in the metallic form. The process is carried out at a temperature in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and at an hourly space velocity in the range 0.
    Type: Application
    Filed: July 23, 2001
    Publication date: November 21, 2002
    Applicant: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George
  • Patent number: 6475464
    Abstract: The present invention concerns a process for preparing a zeolite with structure type MTT comprising at least one element X selected from silicon and germanium and at least one element T selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, characterized in that seeds of at least one zeolitic material are used comprising at least one element X′ selected from silicon and germanium and at least one element T′ selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, said seeds being different from the zeolite with structure type MTT being synthesised. The present invention also concerns the use of the zeolite obtained as a catalyst in a process for converting hydrocarbon-containing feeds, as an adsorbent to control pollution and as a molecular sieve for separation.
    Type: Grant
    Filed: September 29, 2000
    Date of Patent: November 5, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Loïc Rouleau, Frédéric Kolenda, Eric Benazzi
  • Publication number: 20020160911
    Abstract: The invention relates to a catalyst that contains at least one silica-alumina, whereby said silica-alumina has the following characteristics:
    Type: Application
    Filed: January 15, 2002
    Publication date: October 31, 2002
    Applicant: Institut Francais du Petrole
    Inventors: Eric Benazzi, Tivadar Cseri, Magalie Roy-Auberger, Patrick Euzen
  • Patent number: 6436278
    Abstract: The invention concerns a process for producing gasoline with an improved octane number, optionally accompanied by oil and/or middle distillate production, by conversion-hydroisomerization of the paraffins in the feed using a catalyst containing at least one noble metal deposited on an amorphous acidic support. Isoparaffins are separated from the gasoline cut obtained, and normal paraffins and possibly monobranched paraffins contained in the resulting effluent are isomerized using a catalyst containing at least one hydrodehydrogenating metal and at least one acidic solid. The ensemble of the streams charged with isoparaffins with an improved octane number is sent to the gasoline pool. The residue undergoes catalytic dewaxing.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: August 20, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Pierre-Henri Bigeard, Nathalie Marchal-George, Tivadar Cseri
  • Patent number: 6402936
    Abstract: The invention relates to a catalyst that contains at least one partially amorphous Y zeolite, at least one metal of group VB, preferably niobium, at least one amorphous or poorly crystallized matrix, optionally at least one metal that is selected from group VIB and group VIII, optionally at least one element that is selected from the group that is formed by P, B, and Si, and optionally at least one element of group VIIA. The invention also relates to the use of this catalyst in hydrocracking and hydrorefining of hydrocarbon feedstocks.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: June 11, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Jean-Marie Deves, Slavik Kasztelan
  • Patent number: 6387246
    Abstract: The invention relates to a catalyst that contains at least one matrix, a partially amorphous Y zeolite, optionally at least one metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, optionally at least one element that is selected from the group that is formed by phosphorus, boron and silicon, optionally at least one element of group VIIA, and optionally at least one element of group VIIB. The partially amorphous Y zeolite has a peak rate that is less than 0.4, and a crystalline fraction that is expressed relative to a reference zeolite in sodium form and that is less than 60%. The invention also relates to the use of this catalyst in hydroconversion, in particular hydrocracking and hydrorefining of hydrocarbon feedstocks.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: May 14, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Jean-Marie Deves, Bernadette Rebours, Frédéric Chaigne, Tivadar Cseri, Slavik Kasztelan
  • Publication number: 20020045542
    Abstract: The invention concerns a catalyst comprising at least one matrix, at least one dioctahedral 2:1 phyllosilicate which is optionally synthesised in a fluorine-containing medium and optionally bridged, at least one metal selected from elements from group VIB and/or group VIII of the periodic table, boron and/or silicon, optionally phosphorous, optionally at least one group VIIA element, and optionally at least one group VIIB element. The invention also concerns the use of the catalyst for hydrocracking hydrocarbon-containing feeds.
    Type: Application
    Filed: May 8, 2001
    Publication date: April 18, 2002
    Inventors: Eric Benazzi, Slavik Kasztelan, Nathalie George-Marchal
  • Publication number: 20020027094
    Abstract: The invention provides a process for hydrocracking hydrocarbon-containing petroleum feeds in the presence of a catalyst comprising a support containing at least one matrix, and at least one zeolite selected from the group, formed by NU-85, NU-86 and NU-87 zeolites.
    Type: Application
    Filed: September 6, 2001
    Publication date: March 7, 2002
    Inventors: Eric Benazzi, Nathalie George-Marchal, Slavik Kasztelan
  • Patent number: 6350370
    Abstract: The present invention relates to a process for improving the pour point of a feed including paraffins containing more than 10 carbon atoms. Desirably, the feed to be treated is brought into contact with a catalyst based on NU-85 zeolite, at least partially in its acid form, and at least one hydro-dehydrogenating element, at a temperature which is in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and at an hourly space velocity in the range 0.05 to 100 h−1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: February 26, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie George-Marchal, Christophe Gueret, Patrick Briot, Alain Billon, Pierre Marion
  • Publication number: 20020019307
    Abstract: The invention concerns a process for skeletal isomerisation of linear olefins using a catalyst containing at least one pre-treated molecular sieve selected from the group formed by SAPO-31, SAPO-11, Theta-1, EU-1, omega zeolite, mordenite, Nu-10, Nu-86, Nu-87, ferrierite, ZSM-12 and ZSM-23.
    Type: Application
    Filed: September 11, 1998
    Publication date: February 14, 2002
    Inventors: ERIC BENAZZI, MICHEL GUISNET, CHRISTINE TRAVERS, NGI SUOR GNEP, PATRICIA ANDY
  • Patent number: 6344135
    Abstract: The invention concerns a hydrocracking process using a catalyst comprising at least one matrix, an IM-5 zeolite, at least one metal selected from the group formed by metals from group VIB and group VIII of the periodic table, optionally at least one element selected from the group formed by phosphorous, boron and silicon, and optionally at least one group VIIA and/or at least one group VIIB and/or at least one group VB element (in particular niobium). The invention also concerns a catalyst containing at least one matrix, an IM-5 zeolite, at least one metal from groups VIII and/or VIB and at least one promoter element which is boron and/or silicon. The catalyst can also contain at least one group VIIA element and/or at least one group VIIB element and/or at least one group VB element.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: February 5, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Slavik Kasztelan
  • Patent number: 6337427
    Abstract: A process for isomerising aromatic compounds containing eight carbon atoms is described in which the catalyst used contains at least one zeolite with structure type EUO and a group VIII element. In FIG. 1, the feed to be isomerised is introduced into reactor R via line 1. This fresh feed is enriched via lines 6 and 11 with a mixture containing at least one compound selected from the group formed by paraffins containing eight carbon atoms, benzene, toluene and naphthenes containing eight carbon atoms. Hydrogen is added via line 15.
    Type: Grant
    Filed: April 7, 1999
    Date of Patent: January 8, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Fabio Alario, Jean-François Joly, Julia Magne-Drisch, Elisabeth Merlen, Eric Benazzi, Sylvie Lacombe
  • Patent number: 6337428
    Abstract: A process for the catalytic conversion of hydrocarbons, in particular for the oligomerization of olefins wherein the catalyst comprises a zeolite which is at least partially in its acid form. The zeolite is a NU-86 zeolite comprising silicon and at least one element T selected from the group formed by aluminum, iron, gallium and boron, preferably aluminum, characterized in that element T has been extracted from the framework, and in that it has a global Si/T atomic ratio of more than about 20. Element T is extracted from the zeolitic framework (or network) by means of at least one heat treatment, optionally carried out in the presence of steam, followed by at least one acid attack using at least one solution of a mineral or organic acid, or by direct acid attack.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: January 8, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nicolas Chouteau, Hervé Cauffriez