Patents by Inventor Freddy Helmer-Metzmann

Freddy Helmer-Metzmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6818590
    Abstract: The present invention relates to an absorbent comprising at least one cycloolefin copolymer which contains polymerized units which are derived from at least one cyclic and at least one acyclic olefin.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: November 16, 2004
    Assignee: Ticona GmbH
    Inventors: Freddy Helmer-Metzmann, Alexandra Jacobs
  • Publication number: 20020162799
    Abstract: The present invention relates to an absorbent comprising at least one cycloolefin copolymer which contains polymerized units which are derived from at least one cyclic and at least one acyclic olefin.
    Type: Application
    Filed: April 30, 2002
    Publication date: November 7, 2002
    Inventors: Freddy Helmer-Metzmann, Alexandra Jacobs
  • Patent number: 6383396
    Abstract: The present invention relates to an absorbent comprising at least one cycloolefin copolymer which contains polymerized units which are derived from at least one cyclic and at least one acyclic olefin.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: May 7, 2002
    Assignees: Ticona GmbH, Mitsui Petrochemical Ind., Ltd.
    Inventors: Freddy Helmer-Metzmann, Alexandra Jacobs
  • Patent number: 6239187
    Abstract: The present invention relates to foams comprising cycloolefin copolymers. The foam of the invention comprises at least one cycloolefin copolymer which comprises from 0.1 to 100% by weight, based on the total mass of the cycloolefin copolymer, of polymerized units derived from one or more polycyclic olefins having one or more norbornene units and from 0 to 99% by weight, based on the total mass of the cycloolefin copolymer, of polymerized units derived from one or more acyclic olefins of the formula  where Ri, Rii, Riii and Riv are identical or different and are each a hydrogen atom, a linear, branched, saturated or unsaturated C1-C20-hydrocarbon radical or a C6-C18-aryl radical and from 0 to 99% by weight, based on the total mass of the cycloolefin copolymer, of polymerized units of one or more monocyclic olefins of the formula VIII  where n is a number from 2 to 10, and voids which can contain one or more gaseous substances.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: May 29, 2001
    Assignee: Ticona GmbH
    Inventors: Wilfried Hatke, Freddy Helmer-Metzmann, Alexandra Jacobs
  • Patent number: 6214488
    Abstract: In order to produce a polymer electrolyte membrane from sulfonated, aromatic polyether ketone, an aromatic polyether ketone of the formula (I) in which Ar is a phenylene ring having p- and/or m-bonds, Ar′ is a phenylene, naphthylene, biphenylene, anthrylene or another divalent aromatic unit, X, N and M, independently of one another are 0 or 1, Y is 0, 1, 2 or 3, P is 1, 2, 3 or 4, is sulfonated and the sulfonic acid is isolated. At least 5% of the sulfonic groups in the sulfonic acid are converted into sulfonyl chloride groups, and these are reacted with an amine containing at least one crosslinkable substituent or a further functional group, and unreacted sulfonyl chloride groups are subsequently hydrolyzed. The resultant aromatic sulfonamide is isolated and dissolved in an organic solvent, the solution is converted into a film, and the crosslinkable substituents in the film are then crosslinked.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: April 10, 2001
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Freddy Helmer-Metzmann, Frank Osan, Arnold Schneller, Helmut Ritter, Konstantin Ledjeff, Roland Nolte, Ralf Thorwirth
  • Patent number: 6132622
    Abstract: The present invention relates to an absorbent comprising at least one cycloolefin copolymer which contains polymerized units which are derived from at least one cyclic and at least one acyclic olefin.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: October 17, 2000
    Assignees: Ticona GmbH, Mitsui Petrochemical Ind. Ltd.
    Inventors: Freddy Helmer-Metzmann, Alexandra Jacobs
  • Patent number: 6096856
    Abstract: The invention relates to a process for the chlorosulfonation of polyarylene sulfide in which the polyarylene sulfide is completely dissolved in chlorosulfonic acid at a temperature of -10 to +20 C., then agitated at reaction temperatures in the +5 to +20 C. range for a reaction time of 180 min at the most, possibly with the addition of oleum or acetic anhydride and the precipitated in an aqueous medium. The polyarylene sulfide is preferably poly-p-phenylene sulfide. The invention also relates to chlorosulfonated polyarylene sulfide produced by this process, which dissolves in a quantity of 10 to 50 wt % in N-methyl pyrrolidone and has a mean molecular weight Mw of >50,000 g/mol. Finally, the invention also relates to the use of chlorosulfonated polyarylene sulfide for the production of molding, foils, fibres or diaphragms with a proton conductivity in the 2 to 200 mS/cm range.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: August 1, 2000
    Assignee: Hoechst Research & Technology Deutschland GmbH & Co. KG
    Inventors: Freddy Helmer-Metzmann, Andreas Schleicher, Arnold Schneller, Helmut Witteler
  • Patent number: 6063949
    Abstract: The present invention relates to a stereorigid metallocene compound having as ligands at least two substituted or unsubstituted cyclopentadienyl groups which are connected to one another via a five-membered ring, where at least one cyclopentadienyl group is fused onto the five-membered ring and the ligand system of the stereorigid metallocene compound is different from 4-[.eta..sup.5 -3'-alkylcyclopentadienyl)-4,6,6-trimethyl-(.eta..sup.5 -2-alkyl-4,5-tetrahydropentalene]. The metallocene compound of the invention is suitable as a catalyst component for olefin polymerization.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: May 16, 2000
    Assignee: Targor GmbH
    Inventors: Michael Aulbach, Frank Kuber, Michael Riedel, Freddy Helmer-Metzmann
  • Patent number: 5853911
    Abstract: In the electrochemical cell comprising a housing in which two diffusion electrodes are arranged which contain active catalyst particles and at whose rears in each case a contiguous compartment for a gas is provided, a compartment for a liquid electrolyte being provided between the diffusion electrodes, there is arranged, between the diffusion electrodes, at least one anion exchanger membrane directly in front of one of the diffusion electrodes.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: December 29, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karl-Heinz Tetzlaff, Rudiger Walz, Freddy Helmer-Metzmann
  • Patent number: 5834566
    Abstract: Homogeneous polymer alloys comprising, as the main constituents, sulfonated aromatic polyether-ketones and at least one aromatic polysulfone, wherein the materials have a good thermal and mechanical stability and are thereby distinguished in particular as cation exchanger membranes for electrochemical cells with operating temperatures above 100.degree. C.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: November 10, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Freddy Helmer-Metzmann, Arnold Schneller
  • Patent number: 5741408
    Abstract: In order to produce a polymer electrolyte membrane from sulfonated, aromatic polyether ketone, an aromatic polyether ketone of the formula (I) ##STR1## in which Ar is a phenylene ring having p- and/or m-bonds,Ar' is a phenylene, naphthylene, biphenylene, anthrylene or another divalent aromatic unit,X, N and M, independently of one another are 0 or 1,Y is 0, 1, 2 or 3,P is 1, 2, 3 or 4,is sulfonated and the sulfonic acid is isolated. At least 5% of the sulfonic groups in the sulfonic acid are converted into sulfonyl chloride groups, and these are reacted with an amine containing at least one crosslinkable substituent or a further functional group, and unreacted sulfonyl chloride groups are subsequently hydrolyzed. The resultant aromatic sulfonamide is isolated and dissolved in an organic solvent, the solution is converted into a film, and the crosslinkable substituents in the film are then crosslinked.In specific cases, the crosslinkable substituents can be omitted.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: April 21, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Freddy Helmer-Metzmann, Frank Osan, Arnold Schneller, Helmut Ritter, Konstantin Ledjeff, Roland Nolte, Ralf Thorwirth
  • Patent number: 5656389
    Abstract: In the electrochemical cell comprising a housing in which two diffusion electrodes are arranged which contain active catalyst particles and at whose rears in each case a contiguous compartment for a gas is provided, a compartment for a liquid electrolyte being provided between the diffusion electrodes, there is arranged, between the diffusion electrodes, at least one ion exchanger membrane directly in front of one of the diffusion electrodes.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: August 12, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karl-Heinz Tetzlaff, Rudiger Walz, Freddy Helmer-Metzmann
  • Patent number: 5561202
    Abstract: In order to produce a polymer electrolyte membrane from sulfonated, aromatic polyether ketone, an aromatic polyether ketone of the formula (I) ##STR1## in which Ar is a phenylene ring having p- and/or m-bonds,Ar' is a phenylene, naphthylene, biphenylene, anthrylene or another divalent aromatic unit,X, N and M, independently of one another are 0 or 1,Y is 0, 1, 2 or 3,P is 1, 2, 3 or 4,is sulfonated and the sulfonic acid is isolated. At least 5% of the sulfonic groups in the sulfonic acid are converted into sulfonyl chloride groups, and these are reacted with an amine containing at least one crosslinkable substituent or a further functional group, and unreacted sulfonyl chloride groups are subsequently hydrolyzed. The resultant aromatic sulfonamide is isolated and dissolved in an organic solvent, the solution is converted into a film, and the crosslinkable substituents in the film are then crosslinked.In specific cases, the crosslinkable substituents can be omitted.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: October 1, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Freddy Helmer-Metzmann, Frank Osan, Arnold Schneller, Helmut Ritter, Konstantin Ledjeff, Roland Nolte, Ralf Thorwirth
  • Patent number: 5510424
    Abstract: Homogeneous polymer alloys based on sulfonated, aromatic polyether ketonesHomogeneous polymer alloys comprising sulfonated, aromatic polyether ketones and at least one polyamide as the main constituents, wherein the polyamide is a completely aromatic polyamide.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: April 23, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Freddy Helmer-Metzmann, Otto Hermann-Schonherr, Uwe Kampschulte
  • Patent number: 5505851
    Abstract: Semipermeable membranes of homogeneously miscible polymer alloys and a process for their preparation. In particular, semipermeable membranes of homogeneous polymer alloys which contain sulfonated, aromatic polyether ketones and at least one polyamide as the main constituents, wherein the polyamide is a completely aromatic polyamide.
    Type: Grant
    Filed: December 28, 1993
    Date of Patent: April 9, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Reinhard Wagener, Freddy Helmer-Metzmann, Otto Herrmann-Schonherr
  • Patent number: 5438082
    Abstract: In order to produce a polymer electrolyte membrane from sulfonated, aromatic polyether ketone, an aromatic polyether ketone of the formula (I) ##STR1## in which Ar is a phenylene ring having p- and/or m-bonds,Ar' is a phenylene, naphthylene, biphenylene, anthrylene or another divalent aromatic unit,X, N and M, independently of one another are 0 or 1,Y is 0, 1, 2 or 3,P is 1, 2, 3 or 4,is sulfonated and the sulfonic acid is isolated. At least 5% of the sulfonic groups in the sulfonic acid are converted into sulfonyl chloride groups, and these are reacted with an amine containing at least one crosslinkable substituent or a further functional group, and unreacted sulfonyl chloride groups are subsequently hydrolyzed. The resultant aromatic sulfonamide is isolated and dissolved in an organic solvent, the solution is converted into a film, and the crosslinkable substituents in the film are then crosslinked.In specific cases, the crosslinkable substituents can be omitted.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: August 1, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Freddy Helmer-Metzmann, Frank Osan, Arnold Schneller, Helmut Ritter, Konstantin Ledjeff, Roland Nolte, Ralf Thorwirth
  • Patent number: 5373081
    Abstract: Polyether ketones and polyether sulfones based on phenylindane and the use thereof for optical systemsPolymeric ethers containing phenylindane units, of the formula ##STR1## in which X=CO or SO.sub.2,Y=a divalent heteroarylene radical or an arylene radical or a divalent group of two aryl radicals which are bonded to one another via a bridge,R.sup.1 =CH.sub.3 ; R.sup.2 =R.sup.3 =H, orR.sup.2 =CH.sub.3 ; R.sup.1 =R.sup.3 =(C.sub.1 to C.sub.16)-alkyl or aryl, orR.sup.1 =CH.sub.3 ; R.sub.3 =H; R.sup.2 =(C.sub.1 to C.sub.16)-alkyl or aryl,are transparent and are suitable for optical systems.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: December 13, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dazhong Yang, Gerhard Maier, Oskar Nuyken, Michael-Joachim Brekner, Freddy Helmer-Metzmann
  • Patent number: 5362836
    Abstract: Polymer electrolytes are described that comprise a sulfonated aromatic polyether ketone, e.g. of the formula II ##STR1## where A is from 0.2 to 1,c is from 0 to 0.8, anda+c=1.The polymer electrolytes are prepared by dissolving an aromatic polyether ketone in 94-97% by weight sulfuric acid and adding a sulfonating agent, e.g. oleum, to the solution until the sulfuric acid concentration is from 98 to 99.9% by weight.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: November 8, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Freddy Helmer-Metzmann, Frank Osan