Patents by Inventor Gabriel Skupin
Gabriel Skupin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11401373Abstract: The invention relates to a continuous process for producing an aliphatic polyester constructed from aliphatic dicarboxylic acids and aliphatic diols comprising the steps of a) esterification, b) polycondensation and optionally c) chain extension, characterized in that during step b) in which the polycondenser functions as a degassing apparatus (B) and/or b?) after the polycondensation in an additional degassing apparatus (B?) the crude polyester is degassed at a pressure of 0.01 to 5 mbar in the presence of 1% to 7% by weight, based on the total weight of the crude polyester of water, introduced into the gas space of the degassing apparatus B and/or B? as an entraining agent.Type: GrantFiled: November 15, 2018Date of Patent: August 2, 2022Assignee: BASF SEInventors: Maximilian Lehenmeier, Norbert Effen, Gabriel Skupin
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Patent number: 11401413Abstract: The present invention relates to an injection molded article comprising: i) 27% to 87% by weight based on the total weight of the components i to iv of a polyester constructed from aliphatic dicarboxylic acids and aliphatic diols; ii) 3% to 15% by weight based on the total weight of the components i to iv of an aliphatic-aromatic polyester comprising: ii-a) 30 to 70 mol % based on the components ii-a to ii-b of a C6-C18-dicarboxylic acid; ii-b) 30 to 70 mol % based on the components ii-a to ii-b of terephthalic acid; ii-c) 99 to 100 mol % based on the components ii-a to ii-b of 1,3-propanediol or 1,4-butanediol; ii-d) 0% to 1% by weight based on the components ii-a to ii-c of a chain extender and/or branching agent; iii) 0% to 35% by weight based on the total weight of the components i to iv of polylactic acid; iv) 10% to 35% by weight based on the total weight of the components i to iv of at least one surface-modified silicate selected from the group consisting of: kaolin, muscovite, montmorillonite, talType: GrantFiled: August 9, 2018Date of Patent: August 2, 2022Assignee: BASF SEInventors: Maximilian Lehenmeier, Martin Bussmann, Norbert Effen, Johannes Klaus Sprafke, Gabriel Skupin
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Publication number: 20220162788Abstract: The present invention relates to a nonwoven fabric comprising continuous spunbonded bicomponent fibers which consist of: 0 to 95% by weight of an aromatic polyester (A) in a core; to 50% by weight of a polyester blend (B) containing a) 65 to 95% of an aromatic polyester (BA) and b) 5 to 35% by weight of an aliphatic-aromatic polyester (BB) with a glass temperature below 0° C. in a sheath surrounding the core; and 0 to 5% by weight of at least one additive (C); wherein the % by weight are based in each case on the total weight of the components (A) and (B) and optionally (C); and wherein the aromatic polyesters (A) and (BA) are selected from the group consisting of poly(ethylene terephthalate) and poly(butylene terephthalate).Type: ApplicationFiled: March 5, 2020Publication date: May 26, 2022Inventors: Gijsbrecht Jacobus Maria HABRAKEN, Klaus SCHEUERMANN, Gabriel SKUPIN, Jens-Uwe SCHIERHOLZ
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Patent number: 11319407Abstract: The present invention relates to a continuous process for purifying a chain-extended aliphatic polyester constructed from aliphatic dicarboxylic acids and aliphatic diols in a degassing apparatus, wherein the crude polyester is degassed for 3 to 30 minutes at a pressure of 0.01 to 5 mbar in the presence of 1% to 7% by weight, based on the total weight of the crude polyester, of an entraining agent.Type: GrantFiled: November 15, 2018Date of Patent: May 3, 2022Assignee: BASF SEInventors: Maximilian Lehenmeier, Norbert Effen, Gabriel Skupin, Rainer Naef
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Publication number: 20210155792Abstract: The present invention relates to an injection molded article comprising: i) 30% to 90% by weight based on the total weight of the components i to iii of a biodegradable polyester comprising: i-a) 90 to 100 mol % based on the components a to b of succinic acid; i-b) 0 to 10 mol % based on the components a to b of one or more C6-C20 dicarboxylic acids; i-c) 99 to 100 mol % based on the components a to b of 1,3-propanediol or 1,4-butanediol; i-d) 0% to 1% by weight based on the components a to c of a chain extender and/or branching agent; ii) 0% to 35% by weight based on the total weight of the components i to iii of polylactic acid; iii) 10% to 35% by weight based on the total weight of the components i to iii of at least one methacryloylsilane- or vinylsilane-modified silicate selected from the group consisting of: kaolin, muscovite, montmorillonite, talc and wollastonite.Type: ApplicationFiled: August 9, 2018Publication date: May 27, 2021Inventors: Maximilian LEHENMEIER, Martin BUSSMANN, Norbert EFFEN, Johannes Klaus SPRAFKE, Gabriel SKUPIN
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Publication number: 20200376822Abstract: The invention relates to a biodegradable three-layer polyester film of 8 to 20 ?m in thickness having a layer construction NB/C or preferably A/B/A, wherein the two outer layers (A) or (A, C) are composed of: Ai) 55% to 99.99% by weight based on the polyester mixture of the outer layers of a polyester selected from the group consisting of: polybutylene sebacate-co-terephthalate, polybutylene sebacate-co-adipate-co-terephthalate, polybutylene sebacate-co-succinate-co-terephthalate or mixtures thereof or a mixture of polybutylene sebacate-co-terephthalate and polybutylene adipate-co-terephthalate; Aii) 0.01% to 5% by weight based on the polyester mixture of the outer layers of at least one additive selected from the group consisting of: a wax, a plasticizer, a nucleating agent, antifogging agents, fillers and an antiblocking agent; and Aiii) 0% to 44.Type: ApplicationFiled: April 5, 2018Publication date: December 3, 2020Inventors: Robert LOOS, Joerg AUFFERMANN, Norbert EFFEN, Nora SCHLUTT, Carsten SINKEL, Jerome LOHMANN, Gabriel SKUPIN, Andreas KUENKEL
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Publication number: 20200362101Abstract: The invention relates to a continuous process for producing an aliphatic polyester constructed from aliphatic dicarboxylic acids and aliphatic diols comprising the steps of a) esterification, b) polycondensation and optionally c) chain extension, characterized in that during step b) in which the polycondenser functions as a degassing apparatus (B) and/or b?) after the polycondensation in an additional degassing apparatus (B?) the crude polyester is degassed at a pressure of 0.01 to 5 mbar in the presence of 1% to 7% by weight, based on the total weight of the crude polyester of water, introduced into the gas space of the degassing apparatus B and/or B? as an entraining agent.Type: ApplicationFiled: November 15, 2018Publication date: November 19, 2020Inventors: Maximilian LEHENMEIER, Norbert EFFEN, Gabriel SKUPIN
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Publication number: 20200362103Abstract: The present invention relates to a continuous process for purifying a chain-extended aliphatic polyester constructed from aliphatic dicarboxylic acids and aliphatic diols in a degassing apparatus, wherein the crude polyester is degassed for 3 to 30 minutes at a pressure of 0.01 to 5 mbar in the presence of 1% to 7% by weight, based on the total weight of the crude polyester, of an entraining agent.Type: ApplicationFiled: November 15, 2018Publication date: November 19, 2020Inventors: Maximilian LEHENMEIER, Norbert EFFEN, Gabriel SKUPIN, Rainer NAEF
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Publication number: 20200255655Abstract: The present invention relates to an injection molded article comprising: i) 27% to 87% by weight based on the total weight of the components i to iv of a polyester constructed from aliphatic dicarboxylic acids and aliphatic diols; ii) 3% to 15% by weight based on the total weight of the components i to iv of an aliphatic-aromatic polyester comprising: ii-a) 30 to 70 mol % based on the components ii-a to ii-b of a C6-C18-dicarboxylic acid; ii-b) 30 to 70 mol % based on the components ii-a to ii-b of terephthalic acid; ii-c) 99 to 100 mol % based on the components ii-a to ii-b of 1,3-propanediol or 1,4-butanediol; ii-d) 0% to 1% by weight based on the components ii-a to ii-c of a chain extender and/or branching agent; iii) 0% to 35% by weight based on the total weight of the components i to iv of polylactic acid; iv) 10% to 35% by weight based on the total weight of the components i to iv of at least one surface-modified silicate selected from the group consisting of: kaolin, muscovite, montmorillonite, talType: ApplicationFiled: August 9, 2018Publication date: August 13, 2020Inventors: Maximilian LEHENMEIER, Martin BUSSMANN, Norbert EFFEN, Johannes Klaus SPRAFKE, Gabriel SKUPIN
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Patent number: 10526461Abstract: The invention relates to a biodegradable polyester mixture comprising: i) 71 to 91 wt %, based on the total weight of components i and ii, of a polyester I constructed from: a-1) 40 to 70 wt %, based on the total weight of components a and b, of an aliphatic C9-C16 dicarboxylic acid or of a C9-C16 dicarboxylic acid derivative; b-1) 30 to 60 wt %, based on the total weight of components a and b, of terephthalic acid or of a terephthalic acid derivative; c-1) 98 to 100 wt %, based on the total weight of components a and b, of a C3-C6 diol; d-1) 0 to 2 wt %, based on the total weight of components a and b, of an at least trihydric alcohol; e-1) 0 to 2 wt %, based on the total weight of components a to e, of a chain extender, and ii) 9 to 29 wt %, based on the total weight of components i and ii, of a polyester II constructed from: a-2) 40 to 70 wt %, based on the total weight of components a and b, of an aliphatic C4-C6 dicarboxylic acid or of a C4-C6 dicarboxylic acid derivative; b-2) 30 to 60 wt %, basedType: GrantFiled: November 8, 2013Date of Patent: January 7, 2020Assignee: BASF SEInventors: Xin Yang, Jörg Auffermann, Carsten Sinkel, Jerome Lohmann, Robert Loos, Gabriel Skupin, Andreas Künkel, Lars Börger
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Patent number: 9914831Abstract: The present invention relates to an injection-molded item with HDT-B temperature of from 80 to 105° C. in accordance with DIN EN ISO 75-2:2004-09, comprising: i) from 47 to 59% by weight, based on the total weight of components i to iv, of a biodegradable aliphatic polyester; ii) from 3 to 14% by weight, based on the total weight of components i to iv, of an aliphatic-aromatic polyester; iii) from 15 to 24% by weight, based on the total weight of components i to iv, of polylactic acid; iv) from 10 to 35% by weight, based on the total weight of components i to iv, of at least one mineral filler; where the following applies to the compounded material comprising components i to iv: the ratio of component i to component iii in the compounded material is from 2.2 to 3.2, and the MVR of the compounded material is from 8 to 50 cm3/10 min in accordance with DIN EN 1133-1 of Mar. 1, 2012 (190° C., 2.16 kg).Type: GrantFiled: April 29, 2015Date of Patent: March 13, 2018Assignee: BASF SEInventors: Maximillian Lehenmeier, Gabriel Skupin, Martin Bussmann
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Patent number: 9914832Abstract: The present invention relates to an item produced by thermoforming, comprising: i) from 45 to 59% by weight, based on the total weight of components i to iv, of a biodegradable polyester comprising: i-a) from 90 to 100 mol %, based on components i-a to i-b, of succinic acid; i-b) from 0 to 10 mol %, based on components i-a to i-b, of one or more C6-C20 dicarboxylic acids; i-c) from 98 to 102 mol %, based on components i-a to i-b, of 1,3-propanediol or 1,4-butanediol; i-d) from 0.05 to 1% by weight, based on components i-a to i-c, of a chain extender or branching agent; ii) from 5 to 14% by weight, based on the total weight of components i to iv, of an aliphatic-aromatic polyester comprising: ii-a) from 30 to 70 mol %, based on components ii-a to ii-b, of a C6-C18-dicarboxylic acid; ii-b) from 30 to 70 mol %, based on components ii-a to ii-b, of terephthalic acid; ii-c) from 98 to 100 mol %, based on components ii-a to ii-b, of 1,3-propanediol or 1,4-butanediol; ii-d) from 0.Type: GrantFiled: April 29, 2015Date of Patent: March 13, 2018Assignee: BASF SEInventors: Maximilian Lehenmeier, Gabriel Skupin, Martin Bussmann
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Patent number: 9844797Abstract: The present invention relates to a process for coating paper, wherein the coating material used is a biodegradable, aliphatic-aromatic polyester having a melt volume rate (MVR) according to EN ISO 1133 (190° C., 2.16 kg weight) of from 3 to 50 cm3/10 min.Type: GrantFiled: September 24, 2015Date of Patent: December 19, 2017Assignee: BASF SEInventors: Gabriel Skupin, Robert Loos, Andreas Füβl, Kimmo Nevalainien
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Publication number: 20170260388Abstract: The present invention relates to an item produced by thermoforming, comprising: i) from 45 to 59% by weight, based on the total weight of components i to iv, of a biodegradable polyester comprising: i-a) from 90 to 100 mol %, based on components i-a to i-b, of succinic acid; i-b) from 0 to 10 mol %, based on components i-a to i-b, of one or more C6-C20 dicarboxylic acids; i-c) from 98 to 102 mol %, based on components i-a to i-b, of 1,3-propanediol or 1,4-butanediol; i-d) from 0.05 to 1% by weight, based on components i-a to i-c, of a chain extender or branching agent; ii) from 5 to 14% by weight, based on the total weight of components i to iv, of an aliphatic-aromatic polyester comprising: ii-a) from 30 to 70 mol %, based on components ii-a to ii-b, of a C6-C18-dicarboxylic acid; ii-b) from 30 to 70 mol %, based on components ii-a to ii-b, of terephthalic acid; ii-c) from 98 to 100 mol %, based on components ii-a to ii-b, of 1,3-propanediol or 1,4-butanediol; ii-d) from 0.Type: ApplicationFiled: April 29, 2015Publication date: September 14, 2017Inventors: Maximilian LEHENMEIER, Gabriel SKUPIN, Martin BUSSMANN
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Publication number: 20170260387Abstract: The present invention relates to an injection-molded item with HDT-B temperature of from 80 to 105° C. in accordance with DIN EN ISO 75-2:2004-09, comprising: i) from 47 to 59% by weight, based on the total weight of components i to iv, of a biodegradable aliphatic polyester; ii) from 3 to 14% by weight, based on the total weight of components i to iv, of an aliphatic-aromatic polyester; iii) from 15 to 24% by weight, based on the total weight of components i to iv, of polylactic acid; iv) from 10 to 35% by weight, based on the total weight of components i to iv, of at least one mineral filler; where the following applies to the compounded material comprising components i to iv: the ratio of component i to component iii in the compounded material is from 2.2 to 3.2, and the MVR of the compounded material is from 8 to 50 cm3/10 min in accordance with DIN EN 1133-1 of March 1, 2012 (190° C., 2.16 kg).Type: ApplicationFiled: April 29, 2015Publication date: September 14, 2017Inventors: Maximillian LEHENMEIER, Gabriel SKUPIN, Martin BUSSMANN
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Patent number: 9744556Abstract: The present invention relates to a process for coating paper, wherein the coating material used is a biodegradable, aliphatic-aromatic polyester having a melt volume rate (MVR) according to EN ISO 1133 (190° C., 2.16 kg weight) of from 3 to 50 cm3/10 min.Type: GrantFiled: September 22, 2009Date of Patent: August 29, 2017Assignee: BASF SEInventors: Gabriel Skupin, Robert Loos, Andreas Füβl, Kimmo Nevalainen
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Patent number: 9447274Abstract: The invention relates to biodegradable polyester mixture, comprising i) from 5 to 80% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, and ii) from 20 to 95% by weight, based on the total weight of components i to ii, of at least one biodegradable homo- or copolyester selected from the group consisting of polylactide, polycaprolactone, polyhydroxyalkanoates, and polyesters composed of aliphatic dicarboxylic acids and of aliphatic diols, and iii) from 0.Type: GrantFiled: July 13, 2011Date of Patent: September 20, 2016Assignee: BASF SEInventors: Ursula Seeliger, Gabriel Skupin, Dirk Stärke
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Publication number: 20160201270Abstract: The present invention relates to single face or double faced corrugated fiberboard comprising one or more corrugated plies, wherein at least one of the linerboard plies or corrugated plies is a paper-film assembly comprising: i) a 30 to 600 g/m2 grammage papery material of construction, ii) a biodegradable polymeric coating from 1 to 100 ?m in thickness. More particularly, the present invention relates to single face or double faced and/or corrugated fiberboard comprising one or more corrugated plies, wherein at least one of the linerboard plies or corrugated plies is a paper-film assembly comprising: i) a 30 to 600 g/m2 grammage papery material of construction as outer layer, ii) a biodegradable polymeric coating from 1 to 100 ?m in thickness as interlayer, and iii) a 30 to 600 g/m2 grammage papery material of construction as inner layer. The present invention further relates to methods of producing this corrugated fiberboard.Type: ApplicationFiled: January 14, 2015Publication date: July 14, 2016Inventors: Rainer Blum, Gabriel Skupin, Hubertus Kröner, Jurgen Keck
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Patent number: 9296887Abstract: Provided is a resin composition from which a melt molded product which is excellent in transparency, gas barrier property and flexibility and has biodegradability can be obtained. The present invention relates to a resin composition, which comprises a polyvinyl alcohol-based resin (i) comprising a structural unit represented by the following general formula (1) and an aliphatic-aromatic polyester (ii) comprising a specific component, wherein each of R1, R2 and R3 independently represents a hydrogen atom or an organic group, X represents a single bond or a bonding chain, and each of R4, R5 and R6 independently represents a hydrogen atom or an organic group.Type: GrantFiled: March 15, 2011Date of Patent: March 29, 2016Assignee: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.Inventors: Mitsuo Shibutani, Norihito Sakai, Lars Boerger, Gabriel Skupin
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Publication number: 20160010281Abstract: The present invention relates to a process for coating paper, wherein the coating material used is a biodegradable, aliphatic-aromatic polyester having a melt volume rate (MVR) according to EN ISO 1133 (190° C., 2.16 kg weight) of from 3 to 50 cm3/10 min.Type: ApplicationFiled: September 24, 2015Publication date: January 14, 2016Inventors: Gabriel Skupin, Robert Loos, Andreas Füßl, Kimmo Nevalainien