Abstract: Described is an article which dispenses at a constant rate a volatile composition of matter into the atmosphere surrounding the article which volatile composition of matter can be, for example, a perfume composition or air freshener, which article is a container which is a hollow totally enclosed flexible, rigid or partially flexible-partially rigid structure comprising a thin shell totally enclosing an inner void, with the thin shell having a part thereof as a microporous polymer which contains a plurality of finite filler particles which that when the article is located in the ambient environment, the volatile material molecules are passed through the microporous polymer by means of an adsorption desorption mechanism or by means of capillary action. The volatile substance which is a composition of matter is enabled to pass through the microporous polymer at a constant mass flow rate of both the individual volatile components and the total composition.

Abstract: Described is an article useful for dispensing at a constant rate, continuously or discontinuously for discrete periods of time a volatile composition of matter such as an air freshener or perfume composition into the atmosphere surrounding said article, the article being a hollow totally enclosed flexible, rigid or partially flexible-partially rigid structure comprising a thin shell totally enclosing an inner void with part of the thin shell comprising a microporous polymer containing a plurality of finite solid filler particles whereby when the article is located in the ambient environment, the volatile material molecules are transported through the porous polymer at a substantially constant mass flow rate both of the individual volatile components and totally through the porous polymer. The functioning of the article is enabled because the microporous polymer section has (i) the property of transporting water vapor at a rate of between 50 up to 1000 g/m.sup.2 /day at about 25.degree. C.

Abstract: Described is a hollow container comprising a shell which is at least partially porous, containing an entrapped volatile substance and a process for dispensing the volatile substance at a visibly detectable rate, continuously or discontinuously, for discrete periods of time at a steady state, the volatile composition being in the alternative, a perfume composition, a deodorant composition, an air freshener composition, an insecticide composition, a herbicide composition, an odor masking composition, a pheremone composition, an animal repellent composition, or an insect repellent composition. The said container containing the entrapped volatile substance ceases to operate, discretely, when said container is placed in an outer air-tight container. The structure consisting of the outer container and the inner container is also a part of our invention.

Abstract: Described is a hollow container comprising a shell which is at least partially porous, containing an entrapped volatile substance and a process for dispensing the volatile substance at a visibly detectable rate, continuously or discontinuously, for discrete periods of time at a steady state, the volatile composition being in the alternative, a perfume composition, a deodorant composition, an air freshener composition, an insecticide composition, a herbicide composition, an odor masking composition, a pheremone composition, an animal repellent composition, or an insect repellent composition. The said container containing the entrapped volatile substance ceases to operate, discretely, when said container is placed in an outer air-tight container. The structure consisting of the outer container and the inner container is also a part of our invention.