Abstract: A cyanoacrylate-based adhesive composition is disclosed. The cyanoacrylate-based adhesive composition includes a cyanoacrylate monomer, and a bleachable dye including a Michler's hydrol cation or derivatized Michler's hydrol cation, paired with a non-nucleophilic anion that provides a stable color to the cyanoacrylate-based adhesive.

Abstract: Compositions containing conductivity enhancers, which are capable of being coated onto a substrate by means of electrostatic assistance. The compositions comprise one or more cationically polymerizable monomer(s), one or more cationic initiator(s), and one or more non-volatile conductivity enhancer(s) having anionic and cationic portions which are soluble in the monomer(s) and which do not interfere with cationic polymerization wherein the anionic portion is a non-coordinating carbon-containing anion. The compositions may further comprise one or more dissociation enhancing agent(s), oligomer(s) or polymer(s), preferably co-reactive, free-radically curable monomer(s), free-radical generating initiator(s), leveling agents, and other additives or adjuvants to impart specific properties to the polymerized composition.

Abstract: Positive-acting no-process printing plates are disclosed in which a stable visual or print-out image is obtained upon exposure of the plate to actinic radiation. The visual image is obtained by incorporation into the photosensitive layer, a dye which is irreversibly bleached upon exposure of the printing plate. For example, an acid which is generated upon exposure of a photopolymer to radiation may be used to bleach a dye of this invention. The visual or print-out images produced are useful in the production cycle and are stable to basic environments that may be encountered in the production setting.

Abstract: The present invention provides novel dental impression materials, the cure of which can be monitored visually, comprising: (1) a curable silicone polymer; (2) a crosslinker compound containing silicon-bonded-hydrogen groups; (3) a hydrosilation catalyst; and (4) one or more cure-indicating dyes that exhibit a color change in the presence of a silicon-bonded-hydrogen compound and a hydrosilation catalyst. The cure-indicating dye provides the composition with an initial pre-cure color and a different post-cure color. As a result of this change in color, the state of cure of the impression material can be visually monitored.

Abstract: The present invention provides novel hydrosilation-curable compositions, the cure of which can be monitored visually, comprising: (1) an ethylenic compound; (2) a compound containing silicon-bonded-hydrogen groups; (3) a hydrosilation catalyst; and (4) one or more cure-indicating dyes with light absorption in the visible spectrum that exhibit a color change in the presence of a silicon-bonded-hydrogen compound and a precious metal hydrosilation catalyst. The cure-indicating dye provides the composition with an initial pre-cure color and a different post-cure color. As a result of this change in color, the state of cure of the composition can be visually monitored.

Abstract: A process for polymerizing a free-radically polymerizable composition comprising the steps:(a) coating a coatable free-radically polymerizable mixture onto at least one major surface of a web;(b) deoxygenating a liquid inerting medium;(c) immersing the coated web into the deoxygenated liquid inerting medium; and(d) irradiating the immersed coated web with actinic radiation sufficient to effect polymerization of the free-radically polymerizable mixture, while maintaining the liquid inerting medium in an essentially oxygen-free state.

Abstract: A method for monitoring the coating weight, uniformity, defects or markings present in a coating of a composition applied to a substrate comprises the steps:a) providing a substrate with a functional coating of a composition comprising an effective amount of uvescer that absorbs radiant energy, i.e., has an excitation energy, of wavelength .lambda..sub.1 and emits radiant energy of wavelength .lambda..sub.2 ;b) scanning the coating with radiant energy having a wavelength within wavelength .lambda..sub.1 ;c) detecting the radiant energy of wavelength .lambda..sub.2 emitted by the coating; andd) optionally, correlating the emitted radiant energy to independently measured standard coating weights or thicknesses, of the coating so as to measure coating weight, thickness, uniformity, defects, or markings.

Abstract: A method for monitoring the coating weight, uniformity, defects or markings present in a coating of a composition applied to a substrate comprises the steps:a) providing a substrate with a functional coating of a composition comprising an effective amount of uvescer that absorbs radiant energy, i.e., has an excitation energy, of wavelength .lambda..sub.1 and emits radiant energy of wavelength .lambda..sub.2 ;b) scanning the coating with radiant energy having a wavelength within wavelength .lambda..sub.1 ;c) detecting the radiant energy of wavelength .lambda..sub.2 emitted by the coating; andd) optionally, correlating the emitted radiant energy to independently measured standard coating weights or thicknesses, of the coating so as to measure coating weight, thickness, uniformity, defects, or markings.

Abstract: A thermal-dye-bleach construction comprising a thermal nucleophile-generating agent in association with a styryl dye having a nucleus of general formula (I): ##STR1## representing the nucleus of a styryl dye in which R=methyl or ethyl groupY=alkoxy of 1 to 20 carbon atomsm=1 or 2,n=1, 2, or 3, andx.sup..crclbar. =an anionThe aromatic fused benzene portion of the indolenine ring may be further substituted with commonly acceptable dye substituents such as alkyl and substituted alkyl (of 1 to 10 carbon atoms) groups, alkoxy groups (preferably of 1 to 10 carbon atoms), fused aromatic rings (as to make the benzene ring a fused naphthalene ring), halogen (including fluoro), cyano, nitro, carboxamido, amido, etc. One or two substituents chosen variously from said group may also be present on the phenyl ring to which the alkoxy group is attached.

Abstract: Light-stable film-forming salts of a sulfonated polymer, especially a sulfonated polyester, and a cationic dye. When these dye-polysalts are coated onto shaped polymeric structures, especially transparent self-supporting films, the resultant products have important optical uses. A polyester film coated with certain red or amber blends of dye-polysalts and provided with a pressure-sensitive adhesive coating is useful as a lithographers' tape.

Abstract: A curable composition, the cure of which can be monitored optically, comprises at least one of a hydride curable silicone, an ethylenically unsaturated compound, and a cationically polymerizable monomer, and as cure monitor dibenzofulvene or derivative thereof. The cure monitor is a latent fluorophore which reacts under the cure conditions to form a UV-detectable fluorophore.The invention also provides a method for measuring degree of cure of a polymeric material which can be a coating or an article.

Abstract: A curable composition, the cure of which can be monitored optically, comprises at least one of a hydride curable silicone, an ethylenically unsaturated compound, and a cationically polymerizable monomer, and as cure monitor dibenzofulvene or derivatives thereof. The cure monitor is a latent fluorophore which reacts under the cure conditions to form a UV-detectable fluorophore.The invention also provides a method for measuring degree of cure of a polymeric material which can be a coating or an article.

Abstract: A method for monitoring the coating weight, uniformity, defects or markings present in a coating of a composition applied to a substrate comprises the steps:a) providing a substrate with a functional coating of a composition comprising an effective amount of uvescer that absorbs radiant energy, i.e., has an excitation energy, of wavelength .lambda..sub.1 and emits radiant energy of wavelength .lambda..sub.2 ;b) scanning the coating with radient energy having a wavelength within wavelength .lambda..sub.1 ;c) detecting the radiant energy of wavelength .lambda..sub.2 emitted by the coating; andd) optionally, correlating the emitted radiant energy to independently measured standard coating weights or thicknesses, of the coating so as to measure coating weight, thickness, uniformity, defects, or markings.

Abstract: Devices for and method of generating coherent second harmonic light radiation. The devices comprise a laser source of coherent light radiation at a fixed fundamental frequency, an acentrically crystalline, achiral, straight-chain N-nitrophenyl carbamyl compound, means for directing the output radiation of the laser onto the acentrically crystalline, achiral, straight-chain N-nitrophenyl carbamyl compound, and output means for utilizing the second harmonic frequency. N-nitrophenyl carbamyl compounds, and acentric crystals thereof that are capable of being used in the aforementioned devices and method, are also described herein.

Abstract: A curable composition, the cure of which can be monitored optically, comprises at least one of a hydride curable silicone, an ethylenically unsaturated compound, and a cationically polymerizable monomer, and as cure monitor dibenzofulvene or derivatives thereof. The cure monitor is a latent fluorophore which reacts under the cure conditions to form a UV-detectable fluorophore.The invention also provides a method for measuring degree of cure of a polymeric material which can be a coating or an article.

Abstract: A method for monitoring the coating weight, uniformity, defects or markings present in a coating of a composition applied to a substrate comprises the steps:(a) providing a substrate with a functional coating of a composition comprising an effective amount of uvescer that absorbs radiant energy, i.e., has excitation energy, of wavelength .lambda..sub.1 and emits radiant energy of wavelength .lambda..sub.2 ;(b) scanning the coating with radiant energy having a wavelength within wavelength .lambda..sub.1 ;(c) detecting the radiant energy of wavelength .lambda..sub.2 emitted by the coating; and(d) optionally, correlating the emitted radiant energy to independently measured standard coating weights or thicknesses, of the coating so as to measure coating weight, thickness, uniformity, defects, or markings.The invention also provides novel siloxane polymers containing fluorene uvaphores which are useful in the coating comopsition of the invention.

Abstract: Devices for and method of generating coherent second harmonic light radiation. The devices comprise a laser source of coherent light radiation at a fixed fundamental frequency, a crystalline N-aryl carbamyl compound that crystallizes in a non-centrosymmetric configuration, means for directing the output radiation of the laser onto the crystalline chiral N-aryl carbamyl compound, and output means for utilizing the second harmonic frequency.

Abstract: Durable, specularly reflective mirrors for solar reflectors or fluorescent lamp fixtures are formed by vapor-depositing silver on a polyester film and protectively covering it with a coating of transparent acrylate polymer containing a silver corrosion inhibitor such as glycol dimercaptoacetate. In a preferred embodiment a pressure-sensitive mounting adhesive is applied to the opposite face of the polyester film. Degradation of the polyester, and consequent bubbling of the adhesive, is reduced or eliminated by incorporating UV absorber in acrylate polymer that is applied as a second protective coating.

Abstract: Imaging systems comprising a tetra(hydrocarbyl)borate and a bleachable dye may be rendered desensitizable by the inclusion of a second bleachable dye which absorbs radiation in a different portion of the electromagnetic spectrum than the first bleachable dye.

Abstract: A method for forming an image includes the step of desensitizing a radiation sensitive imaging system comprising a dye and a tetra (hydrocarbyl) borate in a binder by converting the tetra (hydrocarbyl) borate to a compound having fewer than four carbon-to-boron bonds.