Patents by Inventor Gerardus Cornelis Overbeek

Gerardus Cornelis Overbeek has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11001663
    Abstract: The present invention relates to an aqueous dispersion comprising dispersed particles of an acrylic copolymer having a volume average particle size diameter (d50) of from 1 to 50 ?m (microns), wherein the aqueous dispersion further comprises (i) an acrylic copolymer dispersant having an alkaline solubility higher than 50 wt. %, and being present in the dispersion in an amount of from 10 to 35% by weight, relative to the total amount of monomers used to prepare the acrylic copolymer of the dispersed polymeric particles; and (ii) decomposition products of an oil-soluble organic initiator.
    Type: Grant
    Filed: October 17, 2017
    Date of Patent: May 11, 2021
    Assignee: DSM IP ASSETS B.V.
    Inventors: Adrianus Antonius Johannes Van Geel, Franciscus Adrianus Johannes Suykerbuyk, Gerardus Cornelis Overbeek, Jurgen Scheerder
  • Publication number: 20210087427
    Abstract: Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol.
    Type: Application
    Filed: December 1, 2020
    Publication date: March 25, 2021
    Inventors: Roel Johannes Marinus SWAANS, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Paul de KOK
  • Publication number: 20210079209
    Abstract: The present invention relates to a waterborne dispersion comprising (A) amphiphilic block copolymer obtained with a controlled radical polymerization process and comprising at least blocks [A] and [B], whereby block [A] comprises ethylenically unsaturated monomer(s) bearing water-soluble and/or water-dispersible functional groups (monomer(s) (i)), and block [B] comprises ethylenically unsaturated monomer(s) different from monomer(s) (i) (monomer(s) (ii)); and (B) polymer P comprising ethylenically unsaturated monomer(s) different from (i) (monomer(s) (ii)), characterized in that the amount of block copolymer is higher than 1 and lower than 30 wt. %, based on the total weight of monomers used to prepare the block copolymer and polymer P; the acid value of the composition consisting of block copolymer and polymer P is higher than 1 and at most 35 mg KOH per g of the block copolymer-polymer P composition; the block copolymer has a calculated glass transition temperature of higher than 10° C.
    Type: Application
    Filed: December 18, 2018
    Publication date: March 18, 2021
    Inventors: Michael Arnoldus Jacobus SCHELLEKENS, Johannes Hendrikus DE BONT, John BARBOSA, Jon Andrew CRONIN, Charles SHEARER, Matthew Stewart GEBHARD, Gerardus Cornelis OVERBEEK
  • Publication number: 20210070977
    Abstract: The present invention further relates to a waterborne dispersion comprising (A) polymer P; (B) amphiphilic block copolymer obtained with a controlled radical polymerization process and comprising at least blocks [A] and [B], whereby block [A] comprises ethylenically unsaturated monomer(s) bearing water-soluble and/or water-dispersible functional groups (monomer(s) (i)), and block [B] comprises ethylenically unsaturated monomer(s) different from monomer(s) (i) (monomer(s) (ii)); and (C) crosslinker, characterized in that the polymer P is crosslinkable and comprises ethylenically unsaturated monomer(s) bearing crosslinkable functional groups different from monomer(s) (i) and monomer(s) (ii) (monomer(s) (iii)) in an amount of from 1 to 10 wt. %, based on the total weight of monomers used to prepare the polymer P, the amount of lock copolymer is higher than 1 wt. % and lower than 30 wt.
    Type: Application
    Filed: December 18, 2018
    Publication date: March 11, 2021
    Inventors: Michael Arnoldus Jacobus SCHELLEKENS, Johannes Hendrikus DE BONT, John BARBOSA, Jon Andrew CRONIN, Charles SHEARER, Matthew Stewart GEBHARD, Gerardus Cornelis OVERBEEK
  • Patent number: 10883015
    Abstract: Aqueous coating compositions include dispersed polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane. The polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, and the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt. % of at least one active-hydrogen chain extending compound with a functionality of at least 2 other than water, (e) from 0 to 10 wt. % of at least one diol having a molecular weight below 500 g/mol.
    Type: Grant
    Filed: August 15, 2019
    Date of Patent: January 5, 2021
    Assignee: DSM IP ASSETS B.V.
    Inventors: Roel Johannes Marinus Swaans, Ronald Tennebroek, Gerardus Cornelis Overbeek, Paul de Kok
  • Publication number: 20200317842
    Abstract: The present invention relates to an aqueous dispersion comprising dispersed particles of an acrylic copolymer having a volume average particle size diameter (d50) of from 1 to 50 ?m (microns), wherein the aqueous dispersion further comprises (i) an acrylic copolymer dispersant having an alkaline solubility higher than 50 wt. %, and being present in the dispersion in an amount of from 10 to 35% by weight, relative to the total amount of monomers used to prepare the acrylic copolymer of the dispersed polymeric particles; and (ii) decomposition products of an oil-soluble organic initiator.
    Type: Application
    Filed: October 17, 2017
    Publication date: October 8, 2020
    Inventors: Adrianus Antonius Johannes VAN GEEL, Franciscus Adrianus Johannes SUYKERBUYK, Gerardus Cornelis OVERBEEK, Jurgen SCHEERDER
  • Patent number: 10767072
    Abstract: The current invention relates to a process for preparing an aqueous binder composition free of organic solvent, the process comprising at least the following steps: A) preparing a hydrophilic vinyl polymer (Polymer A) by polymerisation of a monomer composition A that contains: Ai) at least one carboxylic acid functional olefinically unsaturated monomer; and Aii) at least one olefinically unsaturated monomer different than Ai); and Aiii) optionally at least one wet adhesion promoting olefinically unsaturated monomer different than Ai and Aii); where Polymer A has an acid value (AV) from 32 to 98 mg KOH/g of solid Polymer A; B) preparing a hydrophobic vinyl polymer (Polymer B) by emulsion polymerization of a monomer composition B in the presence of Polymer A where the monomer composition B contains: Bi) at least one olefinically unsaturated monomer; Bii) optionally carboxylic acid functional olefinically unsaturated monomer different than Bi); and Biii) optionally wet adhesion promoting olefinically unsaturated
    Type: Grant
    Filed: October 21, 2015
    Date of Patent: September 8, 2020
    Assignee: DSM IP ASSETS B.V.
    Inventors: Tijs Nabuurs, Willem-Jan Soer, Gerardus Cornelis Overbeek
  • Publication number: 20200239731
    Abstract: The present invention relates to a radiation-curable aqueous coating composition comprising a polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least two cyclic groups, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has from 4 to 36 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and optionally radiation-curable diluent; whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1; and whereby the ethylenically unsaturated bond concentration of the coating composition is in the range from 0.5 to 6 milliequivalents per g of polyurethane A and radiation-curable diluent.
    Type: Application
    Filed: February 7, 2018
    Publication date: July 30, 2020
    Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN
  • Publication number: 20200207994
    Abstract: The current invention relates to an one-pack aqueous coating composition comprising dispersed carbonyl functional vinyl polymer(s) particles, characterized in that the coating composition further comprises carbodihydrazide, whereby (i) the equivalent molar ratio of hydrazide groups to carbonyl groups is from 0.1 to 0.95, (ii) the ratio of number-average molecular weight of the carbonyl functional vinyl polymer(s) to acid value of the carbonyl functional vinyl polymer(s) is higher than 400, and (iii) the acid value of the carbonyl functional vinyl polymer(s) is from 2 to 100 mg KOH/gram carbonyl functional vinyl polymer.
    Type: Application
    Filed: July 16, 2018
    Publication date: July 2, 2020
    Inventors: Gerardus Cornelis OVERBEEK, Alfred Jean Paul BÜCKMANN, Patrick Johannes Maria STALS, Daan VAN DER ZWAAG, Jurgen SCHEERDER, Stella Josette VAN DIJK
  • Publication number: 20200095460
    Abstract: The present invention relates to an aqueous coating composition comprising polyurethane A and vinyl polymer, wherein the polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least one cyclic group, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has 5 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1.
    Type: Application
    Filed: February 7, 2018
    Publication date: March 26, 2020
    Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN, Jacobus Willem GRIFFIOEN
  • Publication number: 20200024474
    Abstract: The present invention relates to a radiation-curable aqueous coating composition comprising a polyurethane A comprising as building blocks at least: (a) a polyisocyanate(s) containing at least one cyclic group, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has 5 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and optionally radiation-curable diluent; whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1; and whereby the ethylenically unsaturated bond concentration of the coating composition is in the range from 0.5 to 6 milliequivalents per g of polyurethane A and radiation-curable diluent.
    Type: Application
    Filed: February 7, 2018
    Publication date: January 23, 2020
    Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN, Jacobus Willem GRIFFIOEN
  • Publication number: 20200024473
    Abstract: The present invention relates to an aqueous coating composition comprising polyurethane A and vinyl polymer, wherein the polyurethane A comprises as building blocks at least: (a) a polyisocyanate(s) containing at least two cyclic groups, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has from 4 to 36 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1.
    Type: Application
    Filed: February 7, 2018
    Publication date: January 23, 2020
    Inventors: Ilse VAN CASTEREN, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Jourraine CELESTIJN
  • Publication number: 20190367772
    Abstract: The present invention relates to an aqueous coating composition comprising dispersed polymer particles, wherein (i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane, (ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, (iii) the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt.
    Type: Application
    Filed: August 15, 2019
    Publication date: December 5, 2019
    Inventors: Roel Johannes Marinus SWAANS, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Paul de KOK
  • Publication number: 20190367644
    Abstract: The present invention relates to an aqueous emulsion comprising at least 30 wt. % of vinyl copolymer(s) (A), said vinyl copolymer(s) (A) containing the following monomers: (I) isobornyl methacrylate and 2-octyl acrylate in a summed amount of at least 30 wt. %, in a weight ratio of isobornyl methacrylate to 2-octyl acrylate from 5:95 to 95:5; (II) no more than 70 wt. % of at least one ethylenically unsaturated monomer other than 2-octyl acrylate and isobornyl methacrylate, whereby the summed amount of (I) and (II) is 100 wt. % and whereby the amount of vinyl copolymer(s) (A) is given relative to the total weight amount of binder present in the emulsion.
    Type: Application
    Filed: July 3, 2017
    Publication date: December 5, 2019
    Inventors: Tijs NABUURS, Maud KASTELIJN, Johannes Hendrikus DE BONT, Gerardus Cornelis OVERBEEK, Saskia Carolien VAN DER SLOT, Ronald TENNEBROEK, Addy MOLHOEK
  • Patent number: 10457763
    Abstract: The present invention relates to an aqueous polymer emulsion comprising at least 30 wt. % of a vinyl copolymer (A), said vinyl copolymer comprising: (I) from 10 to 90 wt. % of 2-octyl acrylate monomer; (II) from 10 to 90 wt. % of at least one itaconate ester monomer according to formula (1) in which A and B may be different or the same and A and B are independently an alkyl group or an aryl group; and (III) from 0 to 80 wt. % of ethylenically unsaturated monomer other than (I) and (II); whereby the summed amount of (I), (II) and (III) is 100 wt. % and whereby the amount of vinyl copolymer (A) is given relative to the total weight amount of the polymers present in the emulsion.
    Type: Grant
    Filed: February 12, 2016
    Date of Patent: October 29, 2019
    Assignee: DSM IP ASSETS B.V.
    Inventors: Tijs Nabuurs, Jeffrey Stubbs, Johannes Hendrikus De Bont, Gerardus Cornelis Overbeek
  • Patent number: 10428237
    Abstract: The present invention relates to an aqueous coating composition comprising dispersed polymer particles, wherein (i) the dispersed polymer particles are polyurethane-vinyl polymer hybrid particles obtained by free-radical polymerization of at least one vinyl monomer in the presence of a polyurethane, (ii) the polyurethane and the vinyl polymer in the hybrid particles are present in a weight ratio of polyurethane to vinyl polymer ranging from 1:1 to 20:1, (iii) the polyurethane is the reaction product of at least the following components: (a) from 5 to 40 wt. % of at least one organic difunctional isocyanate, (b) from 0.5 to 4 wt. % of an isocyanate-reactive compound containing ionic or potentially ionic water-dispersing groups having a molecular weight of from 100 to 500 g/mol, (c) from 40 to 80 wt. % of at least one diol having a molecular weight from 500 to 5000, (d) from 0 to 10 wt.
    Type: Grant
    Filed: December 22, 2015
    Date of Patent: October 1, 2019
    Assignee: DSM IP ASSETS B.V.
    Inventors: Roel Johannes Marinus Swaans, Ronald Tennebroek, Gerardus Cornelis Overbeek, Paul De Kok
  • Publication number: 20190211158
    Abstract: The present invention relates to a dispersion comprising (A) a carrier fluid in an amount from 35 to 95 wt. %, the carrier fluid comprising: (A1) water, and (A2) at least one compound selected from the group consisting of ethanol, 1-propanol, 2-propanol, ethyl acetate, n-propyl acetate, isopropyl acetate, acetone, methyl ethyl ketone and any mixture of at least two of these compounds, whereby the amount of water (A1) relative to the carrier fluid (A) is less than 85 wt. % and the amount of water relative to the dispersion is from 1 to 30 wt. %; and (B) polymer(s) in an amount from 5 to 65 wt.
    Type: Application
    Filed: September 12, 2017
    Publication date: July 11, 2019
    Inventors: Roel Johannes Marinus SWAANS, Matthew Stewart GEBHARD, Ronald TENNEBROEK, Gerardus Cornelis OVERBEEK, Koen BIEMANS, Paulus Johannes Maria HÖNEN, Petrus Johannes Maria VAN OORSCHOT
  • Patent number: 10336853
    Abstract: There is described a low number average molecular weight (MN<10 kD) and high glass transition temperature (>75° C.) copolymer (optionally a solid grade oligomer (SGO)) that comprises (a) at least 20 wt-% of itaconate functional monomer(s), (b) not more than 40% of a hydrophilic monomer, preferably an acid functional monomer(s) in an amount sufficient to achieve an acid value from 65 to 325 mg KOH per g of solid polymer; (c) optionally not more than 70% of other monomers not being either (a) or (b), having a max content of vinyl aromatic monomer(s) of 40 wt-% and/or max content of methacrylate(s) of 40 wt-%; where the weight percentages of monomers (a), (b) and (c) are calculated as a proportion of the total amount of monomers in the copolymer being 100%.
    Type: Grant
    Filed: November 14, 2017
    Date of Patent: July 2, 2019
    Assignee: DSM IP ASSETS B.V.
    Inventors: Tijs Nabuurs, Yvonne Wilhelmina Smak, Gerardus Cornelis Overbeek
  • Patent number: 10167408
    Abstract: An aqueous polymer composition which when in the form of a film shows excellent elongation at break comprising (i) 5 to 30 wt. % of polyurethane where the acid value of the polyurethane is between 3 to 40 mg KOH/g; (ii) 70 to 95 wt. % of vinyl polymer comprising 20 to 90 wt. % of vinyl polymer with Tg<20° C.; 10 to 80 wt. % of vinyl polymer with Tg?20° C.; where at least one of the vinyl polymers contains acid functional groups with acid value in the range of from 15 and 240 mg KOH/g.
    Type: Grant
    Filed: April 23, 2015
    Date of Patent: January 1, 2019
    Assignee: DSM IP ASSETS B.V.
    Inventors: Rajasingham Satgurunathan, Jurgen Scheerder, Gerardus Cornelis Overbeek, Roel Johannes Marinus Swaans, Ronald Tennebroek, Tijs Nabuurs, Maud Kastelijn, Hinrike Malda
  • Publication number: 20180118933
    Abstract: The present invention relates to an aqueous dispersion comprising (i) dispersed particles of vinyl polymer having a volume average particle size diameter (D50) of from 1 to 30 ?m (microns); (ii) a partially hydrolysed vinyl acetate (co)polymer in an amount of from 2% to 30% by weight, relative to the total amount of monomers used to prepare the vinyl polymer(s) of the dispersed polymeric particles; and (iii) decomposition products of an oil-soluble organic initiator; wherein at least 95 wt. % of the partially hydrolysed vinyl acetate (co)polymer that is present in the aqueous dispersion has a weight average molecular weight Mw from 25 to 500 kDalton and a hydrolysis degree of from 70 to 95 mol %.
    Type: Application
    Filed: April 16, 2016
    Publication date: May 3, 2018
    Inventors: Adrianus Antonius Johannes VAN GEEL, Franciscus Adrianus Johannes SUYKERBUYK, Rajasingham SATGURUNATHAN, Gerardus Cornelis OVERBEEK, Johannes VAN HILST