Abstract: The invention relates to a radiation curable composition for additive-manufacturing processes, the composition comprising (meth)acrylate component(s) not comprising an urethane moiety having a molecular weight Mw of at least 1,000 as Component A1, photo initiator as Component B, red, yellow or orange dye or combination thereof as Component C, blue dye having a light absorption band in the range of 350 to 420 nm as Component D, and optionally stabilizer as Component E. The invention further relates to a process of producing an elastomeric 3-dim article from the radiation curable composition in an additive-manufacturing process and the obtained elastomeric 3-dim article.

Abstract: The invention relates to a coloured curable composition for use in an additive manufacturing process, the composition comprising a curable resin composition comprising radiation curable components, a photo initiator, a dye composition comprising a dye D1 and a dye D2, dye D1 having a light absorption maximum within a wave length range from 400 to 530 nm, dye D2 showing a light absorption maximum within a wave length range from 540 to 650 nm. The invention also relates to a 3-dim composite article obtained by processing the curable composition in an additive manufacturing process.

Abstract: A process of producing a surface-modified 3-dimensional article, the process comprising the steps of providing a radiation-curable composition, building-up a 3-dimensional article by radiation-curing the radiation-curable composition layer by layer, preferably by using a stereolithography or digital light processing unit, partially removing radiation-curable composition which sticks to the surface of the 3- dimensional article, treating only a portion of the surface of the 3- dimensional article to which the radiation-curable composition is stuck with particles, applying an additional curing step to the 3-dimensional article, preferably by applying heat and/or radiation. A 3-dimensional article which can be obtained by such a process and a kit of parts comprising such a 3-dimensional article.

Abstract: An additive manufacturing system has a light permeable base, a build carrier for holding a workpiece and a light source which is arranged to emit light through the light permeable base. The light permeable base and the build carrier are positionable relative to each other in a build dimension in which the workpiece is built up. The system further has a resin vat in which the light permeable base forms a wall portion thereof. The system further comprises a plurality of resin supplies for supplying different light hardenable resins in direct contact with each other in said vat. The system facilitates the rapid manufacturing of a dental restoration having a color gradation.

Abstract: The invention relates to a preformed dental composite crown being characterized by its shape and chemical composition, the shape being characterized as follows: having an occlusal top surface and depending buccal, mesial, distal and lingual side surfaces, the side surfaces being connected to each other and forming a crown cervix, the wall thickness of the crown at the crown cervix being lower than 0.6 mm; at least two of opposing depending side surfaces having a concave shape; the chemical composition of the material the preformed dental composite crown is made of being a hardened composition comprising the following components: nano-filler(s) in an amount from 20 to 70 wt. %, resin matrix in an amount from 20 to 75 wt. %, wt. % with respect to the weight of the chemical composition, the resin matrix comprising urethane(meth)acrylate(s) and (meth)acrylate(s) not comprising a urethane moiety.

Abstract: A method of making a physical object by additive manufacturing. In the method a hardenable primary material is provided, the object is built up by successively hardening layers of the hardenable primary material, and the object is cleaned from excess material by moving the object and thereby generating a mass inertial force in the excess material. The invention facilitates the making of objects by additive manufacturing.

Abstract: The present disclosure provides a build platform for use in an additive manufacturing device that is builds up an object from layers of a light-hardenable resin, wherein the build platform comprises a build surface for building up the object thereon, and wherein the build surface comprises a ceramic material. The disclosure also provides a method of making a build surface comprises a ceramic surface. Further, the disclosure provides additive manufacturing devices that include build platforms comprising ceramic material. The disclosure also describes articles made using the methods and devices described.

Abstract: A device for progressively building up an object from a light hardenable material. The device has a perforated build platform for the object. The build platform forms a build surface that faces a light source. The build platform and the light source are positionable relative to each other by computer control. The device is further configured for supplying the light hardenable material through the perforation of the build platform for building up the object. The invention enables the making of colored objects by stereolithography.

Abstract: A method of making a dental article, has steps of (i) providing a layer of sinter powder, (ii) providing a solidifiable binder to form a circumferential fixation zone (114) which encloses a portion of the powder layer. The method further has the step of repeating steps (i) and (ii) with each fixation zone (114) of one layer being in contact with a fixation zone (114) of an adjacent layer such that a plurality of the fixation zones (114) together form a coherent hollow sleeve (116) extending across the layers. The corresponding plurality of powder portions in combination form a contiguous batch (118) of powder captured in the sleeve. The method facilitates the manufacturing of sintered dental articles.

Abstract: A method of building up at least a first (10) and a second (20) physical workpiece from a light hardenable material (105) on a 3D printing device (100). The method has the steps of providing to the 3D printing device a first dataset for building up a first workpiece; starting a first print job based on the first dataset; providing to the same 3D printing device a second dataset for building up a second workpiece after the start the first print job; and starting a second print job based on the second dataset before finishing the first print job.

Abstract: A method of building up a physical object by additive manufacturing which has the steps of building up the object and at least one support structure layer by layer along a build axis. The support structure supports the object relative to a build platform. During building up the object and the at least one support structure a connection is provided between the support structure and the object by a plurality of layers each of which being a common layer of the object and the support structure.

Abstract: An additive manufacturing system has a light permeable base, a build carrier for holding a workpiece and a light source which is arranged to emit light through the light permeable base. The light permeable base and the build carrier are positionable relative to each other in a build dimension in which the workpiece is built up. The system further has a resin vat in which the light permeable base forms a wall portion thereof. The system further comprises a plurality of resin supplies for supplying different light hardenable resins in direct contact with each other in said vat. The system facilitates the rapid manufacturing of a dental restoration having a color gradation.

Abstract: An additive manufacturing system has a light permeable base (2), a build carrier (4) for holding a workpiece (100) and a light source (5) which is arranged to emit light through the light permeable base (2). The light permeable base (2) and the build carrier (4) are positionable relative to each other in a build dimension in which the workpiece (100) is built up. The system further has a resin vat (3) in which the light permeable base (2) forms a wall portion thereof. The system further comprises a plurality of resin supplies (13, 15) for supplying different light hardenable resins in direct contact with each other in said vat (3). The system facilitates the rapid manufacturing of a dental restoration having a color gradation.

Abstract: The present invention relates to a kit of parts comprising Part A and Part B, Part A comprising: ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, optionally polymerizable component(s) without acidic moieties, optionally polymerizable component(s) with acidic moieties, and optionally filler(s), Part B comprising polymerizable component(s) without acidic moieties, polymerizable component(s) with acidic moieties, transition metal component(s), organic peroxide(s), and optionally filler(s), The invention is also directed to a redox initiator system comprising ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, transition metal component(s), preferably comprising a copper or iron ion containing salt, organic peroxide(s), preferably comprising a hydroperoxide or di-peroxide. The kit of parts and redox initiator system are particularly useful in the dental field.

Abstract: The invention relates to a dental composition comprising a resin matrix, a filler matrix in an amount of at least 25 wt. % with respect to the weight of the dental composition, an initiator system, the resin matrix comprising polymerizable monomer(s) comprising two (meth)acrylate moieties connected to a brominated resorcinol, catechol, tyrosol, benzoic acid or phenol moiety. The invention relates also to a dental milling block comprising this composition in its hardened stage.

Abstract: The invention relates to a dental composition comprising a resin matrix, a filler matrix in an amount of at least 25 wt. % with respect to the weight of the dental composition, an initiator system, the resin matrix comprising polymerizable monomer(s) comprising two (meth)acrylate moieties connected to a brominated resorcinol, catechol, tyrosol, benzoic acid or phenol moiety. The invention relates also to a dental milling block comprising this composition in its hardened stage.

Abstract: A method of making a physical object by additive manufacturing. The method has the steps of providing a light hard-enable primary material (11), building up the object (100) by successively hardening portions of the light hardenable primary material (11) by irradiating the portions with light, coating at least a part of the object (100) with a light permeable coating or oxygen protective material; and irradiating the coated object (100) with light and thereby post-hardening any light hardenable material (11).

Abstract: A method of making a physical object by additive manufacturing. In the method a hardenable primary material is provided, the object is built up by successively hardening layers of the hardenable primary material, and the object is cleaned from excess material by moving the object and thereby generating a mass inertial force in the excess material. The invention facilitates the making of objects by additive manufacturing.

Abstract: The invention relates to a preformed dental composite crown being characterized by its shape and chemical composition, the shape being characterized as follows: having an occlusal top surface and depending buccal, mesial, distal and lingual side surfaces, the side surfaces being connected to each other and forming a crown cervix, the wall thickness of the crown at the crown cervix being lower than 0.6 mm; at least two of opposing depending side surfaces having a concave shape; the chemical composition of the material the preformed dental composite crown is made of being a hardened composition comprising the following components: nano-filler(s) in an amount from 20 to 70 wt. %, resin matrix in an amount from 20 to 75 wt. %, wt. % with respect to the weight of the chemical composition, the resin matrix comprising urethane(meth)acrylate(s) and (meth)acrylate(s) not comprising a urethane moiety.

Abstract: The invention relates to A curable composition for producing dental composite crowns, the composition comprising a resin matrix comprising polymerizable (meth)acrylate(s) not comprising a urethane moiety, polymerizable urethane(meth)acrylate(s), wherein the polymerizable (meth)acrylate(s) not comprising an urethane moiety are used in excess over the polymerizable urethane(meth)acrylate(s), a filler matrix comprising nanocluster(s), fumed silica in an amount below 8 wt. % with respect to the weight of the whole composition, an initiator system comprising photoinitiator(s), organic dye(s), the curable composition not comprising softener in an amount of more than 5 wt. % with respect to the weight of the whole composition, the curable composition having a viscosity below 150 Pa*s at 23° C. and a shear rate of 1 s?1. The invention also relates to a cured article obtained by radiation curing this curable composition by use of an additive-manufacturing method.