Patents by Inventor Hans-Dieter Hille

Hans-Dieter Hille has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7531614
    Abstract: Water-thinnable polyurethane with at least two free OH groups obtainable from a first conversion of a primary and/or secondary alkanolamine with a NCO compound giving an intermediate product, followed by the addition of a cyclic carboxylic anhydride to the intermediate product; with the NCO compound exhibiting at least one free NCO group and no blocked NCO group; all alkanolamine being converted during the first conversion to the intermediate product such that the nitrogen atom of the alkanolamine reacts with one of the free NCO groups of the prepolymer to form a urea bond; and the cyclic carboxylic anhydride reacting, with ring opening, with the OH group, originating from the alkanolamine, of the intermediate product; and its use for the production of hot curing coating compositions.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: May 12, 2009
    Assignee: PPG Industries Ohio Inc.
    Inventors: Hans-Dieter Hille, Karsten Jahny, Paul Lamers
  • Publication number: 20090004397
    Abstract: This invention relates to a method of coating a motor vehicle body including (i) applying as a first layer an electro-dip primer coat; (ii) mixing a water dilutable compensation paint comprising 40 to 80 wt. % binders and a commercial base coat to obtain a mixture, and applying the mixture as a second primer surface layer on said primer coat wherein the primer surface layer applied has a thickness of from 10 to 20 ?m; (iii) applying a third layer consisting of a water soluble base coat; and (iv) applying a covering layer of clear coat.
    Type: Application
    Filed: May 5, 2008
    Publication date: January 1, 2009
    Inventor: Hans-Dieter Hille
  • Publication number: 20050154177
    Abstract: Water-thinnable polyurethane with at least two free OH groups obtainable from a first conversion of a primary and/or secondary alkanolamine with a NCO compound giving an intermediate product, followed by the addition of a cyclic carboxylic anhydride to the intermediate product; with the NCO compound exhibiting at least one free NCO group and no blocked NCO group; all alkanolamine being converted during the first conversion to the intermediate product such that the nitrogen atom of the alkanolamine reacts with one of the free NCO groups of the prepolymer to form a urea bond; and the cyclic carboxylic anhydride reacting, with ring opening, with the OH group, originating from the alkanolamine, of the intermediate product; and its use for the production of hot curing coating compositions.
    Type: Application
    Filed: March 25, 2003
    Publication date: July 14, 2005
    Inventors: Hans-Dieter Hille, Karsten Jahny, Paul Lamers
  • Patent number: 6770702
    Abstract: Polymer obtainable by a multistage polymerization process which involves conducting, in a first step, an aqueous-phase polymerization of at least one ethylenically monofunctional compound alone or together with at least one ethylenically difunctional or poly-functional compound together in the presence of a polyesterpolyol, polyurethane and/or polyacrylate; and, in a subsequent step, a reaction of the resulting product with at least one ethylenically monofunctional compound alone or together with at least one ethylenically difunctional or polyfunctional compound; followed by a reaction of the resulting product with a crosslinker; and its use.
    Type: Grant
    Filed: April 16, 2002
    Date of Patent: August 3, 2004
    Assignee: PPG Industries Lacke GmbH
    Inventors: Horst Muller, Hans-Dieter Hille
  • Patent number: 6582822
    Abstract: An aqueous coating composition is provided which includes crosslinkable film-forming resin and about 0.01 to about 25 weight percent on a basis of total resin solids of an amphiphilic adjuvant having an acid value of less than 30, a water-soluble polar end including at least one terminal hydroxyl group and a water-insoluble hydrocarbon end including at least seven contiguous carbon atoms. The coating composition is useful as a monocoat or primer, basecoat or clearcoat in a multi-component composite coating composition for automotive applications.
    Type: Grant
    Filed: August 9, 2001
    Date of Patent: June 24, 2003
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Dennis L. Faler, Djurdjica Glas, Hans-Dieter Hille, Michael Jäger, Walter Metzger, Kurt G. Olson, Edward S. Pagac, Daniel E. Rardon, Shanti Swarup
  • Patent number: 6559220
    Abstract: The invention relates to the preparation of a water-dilutable stone impact protection and of a compensation paint and its use and processes for their production, especially in the automobile industry. The water-dilutable stone impact protection paint contains 20 to 60 wt % binder and 2 to 10 wt % pigments and possibly uncoagulated overspray of water-soluble base paints and the compensation paint contains 40 to 80 wt % binder.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: May 6, 2003
    Assignee: Bollig & Kemper GmbH & Co. KG
    Inventor: Hans-Dieter Hille
  • Patent number: 6538059
    Abstract: Polymer obtainable by a multistage polymerization process which involves conducting, in a first step, an aqueous-phase polymerization of at least one ethylenically monofunctional compound alone or together with at least one-ethylenically difunctional or poly-functional compound together in the presence of a polyesterpolyol, polyurethane and/or polyacrylate; followed by a reaction of the resulting product with a crosslinker; and its use.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: March 25, 2003
    Assignee: PPG Industries Lacke GmbH
    Inventors: Horst Muller, Hans-Dieter Hille
  • Publication number: 20030040567
    Abstract: Disclosed is the preparation of a water-dilutable stone impact protection and of a compensation paint and its use and processes for their production, especially in the automobile industry. The water-dilutable stone impact protection paint contains 20 to 60 wt % binder and 2 to 10 wt % pigments and possibly uncoagulated overspray of water-soluble base paints and the compensation paint contains 40 to 80 wt % binder.
    Type: Application
    Filed: July 24, 2002
    Publication date: February 27, 2003
    Applicant: Bollig & Kemper
    Inventor: Hans-Dieter Hille
  • Patent number: 6472465
    Abstract: Coating composition obtainable by mixing a) a composition A containing a dispersion of a polyurethane having an acid number of more than 20 and comprising as its soft segment at least one polytetrahydrofuran segment having a number-average molecular weight of between 650 and 5000 and as its hard segment at least one segment derived from a diisocyanate; with b) a composition B containing a dispersion of a polyurethane having an acid number of less than 20 and comprising as its soft segment at least one polytetrahydrofuran segment having a number-average molecular weight of between 800 and 5000 and as its hard segment at least one segment derived from a diisocyanate.
    Type: Grant
    Filed: December 3, 1999
    Date of Patent: October 29, 2002
    Assignee: Bollig & Kemper
    Inventors: Hans-Dieter Hille, Horst Müller
  • Publication number: 20020013400
    Abstract: The invention relates to the preparation of a water-dilutable stone impact protection and of a compensation paint and its use and processes for their production, especially in the automobile industry. The water-dilutable stone impact protection paint contains 20 to 60 wt % binder and 2 to 10 wt % pigments and possibly uncoagulated overspray of water-soluble base paints and the compensation paint contains 40 to 80 wt % binder.
    Type: Application
    Filed: March 22, 1996
    Publication date: January 31, 2002
    Inventor: HANS-DIETER HILLE
  • Publication number: 20020010260
    Abstract: An aqueous coating composition is provided which includes crosslinkable film-forming resin and about 0.01 to about 25 weight percent on a basis of total resin solids of an amphiphilic adjuvant having an acid value of less than 30, a water-soluble polar end including at least one terminal hydroxyl group and a water-insoluble hydrocarbon end including at least seven contiguous carbon atoms. The coating composition is useful as a monocoat or primer, basecoat or clearcoat in a multi-component composite coating composition for automotive applications.
    Type: Application
    Filed: August 9, 2001
    Publication date: January 24, 2002
    Inventors: Dennis L. Faler, Djurdjica Glas, Hans-Dieter Hille, Michael Jager, Walter Metzger, Kurt G. Olson, Edward S. Pagac, Daniel E. Rardon, Shanti Swarup
  • Patent number: 6291564
    Abstract: An aqueous coating composition is provided which includes crosslinkable film-forming resin and about 0.01 to about 25 weight percent on a basis of total resin solids of an amphiphilic adjuvant having an acid value of less than 30, a water-soluble polar end including at least one terminal hydroxyl group and a water-insoluble hydrocarbon end including at least seven contiguous carbon atoms. The coating composition is useful as a monocoat or primer, basecoat or clearcoat in a multi-component composite coating composition for automotive applications.
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: September 18, 2001
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Dennis L. Faler, Djurdjica Glas, Hans-Dieter Hille, Michael Jäger, Walter Metzger, Kurt G. Olson, Edward S. Pagac, Daniel E. Rardon, Shanti Swarup
  • Patent number: 6043301
    Abstract: The invention relates to aqueous coating compositions comprising:an aqueous, polyester- and acrylate-based polymer dispersion obtainable by free-radical polymerization of at least:a. one (meth)acrylic acid ester;b. one ethylenically unsaturated, at least monofunctional acid; and optionallyc. one ethylenically unsaturated monomer other than (a) and (b)or mixtures thereof, with a poly ester resin capable of undergoing a free-radical polymerization;one amino resin as crosslinking agent,one water-soluble and/or water-emulsifiable polyalcohol and optionally conventional laquer additives.Furthermore, the invention relates to the use of these aqueous coating compositions as clear coats for the preparation of multi-layer coatings.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: March 28, 2000
    Inventors: Hans-Dieter Hille, Horst Muller
  • Patent number: 5977258
    Abstract: A microgel obtained by polymerizing in aqueous phase a monomer blend comprising at least one ethylenic monofunctional compound, selected from the group consisting of vinylic compounds, alkyl esters of acrylic or methacrylic acid, hydroxyalkyl (meth)acrylates and vinyl acetate, and at least one ethylenic di- or multifunctional compound, selected from the group consisting of diacrylates, triacrylates and/or (meth)acrylates of polyfunctional alcohols, in the presence of a polycondensation product of a polycarboxylic acid, polyhydroxycarboxylic acid, hydroxypolycarboxylic acid and/or polyhydroxypolycarboxylic acid with a polyol, and its use for aqueous or solvent-containing coating compositions, in particular for aqueous or solvent-containing base coats, effect base coats or clear coat systems in the motorcar industry.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: November 2, 1999
    Assignee: Bollig & Kemper KG
    Inventors: Hans-Dieter Hille, Stephan Neis, Horst Muller
  • Patent number: 5648410
    Abstract: The invention relates to an aqueous polyester- and acrylate-based polymer dispersion, obtainable by free radical-initiated polymerization of at least(a) one (meth)acrylic acid ester,(b) one ethylenically unsaturated, at least monofunctional acid, and optionally(c) one ethylenically unsaturated monomer other than (a) and (b),or mixtures thereof with a polyester resin capable of undergoing a free radical-initiated polymerization. The invention further relates to the production of these aqueous polymer dispersions, to aqueous clear coat compositions containing said dispersions, and to the use thereof.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 15, 1997
    Assignee: Bollig & Kemper KG
    Inventors: Hans Dieter Hille, Horst Muller
  • Patent number: 5512322
    Abstract: The invention relates to a basecoat/clearcoat process in which the basecoat composition used contains as a film former a polyurethane resin which can be prepared by preparing an intermediate from(A) a mixture obtained from 10 to 90 mol % of linear polyether diols and 90 to 10 mol % of polyester diols,(B) diisocyanates,(C) compounds which contain two groups reactive toward isocyanate groups, at least some of these compounds having at least one group capable of forming anions,and the free isocyanate groups of the said intermediate are then reacted with(D) polyols containing at least three hydroxyl groups, and the reaction product obtained in this manner is transferred into an aqueous base, whereina) the polyester diol is prepared from diols and an acid component which consists of 60 to 100% by weight of aliphatic dicarboxylic acids of more than 18 carbon atoms and of 40 to 0% by weight of aliphatic dicarboxylic acids of 2 to 18 carbon atoms,b) the equivalent ratio of the NCO groups to the total of the OH groups
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: April 30, 1996
    Assignee: BASF Lacke & Farben Akt.
    Inventors: Hans-Dieter Hille, Stefan C. Wieditz, Arnold Dobbelstein, Horst Muller
  • Patent number: 5412023
    Abstract: The invention relates to aqueous dispersions of cross-linked polymer microparticles, prepared in an aqueous medium from a polymer, optionally dissolved in an organic solvent, said polymer bearing at least two hydroxyl groups and comprising a number of ionic groups sufficient for the formation of a stable aqueous dispersion, as the component (A) and one further component (B) at an elevated temperature, characterized in that component (A) is a polyesterpolyol, a polyurethane or a polyacrylate having an acid value of from 5 to 168, and that component (B) is an aminoplast resin consisting of molecules containing at least two reactive groups consisting of hydroxyl and/or amino and/or ether groups, that the ratio by weight of component (A) to component (B) is between 30:70 and 95:5, and that the dispersion is stable and usable in water and/or an organic solvent or mixtures thereof.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: May 2, 1995
    Assignee: Bollig & Kemper KG
    Inventors: Hans-Dieter Hille, Matthias Massone
  • Patent number: 5370910
    Abstract: The invention relates to a basecoat/clearcoat process in which the basecoat composition used contains as a film former a polyurethane resin which can be prepared by preparing an intermediate from(A) a mixture obtained from 10 to 90 mol % of linear polyether diols and 90 to 10 mol % of polyester diols,(B) diisocyanates,(C) compounds which contain two groups reactive toward isocyanate groups, at least some of these compounds having at least one group capable of forming anions, and the free isocyanate groups of the said intermediate are then reacted with(D) polyols containing at least three hydroxyl groups, and the reaction product obtained in this manner is transferred into an aqueous base, whereina) the polyester diol is prepared from diols and an acid component which consists of 60 to 100 % by weight of aliphatic dicarboxylic acids of more than 18 carbon atoms and of 40 to 0 % by weight of aliphatic dicarboxylic acids of 2 to 18 carbon atoms,b) the equivalent ratio of the NCO groups to the total of the OH gro
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: December 6, 1994
    Assignee: BASF Lacke + Farben AG
    Inventors: Hans-Dieter Hille, Stefan C. Wieditz, Arnold Dobbelstein, deceased, Horst Muller
  • Patent number: 5210154
    Abstract: The invention relates to water-thinnable baking paints, the use thereof as filler material and intermediate stone chip resistant coat as well as a process for painting motor vehicle bodies.The water-thinnable baking paints comprise as binders a combination of(I) 20 to 70% by weight of a water-thinnable polyurethane resin with an acid value of 15 to 35,(II) 20 to 70% by weight of an epoxy resin-modified water-thinnable polyester which can be prepared by reacting a polyester (A) with a molecular weight (number average) below 2000, an acid value of 35-240 and a hydroxyl value of 56-320, with 0.3 to 1.
    Type: Grant
    Filed: December 10, 1990
    Date of Patent: May 11, 1993
    Assignee: BASF Lacke + Farben Aktiengesellschaft
    Inventors: Klaus Weidemeier, Winfried Schmidt, Hans-Dieter Hille, Bodo Muller
  • Patent number: 5169922
    Abstract: The invention relates to coating compositions which are particularly suitable for the preparation of the basecoat for two-coat coatings of the basecoat/clearcoat type, and which comprise organic diluents, at least one resin containing urethane and urea groups, and, where appropriate, other resins, pigments and other conventional additives in common use.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: December 8, 1992
    Assignee: BASF Lacke + Farben AG
    Inventors: Hans-Dieter Hille, Arnold Dobbelstein, Horst Grosch