Patents by Inventor Heinrich Hartmann

Heinrich Hartmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5399286
    Abstract: Polyacetals useful as detergent additives contain units of the formula ##STR1## where R is hydrogen, C.sub.1 -C.sub.4 -alkyl or COOM,M is C.sub.1 -C.sub.4 -alkyl or an alkali metal, ammonium or alkanolamine group, andm is from 0 to 9,have K values (determined by the method of H. Fikentscher on the sodium salt in 1% strength by weight aqueous solution at 25.degree. C. and pH 7) of at least 8.5, and are prepared by polymerizing compounds of the formula ##STR2## where R is hydrogen, C.sub.1 -C.sub.4 -alkyl or COOM,M is C.sub.1 -C.sub.4 -alkyl or an alkali metal, ammonium or alkanolamine group,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, andm is from 0 to 9,in the presence of initiators and optionally comonomers with or without hydrolysis of the ester groups.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: March 21, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Hans-Peter Seelmann-Eggebert, Heinrich Hartmann, Richard Baur, Volker Schwendemann, Alexander Kud, Werner Bertleff
  • Patent number: 5374681
    Abstract: Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: December 20, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Richard Baur, Volker Schwendemann, Hans-Ulrich Jaeger, Johannes Perner
  • Patent number: 5352729
    Abstract: Pigment formulations containing(a) at least one finely divided pigment,(b) at least one copolymer obtainable by free radical polymerization of(.alpha..sub.1) C.sub.8 -C.sub.40 -monoolefins or(.alpha..sub.2) C.sub.8 -C.sub.40 -alkyl vinyl ethers or(.alpha..sub.3) a mixture of C.sub.8 -C.sub.40 -alkyl vinyl ethers and up to 50 mol % of C.sub.8 -C.sub.40 -monoolefins with(.beta.) monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids or C.sub.4 -C.sub.12 -dicarboxylic anhydridesand having a molecular weight of from 500 to 20,000 g/mol, some or all of whose carboxyl or anhydride groups may be reacted with ammnonia, amines, alcohols, amino- or hydroxycarboxylic acids or alkali metal or alkaline earth metal hydroxides, and(c) if required, further assistants conventionally used in pigment formulationsare used for the preparation of pastes, printing inks and coatings.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: October 4, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Hermann Birkhofer, Walter Denzinger, Heinrich Hartmann, Juan A. G. Gomez, Paul Guenthert, Joachim Jesse, Robert Kreuzer, Knut Oppenlaender, Reinhard U. Roth, Benno Sens
  • Patent number: 5346986
    Abstract: Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers are prepared by azeotropic dewatering of water-in-oil emulsions of water-soluble or water-swellable polymers in the presence of from 1 to 40% by weight, based on the polymers, of polyalkylene glycols which(a) are obtainable by an addition reaction of C.sub.2 -C.sub.4 -alkylene oxides with alcohols, phenols, amines or carboxylic acids and(b) contain not less than 2 polymerized alkylene oxide unitsand isolation of the agglomerated polymer particles. The water-soluble agglomerated polymer particles are used as flocculants and retention and drainage aids, while the water-swellable polymer powders are employed as thickeners for aqueous systems, in particular as thickeners for textile print pastes.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: September 13, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhard Schneider, Norbert Grund, Heinrich Hartmann
  • Patent number: 5334287
    Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: August 2, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
  • Patent number: 5330675
    Abstract: Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: July 19, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Richard Baur, Volker Schwendemann, Hans-Ulrich Jaeger, Johannes Perner
  • Patent number: 5292800
    Abstract: Water-in-oil emulsions of water-soluble or water-swellable polymers, in which the oil phase of the emulsion consists of not less than 50% by weight of an oil of vegetable or animal origin, contain, as water-in-oil emulsifiers, compounds which are obtainable by(A) reacting a C.sub.10 -C.sub.22 -fatty alcohol with epichlorohydrin in a molar ratio of from 1:0.5 to 1:1.5 to give a glycidyl ether,(B) reacting the glycidyl ether with (1) a saturated C.sub.2 -C.sub.6 -alcohol containing from 2 to 6 OH groups or (2) the monoether thereof with a C.sub.10 -C.sub.22 -fatty alcohol, in a molar ratio of glycidyl ether to (1) or (2) of from 1:0.5 to 1:6, in the presence of an acid or base and(C) alkoxylating the reaction product from (B) with one or more C.sub.2 -C.sub.4 -alkylene oxides in a molar ratio of from 1:1 to 1:6,if necessary, from 5 to 95% by weight of the stated water-in-oil emulsifier being replaced with other water-in-oil emulsifiers.
    Type: Grant
    Filed: August 13, 1992
    Date of Patent: March 8, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietmar Moench, Heinrich Hartmann, Hans-Ulrich Wekel
  • Patent number: 5290880
    Abstract: N-vinylformamide is polymerized with or without other water-soluble monoethylenically unsaturated monomers and with or without water-insoluble monoethylenically unsaturated monomers in not less than 30% strength by weight aqueous monomer solutions in the presence of a polymerization initiator at not more than 150.degree. C. in a kneader by a method in which the polymerization is carried out to such an extent that the initially formed water-containing polymer gel disintegrates into fine particles and the finely divided polymer obtainable in this manner is hydrolyzed, preferably in the kneader, so that not less than 0.1 mol % of the N-vinylformamide units present in the polymer are converted into vinylamine units. The polymers obtainable in this manner dissolve readily in water. The aqueous solutions are used, for example, in papermaking and tertiary oil production.
    Type: Grant
    Filed: February 27, 1991
    Date of Patent: March 1, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietmar Moench, Michael Kroener, Enrique Freudenberg, Heinrich Hartmann, Norbert Sendhoff
  • Patent number: 5286263
    Abstract: Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 -C.sub.40 -alkyl vinyl ethers, if necessary as a mixture with not more than 50 mol % of C.sub.8 -C.sub.40 -monoolefins, with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for imparting water repellency to leathers and skins.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: February 15, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Ortwin Schaffer, Herbert Bay, Karl Stork, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5279613
    Abstract: Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 --C.sub.40 -monoolefins with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides by mass polymerization at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for rendering leathers and skins water-repellent.
    Type: Grant
    Filed: February 5, 1992
    Date of Patent: January 18, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Ortwin Schaffer, Herbert Bay, Karl Stork, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5273676
    Abstract: Copolymers useful in amounts of from 0.1 to 15% by weight as grayness inhibiting and primary detergency boosting additives in pulverulent liquid detergents have K values of from 10 to 80 (determined by Fikentscher in dimethylformamide at 25.degree. C. with a polymer concentration of 2% by weight) and are obtainable by copolymerizing monomer mixtures of(a) from 10 to 60% by weight of water-soluble monomers obtainable from (A) water-soluble polyalkylene glycols or (B) water-soluble alkoxylated C.sub.1 -C.sub.25 -alcohols, for example by esterification with C.sub.3 -C.sub.6 -carboxylic acids, by vinylation with acetylene or by allylation with alkenyl ethers, or by reaction with ammonia to give the corresponding end group aminated compounds (A) or (B) and by reaction with monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids to form the amides, and(b) from 40 to 90% by weight of vinyl esters of saturated monocarboxylic acids and/or alkyl esters of monoethylenically unsaturated C.sub.3 -C.sub.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: December 28, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Boeckh, Hans-Peter Seelmann-Eggebert, Heinrich Hartmann, Alexander Kud, Wolfgang Trieselt
  • Patent number: 5266165
    Abstract: Abstract of the Disclosure: Copolymers of (a) C.sub.12 - to C.sub.24 -monoolefins and (b) maleic anhydride or itaconic anhydride, having molecular weights of from 800 to 100,000 g/mol, in the form of partially or completely neutralized semiamides with morpholine, in aqueous solution or dispersion, can be used as sizes for paper.
    Type: Grant
    Filed: October 1, 1992
    Date of Patent: November 30, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Arnold DeClercq, Walter Denzinger, Norbert Greif, Heinrich Hartmann, Knut Oppenlaender, Ulrich Riebeling
  • Patent number: 5262008
    Abstract: Paper, board and cardboard are produced by draining a paper stock in the presence of a nonhydrolyzed copolymer which contains, as polymerized units,(a) from 99 to 1 mol % of N-vinylformamide and(b) from 1 to 99 mol % of one or more water-soluble basic monomers of the formula ##STR1## where R.sup.1 is H, CH.sub.3 or C.sub.2 H.sub.5, R.sup.2, R.sup.3 and R.sup.4 are each H, CH.sub.3, C.sub.2 H.sub.5 or (--CH.sub.2 --CH.sub.2 --O--).sub.n H, R.sup.5 and R.sup.6 are each C.sub.1 -C.sub.10 -alkyl, A is C.sub.1 -C.sub.6 -alkylene, n is from 1 to 6 and Y.sup..crclbar. is an anion, in an amount of from 0.01 to 3.5% by weight, based on dry paper stock.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: November 16, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietmar Moench, Heinrich Hartmann, Enrique Freudenberg, Andreas Stange
  • Patent number: 5260396
    Abstract: Water resistant films and coatings are prepared by treating films or coatings of water soluble or dispersible grafted proteins prepared with monoethylenically unsaturated monomers at above 40.degree. C. and/or with at least one compound which is a hardener for proteins, and are useful as compostable packaging materials or as outer layers of diapers.
    Type: Grant
    Filed: November 2, 1992
    Date of Patent: November 9, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Ekhard Winkler, Juergen Steinmetz, Thomas Anstock
  • Patent number: 5258473
    Abstract: Finely divided, water-soluble polymers are prepared by polymerization of water-soluble, monoethylenically unsaturated monomers in not less than 20% strength by weight aqueous solution in the presence of a polymerization initiator in a kneader by a process in which from 0.1 to 10% by weight, based on the total monomers, of a surfactant are used in the polymerization, the polymerization initially being carried out to a conversion of the monomers of not less than 60% in the absence of the surfactant or in the presence of not more than 50% of the amount of surfactant, and the remaining amount of surfactant then being added to the reaction mixture and the polymerization completed. The addition of surfactant causes the polymer gel to disintegrate with formation of fine particles.
    Type: Grant
    Filed: March 1, 1991
    Date of Patent: November 2, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Niessner, Stefan Wickel, Walter Schneider, Juergen Beck, Heinrich Hartmann, Thomas Meyer
  • Patent number: 5232603
    Abstract: Water-soluble copolymers which contain, polymerized in, as characteristic monomers(a) 99 to 50% by weight of monoethylenically unsaturated carboxylic acids with 3 to 8 carbon atoms or their salts and(b) 1 to 50% by weight of N-vinylimidazole or substituted N-vinylimidazoles, their salts or products of quaternization and which have K values of from 10 to 50 are used for water treatment to reduce deposits of scale and sludge in water-conveying systems.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: August 3, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Charalampos Gousetis, Ulrich Goeckel, Alfred Ruland
  • Patent number: 5228915
    Abstract: A cementing composition useful in cementing oil, gas and water wells, comprising water, hydraulic cement and an effective amount of water soluble fluid loss additive comprised of a blend of a copolymer (i) of acrylamide/vinyl imidazole in a weight percent ratio of from about 95:5 to 5:95, said copolymer (i) having a molecular weight range of from about 100,000 to 3,000,000, and a copolymer (ii) of vinyl pyrrolidone and the sodium salt of vinyl sulfonate in a weight percent ratio of 80:20 to 20:80, said copolymer (ii) having a molecular weight range of from about 100,000 to 3,000,000. The blend is comprised of a weight percent ratio of copolymer (i) to copolymer (ii) in the range of 20:80 to 80:20. The composition can also optionally include a dispersant such as sodium or potassium salts or a sulfonated naphthalene formaldehyde condensate.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: July 20, 1993
    Assignee: BASF Corporation
    Inventors: Stefano C. Crema, Clare H. Kucera, Gerd Konrad, Heinrich Hartmann
  • Patent number: 5227446
    Abstract: Graft copolymers obtainable by free radical-initiated copolymerization of(A) a monomer mixture comprising(a) a monoethylenically unsaturated C.sub.4 - to C.sub.8 -dicarboxylic acid, or an anhydride, alkali metal salt or ammonium salt thereof,(b) a monoethylenically unsaturated C.sub.3 - to C.sub.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: July 13, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Alexander Kud, Richard Baur, John Feldmann, Hans-Juergen Raubenheimer
  • Patent number: 5225088
    Abstract: Nonhydrolyzed copolymers of(a) from 99 to 1 mol % of N-vinylformamide and(b) from 1 to 99 mol % of one or more water-soluble dialkylaminoalkylacrylamides in the form of the salts or quaternized products or a dialkylammonium compoundare used as agents for the treatment of wastewaters and sludges.
    Type: Grant
    Filed: September 18, 1991
    Date of Patent: July 6, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Dietmar Moench, Heinrich Hartmann, Karl-Heinz Buechner
  • Patent number: 5219969
    Abstract: Abstract of the Disclosure: Crosslinked acrylic or methacrylic acid copolymers with crosslinkable groups that are useful as thickeners for textile print pastes are obtainable by copolymerization of(a) from 50 to 99 parts by weight of acrylic acid and/or methacrylic acid,(b) from 1 to 50 parts by weight of at least one N-methylol (meth)acrylamide or derivatives thereof,(c) from 50 to 10,000 ppm, based on the monomers (a) and (b), of an at least bifunctional crosslinker, and(d) from 0 to 49 parts by weight of other monoethylenically unsaturated monomersin the presence of a free radical polymerization initiator in the aqueous phase of a water-in-oil emulsion.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: June 15, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Uhl, Norbert Grund, Reinhard Schneider, Ingeborg Schermann, Manfred Niessner, Heinrich Hartmann