Patents by Inventor Heinrich Hartmann

Heinrich Hartmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5217642
    Abstract: Water-soluble or water-dispersible polyesters obtainable by condensation of tartaric acid or derivatives thereof alone or by condensation of mixtures of tartaric acid or derivatives thereof and citric acid with or without alcohols, water-soluble polyalkylene glycols or water-soluble polyaddition products of alkylene oxides with alcohols, fatty acids, alkylphenols or alkylamines and with or without at least dibasic carboxylic acids are suitable for use as detergent additives.
    Type: Grant
    Filed: October 29, 1991
    Date of Patent: June 8, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Kud, Richard Baur, Dieter Boeckh, Heinrich Hartmann
  • Patent number: 5208075
    Abstract: Water-soluble or water-dispersible grafts of proteins with monoethylenically unsaturated monomers are used as sizing agents for staple fiber and filament yarns.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: May 4, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Manfred Niessner, Heinrich Hartmann, Dieter Voelker, Juergen Hartmann, Holger Schoepke
  • Patent number: 5207941
    Abstract: Phosphate-free and low-phosphate detergents which contain surfactants as essential constituents also contain from 0.1 to 20% by weight, based on the particular formulation, of water-soluble or water-dispersible grafted proteins obtainable by free radical copolymerization of(A) monoethylenically unsaturated monomers in the presence of(B) proteins in a weight ratio of (A):(B) of (0.5-90):(99.5-10).
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: May 4, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Richard Baur, Wolfgang Trieselt
  • Patent number: 5180804
    Abstract: The water absorption capacity of crosslinked, water-swellable polymers is improved by a process in which a water-containing, finely divided polymer gel having a solids content of from 20 to 65% by weight is treated with steam at not less than 50.degree. C., the solids content of the water-containing polymer gel increasing by not more than 30% by weight, and the polymer gel is then dried in a conventional manner.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: January 19, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Niessner, Juergen Beck, Heinrich Hartmann, Andreas H. Kemna, Stefan Wickel
  • Patent number: 5178641
    Abstract: Crude oil middle distillates with improved cold flow properties, containing small amounts ofA. conventional flow improver on an ethylene base, andB. copolymers which consist of 10 to 95 mol-% of one or more acrylacrylates or alkylmethacrylates with C.sub.1 - to C.sub.26 -alkyl chains, and of 5 to 90 mol-% of one or more ethylenically unsaturated dicarboxylic acids or their anhydrides, where the copolymer is reacted to a large extent with one or several primary or secondary amines into the monoamide or amide/ammonia salt of dicarboxylic acid, and the quantitative proportion of A to B is from 40 to 60 up to 95 to 5.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: January 12, 1993
    Assignee: BASF Corporation
    Inventors: Gerd Konrad, Bernd Wenderoth, Klaus Barthold, Erich Schwartz, Hans-Juergen Raubenheimer, Heinrich Hartmann
  • Patent number: 5175361
    Abstract: A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: December 29, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Wolfgang Trieselt, Albert Hettche, Rolf Schneider, Hans-Juergen Raubenheimer
  • Patent number: 5149750
    Abstract: Finely divided, gel-like, water-swellable copolymers are prepared by copolymerizing(a) 100 parts by weight of water-soluble, monoethylenically unsaturated monomers,(b) from 0.01 to 5 parts by weight of monomers containing two or more ethylenically unsaturated double bonds and(c) from 0 to 20 parts by weight of water-insoluble, monoethylenically unsaturated monomersin 20-80% strength by weight aqueous solution in the presence of a polymerization initiator and from 0.1 to 10% by weight, based on the monomers used in the copolymerization, of a surfactant, by a process in which the monomers are copolymerized in the presence of initially from 0 to 50% by weight of the amount of surfactant to a conversion of not less than 60%, the remaining amount of surfactant is then added to the reaction mixture and the copolymerization is completed and the resulting gel particles dried.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: September 22, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Niessner, Stefan Wickel, Wilfried Heide, Heinrich Hartmann
  • Patent number: 5145559
    Abstract: Paper, board and cardboard are produced by draining a paper stock, containing undesirable substances, in the presence of hydrolyzed homo- and/or copolymers of N-vinylformamide having a degree of hydrolysis of not less than 60% and a cationic retention aid. According to the invention, faster drainage and improved retention are obtained compared with the use of known fixing agents.
    Type: Grant
    Filed: January 16, 1991
    Date of Patent: September 8, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Auhorn, Friedrich Linhart, Primoz Lorencak, Michael Kroener, Norbert Sendhoff, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5142020
    Abstract: Polyesters obtainable by condensation of(a) an at least dicarboxylic acid, or an ester or anhydride or a mixture thereof,(b) an at least dihydric alcohol or an addition product of from 1 to 5 mol of at least one alkylene oxide of 2 or 3 carbon atoms with 1 mol of an at least dihydric alcohol, or a mixture thereof, and(c) a water-soluble addition product of from 5 to 80 mol of at least one alkylene oxide with 1 mol of a C.sub.8 -C.sub.24 -alcohol, a C.sub.8 -C.sub.18 -alkylphenol or a C.sub.8 -C.sub.24 -alkylaminein a molar ratio of (a):(b):(c) of 100:(25-2500):(5-110) at not less than 120.degree. C. up to a weight average molecular weight of from 2000 to 50000, are used in amounts of from 0.05 to 15% by weight as grayness inhibitors and soil release promoters in detergents.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: August 25, 1992
    Assignee: Basf Aktiengesellschaft
    Inventors: Alexander Kud, Dieter Boeckh, Wolfgang Trieselt, Hans-Ulrich Jaeger, Heinrich Hartmann
  • Patent number: 5126395
    Abstract: Stable water-in-oil emulsions of a hydrolyzed polymer of an N-vinylamide of the formula ##STR1## where R and R.sup.1 are each H or C.sub.1 -C.sub.6 -alkyl, are prepared by polymerizing a compound of the formula I, alone or as a mixture with other monoethylenically unsaturated monomers, in the form of a water-in-oil emulsion to give a water-in-oil polymer emulsion, and then hydrolyzing the polymer, hydrolysis of the polymer in the form of the water-in-oil polymer emulsion being carried out in the presence of an acid or base, and additives in the form of antioxidants, reducing agents or aldehyde acceptors being added for stabilization.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: June 30, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Lutz End, Walter Denzinger, Michael Kroener, Norbert Sendhoff, Enrique Freudenberg, Friedrich Linhart, Rolf Fikentscher, Heinrich Hartmann
  • Patent number: 5126069
    Abstract: A detergent composition contains as essential ingredients surfactants and from 0.1 to 15% by weight of water-soluble or -dispersible polymers obtainable by oxidation of polymers containing not less than 10 mol % of carboxyl-containing monoethylenically unsaturated monomers as copolymerized units and having Fikentscher K values of from 8 to 300.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: June 30, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Kud, Richard Baur, Angelika Funhoff, Walter Denzinger, Heinrich Hartmann, Hans-Juergen Raubenheimer
  • Patent number: 5124181
    Abstract: Copolymers which containa) from 50 to 90% by weight of C.sub.8 -C.sub.40 -alkyl methacrylates, vinyl esters of C.sub.8 -C.sub.40 -carboxylic acids or mixtures thereof andb) from 10 to 50% by weight of monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids, monoethylenically unsaturated dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids, amides of C.sub.3 -C.sub.12 -monocarboxylic acids or mixtures thereofas copolymerized units and have molecular masses of from 500 to 30,000 are used in at least partially neutralized form in aqueous solution or dispersion for making leather and furs water repellent.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: June 23, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Ortwin Schaffer, Herbert Bay, Karl Stork, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5104951
    Abstract: Water-soluble polymers having K values of from 5 to 100 (determined on the Na salt of the polymers according to H. Fikentscher in aqueous solution at 25.degree. C., a pH of 7 and a concentration of 1% by weight of the Na salt of the polymer) are prepared by polymerizing a monomer mixture of(a) monethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acids and(b) more than 20-100 mol % of monomers which have two or more ethylenically unsaturated double bonds linked via one or more ester or amide functions and which contain one or more --CO--OX groups, where X is one hydrogen equivalent, one alkali metal equivalent or one alkaline earth metal equivalent or an ammonium group,in aqueous solution in the presence of a polymerization initiator, and the polymers are used in amounts of from 0.5 to 25% by weight in detergents and cleaners.
    Type: Grant
    Filed: May 29, 1991
    Date of Patent: April 14, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Peter Seelmann-Eggebert, Dieter Boeckh, Heinrich Hartmann, Wolfgang Trieselt, Richard Baur
  • Patent number: 5098521
    Abstract: Paper, board and cardboard are produced from paper stocks containing foreign substances by drainage in the presence of a polymer which contains, as typical polymerized constituents, units of the formulae ##STR1## where R.sup.1 and R.sup.2 are each H, C.sub.1 -C.sub.3 -alkyl, and which have K values of not less than 130, the polymers containing less than 10 mol % of units of the formula II.
    Type: Grant
    Filed: January 9, 1991
    Date of Patent: March 24, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Enrique Freudenberg, Friedrich Linhart, Rainer Tresch, Heinrich Hartmann, Walter Denzinger, Michael Kroener, Norbert Sendhoff
  • Patent number: 5084535
    Abstract: Pulverulent polymers of acrylic acid and methacrylic acid are prepared by polymerizing (a) from 100 to 70% by weight of acrylic acid, methacrylic acid or a mixture thereof and (b) from 0 to 30% by weight of vinylsulfonic acid or an alkali metal salt thereof in a monohydric C.sub.1 -C.sub.8 -alcohol, water or a mixture thereof in a pulverulent bed in the presence of a polymerization initiator and from 0.05 to 10 mol % of thiocarboxylic acid and/or a mercaptoalcohol and from 0.05 to 10 mol % of propionic acid or formic acid as regulators, each percentage being based on the monomers used in the polymerization, by maintaining the pulverulent state during the polymerization, removing the heat of polymerization by distilling off the solvent and recirculating the reaction mixture.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: January 28, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Hennig, Heinrich Hartmann, Hans-Juergen Raubenheimer, Hermann Fischer, Walter Denzinger
  • Patent number: 5073269
    Abstract: Water-soluble copolymers of maleic acid useful as water treatment agents are prepared by copolymerizing(a) from 99 to 80% by weight of maleic anhydride and(b) from 1 to 20% by weight of a monoethylenically unsaturated monomer copolymerizable therewith and, facultatively,(c) up to 10% by weight of a crosslinker, at from 60.degree. to 200.degree. C. in an aromatic hydrocarbon in the presence of peroxyesters derived from saturated or monoethylenically unsaturated carboxylic acids, and hydrolyzing the anhydride groups of the copolymers following the polymerization.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: December 17, 1991
    Assignee: BASF Corporation
    Inventors: Walter Denzinger, Heinrich Hartmann, Ulrich Goeckel, Felix Richter, Hans-Juergen Raubenheimer, Ekhard Winkler
  • Patent number: 5046562
    Abstract: A cementing composition useful in cementing oil, gas and water wells, comprising water, hydraulic cement and an effective amount of water soluble fluid loss additive comprised of a blend of a copolymer of acrylamide/vinyl imidazole in a weight percent ratio of from about 95:5 to 5:95, said copolymer having a molecular weight range of from about 100,000 to 3,000,000, and a terpolymer of acrylamide/acrylamidomethylpropane sulfonic acid sodium salt/vinyl imidazole in a weight percent ratio of 60:20:20, said terpolymer having a molecular weight range of from about 100,000 to 3,000.000. The blend is comprised of a weight percent ratio of copolymer to terpolymer in the range of 20:80 to 80:20. The composition can also optionally include a dispersant such as sodium or potassium salts or a sulfonated naphthalene formaldehyde condensate.
    Type: Grant
    Filed: January 22, 1991
    Date of Patent: September 10, 1991
    Assignee: BASF Corporation
    Inventors: Stefano C. Crema, Clare H. Kucera, Gerd Konrad, Heinrich Hartmann
  • Patent number: 5025040
    Abstract: A cementing composition useful in cementing oil, gas and water wells, comprising water, hydraulic cement and an effective amount of water soluble fluid loss additive comprised of a blend of a copolymer of acrylamide/vinyl imidazole in a weight percent ratio of from about 95:5 to 5:95, said copolymer having a molecular weight range of from about 100,000 to 3,000,000, and a terpolymer of acrylamide/acrylamidomethylpropane sulfonic acid sodium salt/vinyl imidazole in a weight percent ratio of 60:20:20, said terpolymer having a molecular weight range of from about 100,000 to 3,000,000. The blend is comprised of a weight percent ratio of copolymer to terpolymer in the range of 20:80 to 80:20. The composition can also optionally include a dispersant such as sodium or potassium salts or a sulfonated naphthalene formaldehyde condensate.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: June 18, 1991
    Assignee: BASF
    Inventors: Stefano C. Crema, Clare H. Kucera, Gerd Konrad, Heinrich Hartmann
  • Patent number: 5009670
    Abstract: Fuels for gasoline engines contain small amounts of copolymers of alkyl (meth)-acrylates where the alkyl radical is of 8 to 40 carbon atoms and/or vinyl esters of carboxylic acids of 8 to 40 carbon atoms and monoethylenically unsaturated mono- and/or dicarboxylic acids of 3 to 12 carbon atoms and/or monoethylenically unsaturated compounds having sulfo and/or phosphonic acid groups, having a total molecular weight of from 500 to 20,000 g per mole, some or all of the carboxyl, sulfo and phosphonic acid groups of the copolymers having been reacted with an alkali or alkaline earth with formation of the alkali metla salts or alkaline earth metal salts and the remainder of the acid groups having been reacted with ammonia and/or amines of not more than 50 carbon atoms to give the corresponding amide groups and/or ammonium salts.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: April 23, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz-Dieter Martischius, Hans-Henning Vogel, Norbert Greif, Knut Oppenlaender, Walter Denzinger, Heinrich Hartmann
  • Patent number: 5009805
    Abstract: Liquid detergent formulations contain as essential constituents a surfactant and 0.1-20% by weight of a copolymer which contains(a) 50-99 mol % of units of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, a half ester of a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, an ester of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a C.sub.2 -C.sub.30 -olefin, styrene, a C.sub.1 -C.sub.3 -alkylstyrene, a C.sub.1 -C.sub.28 -alkyl vinyl ether, a vinyl ester of a saturated C.sub.1 -C.sub.8 -monocarboxylic acid or a mixture thereof and(b) 50-1 mol % of units of an amide of a monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acid where the amide groups have the structure ##STR1## where R.sup.1 is C.sub.8 -C.sub.28 -alkyl or preferably ##STR2## R.sup.3 and R.sup.4 are each H, CH.sub.3 or C.sub.2 H.sub.5, R is C.sub.1 -C.sub.28 -alkyl,n is from 2 to 100 andR.sup.2 is H or R.sup.
    Type: Grant
    Filed: October 19, 1989
    Date of Patent: April 23, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Johannes Perner, Paul Diessel, Heinrich Hartmann, Walter Denzinger, Alfred Oftring, Willibald Schoenleben