Patents by Inventor Henri J. M. Grunbauer

Henri J. M. Grunbauer has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10196478
    Abstract: The present invention relates to a composition comprising a lignin polyol, a method for the manufacturing of said composition and use thereof in different application areas, such as in adhesives, binders, castings, foams (such as in rigid polyurethane and polyisocyanurate foams for thermal insulation and construction applications, semi-rigid, flexible, moulded, laminated, microcellular and viscoelastic polyurethane foams), fillers, glues, sealants, elastomers and rubbers. The present invention also relates to a method for the manufacturing of a foam and use of this foam.
    Type: Grant
    Filed: December 3, 2014
    Date of Patent: February 5, 2019
    Assignee: Stora Enso OYJ
    Inventors: Henri J. M. Grünbauer, Dimitri Areskogh
  • Publication number: 20180179447
    Abstract: The present invention relates to a system and method for converting biomass and the products obtained therefrom. The system comprises a conversion unit (1) provided with an inlet (5) for introducing biomass, an inlet (6) for introducing a gas stream, an outlet (8) for removing carbonized material (9), and an outlet (10) for releasing a fluid (F3), the system further comprising a first separation unit (11), a second separation unit (15), a condensing unit (18).
    Type: Application
    Filed: June 10, 2016
    Publication date: June 28, 2018
    Inventors: Robert Jan Vasbinder, Henri J.M. Grunbauer
  • Publication number: 20170002129
    Abstract: The present invention relates to a composition comprising a lignin polyol, a method for the manufacturing of said composition and use thereof in different application areas, such as in adhesives, binders, castings, foams (such as in rigid polyurethane and polyisocyanurate foams for thermal insulation and construction applications, semi-rigid, flexible, moulded, laminated, microcellular and viscoelastic polyurethane foams), fillers, glues, sealants, elastomers and rubbers. The present invention also relates to a method for the manufacturing of a foam and use of this foam.
    Type: Application
    Filed: December 3, 2014
    Publication date: January 5, 2017
    Inventors: Henri J.M. Grünbauer, Dimitri Areskogh
  • Publication number: 20150144829
    Abstract: The present invention relates to a composition in the form of a dispersion, a method for the manufacturing of said composition and uses thereof.
    Type: Application
    Filed: May 30, 2013
    Publication date: May 28, 2015
    Inventor: Henri J.M. Grünbauer
  • Patent number: 6211285
    Abstract: A polyisocyanate-based polymer having dispersed therein a metal salt, obtained by reacting an organic polyisocyanate with an aqueous composition of a metal salt. The polymer comprises the metal salt in an amount of from at least 10 weight percent based on total weight of the dry salt with the weight of the polyisocyanate-based polymer including salt therein. The polymer on calcination provides a metal-containing powder having an average particle size of 1 micrometer or less. Such metal-containing powders are of value in the preparation of industrial catalysts, ceramics, electronic components, or as fillers in plastics, paints, or cosmetics.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: April 3, 2001
    Assignee: The Dow Chemical Company
    Inventors: Henri J. M. Grünbauer, Jacobus A. F. Broos, Kevin Pickin
  • Patent number: 6162862
    Abstract: Disclosed is a urethane-based composition of value in surface coating applications, including treatment of glass or textiles, in adhesives and in the manufacture of a stabilized latex. The composition comprises a polyfunctional liquid urethane-containing adduct wherein said adduct contains as a first functional group at least one isocyanate moiety per molecule, and a second functional group per molecule which is not an isocyanate moiety and which is not reactive towards isocyanate functionality. The second functional group can comprise ester, nitrile, halogen, halocarbon, siloxyl, silyl, alkyne or alkene, or combinations of two or more thereof.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: December 19, 2000
    Assignee: The Dow Chemical Company
    Inventors: Henri J.M. Grunbauer, Camiel F. Bartelink, Michael J. Elwell, Martin Moller
  • Patent number: 5998523
    Abstract: Disclosed is a composition of an essentially solid phase state having as components, a liquid hydrophilic organic polymer, an aqueous salt solution containing at least one metallic or metalloid element, and a coagulating agent. The composition on calcination provides a metal-containing powder having an average particle size of 1 micrometer or less. Such metal-containing powders are of value in the preparation of industrial catalysts, ceramics, electronic components, or as fillers in plastics, paints or cosmetics.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: December 7, 1999
    Assignee: The Dow Chemical Company
    Inventors: Henri J. M. Grunbauer, Jacobus A. Broos, Frederik R. van Buren
  • Patent number: 5856678
    Abstract: Disclosed is a process for preparing an open-celled rigid polyurethane foam by reacting a polyisocyanate with a polyol in the presence of a blowing agent, usually water, and a cell opening agent. The cell opening agent comprises a combination of a polyoxyalkylene polysiloxane having a cloud point of 65.degree. C. or less, and a second substance that has a critical surface free energy of less than about 23 mJ/m.sup.2. Highly preferred as second substance is fine particulate poly(tetrafluoroethylene) polymer.
    Type: Grant
    Filed: February 20, 1998
    Date of Patent: January 5, 1999
    Assignee: The Dow Chemical Company
    Inventors: Guido F. Smits, Guliano Cini, Henri J. M. Grunbauer, Jacobus A. F. Broos
  • Patent number: 5721284
    Abstract: Disclosed is a process for preparing an open-celled rigid polyurethane foam by reacting a polyisocyanate with a polyol in the presence of a blowing agent, usually water, and a cell opening agent. The cell opening agent comprises a combination of a polyoxyalkylene polysiloxane having a cloud point of 65.degree. C. or less, and a second substance that has a critical surface free energy of less than about 23 mJ/m.sup.2. Highly preferred as second substance is fine particulate poly(tetrafluoroethylene) polymer.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: February 24, 1998
    Assignee: The Dow Chemical Company
    Inventors: Guido F. Smits, Giuliano Cini, Henri J. M. Grunbauer, Jacobus A. F. Broos
  • Patent number: 5338601
    Abstract: This invention relates to the use of a barrier film, being a thermoplastic linear polyolefin resin, to protect a styrenic resin sheet which constitutes the inner liner wall of an insulative cabinet wall of, for example, a refrigeration appliance unit from attack by the halogen-containing blowing agents present in the insulative polyurethane foam found within the cabinet wall. Preferred thermoplastic linear polyolefin resins are linear low density polyethylene.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: August 16, 1994
    Assignee: The Dow Chemical Company
    Inventors: Jan Brands, Henri J. M. Grunbauer, Kees-Jeen van Duin
  • Patent number: 5286759
    Abstract: Polyisocyanate-based foams having a uniformly fine cell size are prepared by reacting a polyisocyanate with an isocyanate-reactive compound in the presence of a blowing agent mixture comprising a hydrocarbon component which has four or more carbon atoms and a polyfluorocarbon component which has a boiling point of from about 283 K. to about 393 K. at 760 mm Hg and wherein the boiling point:molecular weight ratio of said polyfluorocarbon component is less than or equal to 1.7. The hydrocarbon component is present in from about 5 to about 95 mole percent and the polyfluorocarbon in from about 95 to about 5 mole percent based on total amounts of hydrocarbon and polyfluorocarbon.
    Type: Grant
    Filed: March 8, 1991
    Date of Patent: February 15, 1994
    Assignee: The Dow Chemical Company
    Inventors: Guido F. Smits, Henri J. M. Grunbauer, Johan A. Thoen, Werner A. Lidy
  • Patent number: 5227245
    Abstract: This invention relates to the use of a barrier film consisting essentially of thermoplastic homo- or copolymer polyester resin to protect a styrenic resin sheet which constitutes the inner liner wall of an insulative cabinet wall of, for example, a refrigeration appliance unit from attack by the halogen-containing blowing agents present in the insulative polyurethane foam found within the cabinet wall.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: July 13, 1993
    Assignee: The Dow Chemical Company
    Inventors: Jan Brands, Steven B. Swartzmiller, Henri J. M. Grunbauer, Kees-Jeen van Duin
  • Patent number: 4972003
    Abstract: This invention relates to a process for preparing a rigid, closed-celled polyisocyanate-based foam in the presence of a blowing agent composition. The blowing agent composition comprises one or more organic compounds, particularly halocarbons, having a boiling point of less than or equal to 272K at atmospheric pressure, and further is substantially free of organic compounds having a boiling point of 273K or greater. Preferred halocarbons are chlorofluoroethanes and fluoroethanes.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: November 20, 1990
    Assignee: The Dow Chemical Company
    Inventors: Henri J. M. Grunbauer, Guido F. Smits
  • Patent number: 4945119
    Abstract: This invention relates to rigid closed-celled polyisocyanate-based foams exhibiting improved dimensional stability and a process for their preparation. In particular, it relates to foams containing within their cells, when initially prepared, a gas mixture comprising theoretically from about 5 to 70 mole percent carbon dioxide and from about 40 to about 95 mole percent of an organic compound mixture.The organic compound mixture itself, comprises (a) from 40 to 95 mole percent of an organic compound having a boiling point greater than or equal to about 283K, and (b) from 5 to 60 mole percent of an organic compound having a boiling point equal to or less than about 266K. Halocarbons are the preferred organic compounds for components (a) and (b).
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: July 31, 1990
    Assignee: The Dow Chemical Company
    Inventors: Guide F. Smits, Henri J. M. Grunbauer
  • Patent number: 4943597
    Abstract: Rigid closed-cell polyisocyanate-based foams are prepared by the reaction of polyisocyanate with a polyol composition having an average hydroxyl number of about 100 to about 500 and comprising at least one polyether polyol containing four or more active hydrogens and having a hydroxyl number of from about 50 to about 500. The blowing of the foam is essentially with carbon dioxide generated from the reaction of water with polyisocyanate so as to provide foams of the desired density containing at least 40 mole percent carbon dioxide in their cells.
    Type: Grant
    Filed: December 7, 1988
    Date of Patent: July 24, 1990
    Assignee: The Dow Chemical Company
    Inventors: Henri J. M. Grunbauer, Johan A. Thoen, Guido F. Smits