Patents by Inventor Hiroto Tatsuno

Hiroto Tatsuno has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11777109
    Abstract: A hydrophilic porous carbon electrode which has excellent hydrophilicity, which has high reaction activity when used for a battery, and with which excellent battery characteristics is able to be obtained is provided. A hydrophilic porous carbon electrode is a sheet-form hydrophilic porous carbon electrode in which a carbon fiber is bonded using a resin carbide and has a contact angles ?A of water on both surfaces in a thickness direction being 0 to 15° and a contact angle ?B of water in a middle portion in the thickness direction being 0 to 15°. The hydrophilic porous carbon electrode is obtained by forming the carbon fiber and a binder fiber into a sheet, impregnating the sheet into a thermosetting resin, subjecting it to heat press processing, and then subjecting it to carbonization at 400 to 3000° C. in an inert atmosphere. The hydrophilic porous carbon electrode is transported and is subjected to a heat treatment while an oxidizing gas flows at 400 to 800° C.
    Type: Grant
    Filed: July 18, 2022
    Date of Patent: October 3, 2023
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kyu Ota, Hiroto Tatsuno, Kazuhiro Sumioka
  • Publication number: 20220359887
    Abstract: A hydrophilic porous carbon electrode which has excellent hydrophilicity, which has high reaction activity when used for a battery, and with which excellent battery characteristics is able to be obtained is provided. A hydrophilic porous carbon electrode is a sheet-form hydrophilic porous carbon electrode in which a carbon fiber is bonded using a resin carbide and has a contact angles ?A of water on both surfaces in a thickness direction being 0 to 15° and a contact angle ?B of water in a middle portion in the thickness direction being 0 to 15°. The hydrophilic porous carbon electrode is obtained by forming the carbon fiber and a binder fiber into a sheet, impregnating the sheet into a thermosetting resin, subjecting it to heat press processing, and then subjecting it to carbonization at 400 to 3000° C. in an inert atmosphere. The hydrophilic porous carbon electrode is transported and is subjected to a heat treatment while an oxidizing gas flows at 400 to 800° C.
    Type: Application
    Filed: July 18, 2022
    Publication date: November 10, 2022
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Kyu OTA, Hiroto TATSUNO, Kazuhiro SUMIOKA
  • Patent number: 11437629
    Abstract: A hydrophilic porous carbon electrode which has excellent hydrophilicity, which has high reaction activity when used for a battery, and with which excellent battery characteristics is able to be obtained is provided. A hydrophilic porous carbon electrode is a sheet-form hydrophilic porous carbon electrode in which a carbon fiber is bonded using a resin carbide and has a contact angles ?A of water on both surfaces in a thickness direction being 0 to 15° and a contact angle ?B of water in a middle portion in the thickness direction being 0 to 15°. The hydrophilic porous carbon electrode is obtained by forming the carbon fiber and a binder fiber into a sheet, impregnating the sheet into a thermosetting resin, subjecting it to heat press processing, and then subjecting it to carbonization at 400 to 3000° C. in an inert atmosphere. The hydrophilic porous carbon electrode is transported and is subjected to a heat treatment while an oxidizing gas flows at 400 to 800° C.
    Type: Grant
    Filed: August 12, 2020
    Date of Patent: September 6, 2022
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kyu Ota, Hiroto Tatsuno, Kazuhiro Sumioka
  • Patent number: 10727497
    Abstract: Disclosed herein is a porous electrode substrate in which carbon fibers are dispersed in the structure thereof have a fiber diameter of 3-15 micron and a fiber length of 2-30 mm, and are bound to one another by carbonized resin such that, when a pore distribution in the porous electrode is determined with a mercury intrusion porosimeter, such that a pore distribution curve is plotted on a graph having a common logarithmic scale on the horizontal axis, and a 1-100 micron pore diameter range of the pore distribution curve includes 80 or more measurement points at equal intervals along the common logarithmic scale, the pore distribution has a skewness S of ?2.0<S<?0.8 and a kurtosis K of 3.5<K<10 in the 1-100 micron pore diameter range.
    Type: Grant
    Filed: November 4, 2015
    Date of Patent: July 28, 2020
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hiroto Tatsuno, Makoto Nakamura
  • Publication number: 20190148739
    Abstract: A porous base material and a porous electrode having both gas permeability suitable for a gas diffusion layer for a fuel cell vehicle and mechanical strength capable of withstanding continuous processing in a roll-to-roll manner, and a porous electrode which is suitable for an electrode for a redox flow cell and has excellent diffusibility of an electrolyte are required. Provided is a porous base material containing a carbon fiber (A) having an average fiber diameter of 10 to 20 ?m, an average fiber length of 2 to 30 mm, a tensile modulus of elasticity of 200 to 600 GPa, and a tensile strength of 3,000 to 7,000 MPa and a carbon binder (D), in which the carbon fiber (A) is bound with the carbon binder (D).
    Type: Application
    Filed: January 10, 2019
    Publication date: May 16, 2019
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hiroto TATSUNO, Kazuhiro SUMIOKA, Kota HIDESHIMA
  • Publication number: 20170338497
    Abstract: Disclosed herein is a porous electrode substrate in which carbon fibers are dispersed in the structure thereof have a fiber diameter of 3-15 micron and a fiber length of 2-30 mm, and are bound to one another by carbonized resin such that, when a pore distribution in the porous electrode is determined with a mercury intrusion porosimeter, such that a pore distribution curve is plotted on a graph having a common logarithmic scale on the horizontal axis, and a 1-100 micron pore diameter range of the pore distribution curve includes 80 or more measurement points at equal intervals along the common logarithmic scale, the pore distribution has a skewness S of -2.0<S<-0.8 and a kurtosis K of 3.5<K<10 in the 1-100 micron pore diameter range.
    Type: Application
    Filed: November 4, 2015
    Publication date: November 23, 2017
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hiroto TATSUNO, Makoto NAKAMURA
  • Patent number: 9825304
    Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.
    Type: Grant
    Filed: March 22, 2016
    Date of Patent: November 21, 2017
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Hiroto Tatsuno, Kazuhiro Sumioka, Tadao Samejima
  • Patent number: 9716278
    Abstract: The present invention relates to a method for manufacturing a porous electrode base material including the following steps [1] to [3]: [1] a step for dispersing short carbon fibers (A) to form a sheet-form product; [2] a step for adding, to the sheet-form product, at least one phenolic resin (c) selected from a group consisting of a water soluble phenolic resin and a water dispersible phenolic resin along with carbon powder (d) to form a precursor sheet; and [3] a step for carbonizing the precursor sheet at the temperature of 1000° C. or higher, after the step [2].
    Type: Grant
    Filed: March 29, 2013
    Date of Patent: July 25, 2017
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Hiroto Tatsuno
  • Patent number: 9705137
    Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.
    Type: Grant
    Filed: January 20, 2012
    Date of Patent: July 11, 2017
    Assignee: MITSUBISHI RAYON CO., LTD.
    Inventors: Hiroto Tatsuno, Kazuhiro Sumioka, Tadao Samejima
  • Publication number: 20160204443
    Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.
    Type: Application
    Filed: March 22, 2016
    Publication date: July 14, 2016
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Hiroto TATSUNO, Kazuhiro Sumioka, Tadao Samejima
  • Publication number: 20150086901
    Abstract: The present invention relates to a method for manufacturing a porous electrode base material including the following steps [1] to [3]: [1] a step for dispersing short carbon fibers (A) to form a sheet-form product; [2] a step for adding, to the sheet-form product, at least one phenolic resin (c) selected from a group consisting of a water soluble phenolic resin and a water dispersible phenolic resin along with carbon powder (d) to form a precursor sheet; and [3] a step for carbonizing the precursor sheet at the temperature of 1000° C. or higher, after the step [2].
    Type: Application
    Filed: March 29, 2013
    Publication date: March 26, 2015
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventor: Hiroto Tatsuno
  • Publication number: 20130323620
    Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.
    Type: Application
    Filed: January 20, 2012
    Publication date: December 5, 2013
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Hiroto Tatsuno, Kazuhiro Sumioka, Tadao Samejima
  • Publication number: 20120115063
    Abstract: The present invention provides a porous electrode substrate that has high sheet strength, low production cost, and sufficient gas permeability and electrical conductivity, and a method for producing the same. In the present invention, the porous electrode substrate is produced by producing a precursor sheet including short carbon fibers (A), and one or more types of short precursor fibers (b) that undergo oxidation and/or one or more types of fibrillar precursor fibers (b?) that undergo oxidation, all of which are dispersed in a two-dimensional plane, subjecting the precursor sheet to entanglement treatment to form a three-dimensional entangled structure, then impregnating the precursor sheet with carbon powder and fluorine-based resin, and further heat treating the precursor sheet at a temperature of 150° C. or higher and lower than 400° C.
    Type: Application
    Filed: November 24, 2010
    Publication date: May 10, 2012
    Applicant: MITSUBISHI RAYON CO., LTD.
    Inventors: Kazuhiro Sumioka, Hiroto Tatsuno