Patents by Inventor Hiroto Tatsuno
Hiroto Tatsuno has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11777109Abstract: A hydrophilic porous carbon electrode which has excellent hydrophilicity, which has high reaction activity when used for a battery, and with which excellent battery characteristics is able to be obtained is provided. A hydrophilic porous carbon electrode is a sheet-form hydrophilic porous carbon electrode in which a carbon fiber is bonded using a resin carbide and has a contact angles ?A of water on both surfaces in a thickness direction being 0 to 15° and a contact angle ?B of water in a middle portion in the thickness direction being 0 to 15°. The hydrophilic porous carbon electrode is obtained by forming the carbon fiber and a binder fiber into a sheet, impregnating the sheet into a thermosetting resin, subjecting it to heat press processing, and then subjecting it to carbonization at 400 to 3000° C. in an inert atmosphere. The hydrophilic porous carbon electrode is transported and is subjected to a heat treatment while an oxidizing gas flows at 400 to 800° C.Type: GrantFiled: July 18, 2022Date of Patent: October 3, 2023Assignee: Mitsubishi Chemical CorporationInventors: Kyu Ota, Hiroto Tatsuno, Kazuhiro Sumioka
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Publication number: 20220359887Abstract: A hydrophilic porous carbon electrode which has excellent hydrophilicity, which has high reaction activity when used for a battery, and with which excellent battery characteristics is able to be obtained is provided. A hydrophilic porous carbon electrode is a sheet-form hydrophilic porous carbon electrode in which a carbon fiber is bonded using a resin carbide and has a contact angles ?A of water on both surfaces in a thickness direction being 0 to 15° and a contact angle ?B of water in a middle portion in the thickness direction being 0 to 15°. The hydrophilic porous carbon electrode is obtained by forming the carbon fiber and a binder fiber into a sheet, impregnating the sheet into a thermosetting resin, subjecting it to heat press processing, and then subjecting it to carbonization at 400 to 3000° C. in an inert atmosphere. The hydrophilic porous carbon electrode is transported and is subjected to a heat treatment while an oxidizing gas flows at 400 to 800° C.Type: ApplicationFiled: July 18, 2022Publication date: November 10, 2022Applicant: Mitsubishi Chemical CorporationInventors: Kyu OTA, Hiroto TATSUNO, Kazuhiro SUMIOKA
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Patent number: 11437629Abstract: A hydrophilic porous carbon electrode which has excellent hydrophilicity, which has high reaction activity when used for a battery, and with which excellent battery characteristics is able to be obtained is provided. A hydrophilic porous carbon electrode is a sheet-form hydrophilic porous carbon electrode in which a carbon fiber is bonded using a resin carbide and has a contact angles ?A of water on both surfaces in a thickness direction being 0 to 15° and a contact angle ?B of water in a middle portion in the thickness direction being 0 to 15°. The hydrophilic porous carbon electrode is obtained by forming the carbon fiber and a binder fiber into a sheet, impregnating the sheet into a thermosetting resin, subjecting it to heat press processing, and then subjecting it to carbonization at 400 to 3000° C. in an inert atmosphere. The hydrophilic porous carbon electrode is transported and is subjected to a heat treatment while an oxidizing gas flows at 400 to 800° C.Type: GrantFiled: August 12, 2020Date of Patent: September 6, 2022Assignee: Mitsubishi Chemical CorporationInventors: Kyu Ota, Hiroto Tatsuno, Kazuhiro Sumioka
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Patent number: 10727497Abstract: Disclosed herein is a porous electrode substrate in which carbon fibers are dispersed in the structure thereof have a fiber diameter of 3-15 micron and a fiber length of 2-30 mm, and are bound to one another by carbonized resin such that, when a pore distribution in the porous electrode is determined with a mercury intrusion porosimeter, such that a pore distribution curve is plotted on a graph having a common logarithmic scale on the horizontal axis, and a 1-100 micron pore diameter range of the pore distribution curve includes 80 or more measurement points at equal intervals along the common logarithmic scale, the pore distribution has a skewness S of ?2.0<S<?0.8 and a kurtosis K of 3.5<K<10 in the 1-100 micron pore diameter range.Type: GrantFiled: November 4, 2015Date of Patent: July 28, 2020Assignee: Mitsubishi Chemical CorporationInventors: Hiroto Tatsuno, Makoto Nakamura
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Publication number: 20190148739Abstract: A porous base material and a porous electrode having both gas permeability suitable for a gas diffusion layer for a fuel cell vehicle and mechanical strength capable of withstanding continuous processing in a roll-to-roll manner, and a porous electrode which is suitable for an electrode for a redox flow cell and has excellent diffusibility of an electrolyte are required. Provided is a porous base material containing a carbon fiber (A) having an average fiber diameter of 10 to 20 ?m, an average fiber length of 2 to 30 mm, a tensile modulus of elasticity of 200 to 600 GPa, and a tensile strength of 3,000 to 7,000 MPa and a carbon binder (D), in which the carbon fiber (A) is bound with the carbon binder (D).Type: ApplicationFiled: January 10, 2019Publication date: May 16, 2019Applicant: Mitsubishi Chemical CorporationInventors: Hiroto TATSUNO, Kazuhiro SUMIOKA, Kota HIDESHIMA
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Publication number: 20170338497Abstract: Disclosed herein is a porous electrode substrate in which carbon fibers are dispersed in the structure thereof have a fiber diameter of 3-15 micron and a fiber length of 2-30 mm, and are bound to one another by carbonized resin such that, when a pore distribution in the porous electrode is determined with a mercury intrusion porosimeter, such that a pore distribution curve is plotted on a graph having a common logarithmic scale on the horizontal axis, and a 1-100 micron pore diameter range of the pore distribution curve includes 80 or more measurement points at equal intervals along the common logarithmic scale, the pore distribution has a skewness S of -2.0<S<-0.8 and a kurtosis K of 3.5<K<10 in the 1-100 micron pore diameter range.Type: ApplicationFiled: November 4, 2015Publication date: November 23, 2017Applicant: Mitsubishi Chemical CorporationInventors: Hiroto TATSUNO, Makoto NAKAMURA
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Patent number: 9825304Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.Type: GrantFiled: March 22, 2016Date of Patent: November 21, 2017Assignee: MITSUBISHI CHEMICAL CORPORATIONInventors: Hiroto Tatsuno, Kazuhiro Sumioka, Tadao Samejima
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Patent number: 9716278Abstract: The present invention relates to a method for manufacturing a porous electrode base material including the following steps [1] to [3]: [1] a step for dispersing short carbon fibers (A) to form a sheet-form product; [2] a step for adding, to the sheet-form product, at least one phenolic resin (c) selected from a group consisting of a water soluble phenolic resin and a water dispersible phenolic resin along with carbon powder (d) to form a precursor sheet; and [3] a step for carbonizing the precursor sheet at the temperature of 1000° C. or higher, after the step [2].Type: GrantFiled: March 29, 2013Date of Patent: July 25, 2017Assignee: Mitsubishi Chemical CorporationInventor: Hiroto Tatsuno
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Patent number: 9705137Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.Type: GrantFiled: January 20, 2012Date of Patent: July 11, 2017Assignee: MITSUBISHI RAYON CO., LTD.Inventors: Hiroto Tatsuno, Kazuhiro Sumioka, Tadao Samejima
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Publication number: 20160204443Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.Type: ApplicationFiled: March 22, 2016Publication date: July 14, 2016Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Hiroto TATSUNO, Kazuhiro Sumioka, Tadao Samejima
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Publication number: 20150086901Abstract: The present invention relates to a method for manufacturing a porous electrode base material including the following steps [1] to [3]: [1] a step for dispersing short carbon fibers (A) to form a sheet-form product; [2] a step for adding, to the sheet-form product, at least one phenolic resin (c) selected from a group consisting of a water soluble phenolic resin and a water dispersible phenolic resin along with carbon powder (d) to form a precursor sheet; and [3] a step for carbonizing the precursor sheet at the temperature of 1000° C. or higher, after the step [2].Type: ApplicationFiled: March 29, 2013Publication date: March 26, 2015Applicant: Mitsubishi Rayon Co., Ltd.Inventor: Hiroto Tatsuno
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Publication number: 20130323620Abstract: According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher.Type: ApplicationFiled: January 20, 2012Publication date: December 5, 2013Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Hiroto Tatsuno, Kazuhiro Sumioka, Tadao Samejima
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Publication number: 20120115063Abstract: The present invention provides a porous electrode substrate that has high sheet strength, low production cost, and sufficient gas permeability and electrical conductivity, and a method for producing the same. In the present invention, the porous electrode substrate is produced by producing a precursor sheet including short carbon fibers (A), and one or more types of short precursor fibers (b) that undergo oxidation and/or one or more types of fibrillar precursor fibers (b?) that undergo oxidation, all of which are dispersed in a two-dimensional plane, subjecting the precursor sheet to entanglement treatment to form a three-dimensional entangled structure, then impregnating the precursor sheet with carbon powder and fluorine-based resin, and further heat treating the precursor sheet at a temperature of 150° C. or higher and lower than 400° C.Type: ApplicationFiled: November 24, 2010Publication date: May 10, 2012Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Kazuhiro Sumioka, Hiroto Tatsuno