Patents by Inventor Hiroyuki Yashima
Hiroyuki Yashima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10294110Abstract: [Problem] To provide a novel production method for pentachlorodisilane and to obtain pentachlorodisilane having a purity of 90 mass % or more by carrying out this production method. [Solution] A production method provided with: a high-temperature reaction step in which a raw material gas containing vaporized tetrachlorosilane and hydrogen is reacted at a high temperature in order to obtain a reaction product gas containing trichlorosilane; a pentachlorodisilane generation step in which the reaction product gas obtained in the high-temperature reaction step is brought into contact with a cooling liquid obtained by circulative cooling of a condensate that is generated by cooling the reaction product gas, the reaction product gas is quickly cooled, and pentachlorodisilane is generated within the condensate; and a recovery step in which the generated pentachlorodisilane is recovered.Type: GrantFiled: September 25, 2015Date of Patent: May 21, 2019Assignees: DENKA COMPANY LIMTIED, L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Hiroyuki Yashima, Takahiro Kozuka, Seiichi Terasaki, Jean-Marc Girard
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Publication number: 20170283267Abstract: [Problem] To provide a novel production method for pentachlorodisilane and to obtain pentachlorodisilane having a purity of 90 mass % or more by carrying out this production method. [Solution] A production method provided with: a high-temperature reaction step in which a raw material gas containing vaporized tetrachlorosilane and hydrogen is reacted at a high temperature in order to obtain a reaction product gas containing trichlorosilane; a pentachlorodisilane generation step in which the reaction product gas obtained in the high-temperature reaction step is brought into contact with a cooling liquid obtained by circulative cooling of a condensate that is generated by cooling the reaction product gas, the reaction product gas is quickly cooled, and pentachlorodisilane is generated within the condensate; and a recovery step in which the generated pentachlorodisilane is recovered.Type: ApplicationFiled: September 25, 2015Publication date: October 5, 2017Applicants: Denka Company Limited, L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EX PLOITATION DES PROCEDES GEORGES CLAUDEInventors: Hiroyuki YASHIMA, Takahiro KOZUKA, Seiichi TERASAKI, Jean-Marc GIRARD
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Patent number: 9464146Abstract: Provided are a chloroprene rubber that is less adhesive to rolls and gives a vulcanized product superior in physical properties, a production method thereof, a chloroprene rubber composition and a vulcanized product thereof. A chloroprene rubber comprising a steroid skeleton-containing compound. The chloroprene rubber may contain a steroid skeleton-containing compound in an amount of 0.01 to 1 mass %. A vulcanized product is prepared by vulcanizing a composition containing the chloroprene rubber. The chloroprene rubber can be prepared, for example, by emulsion-polymerizing chloroprene alone or chloroprene and other monomers in combination in the presence of a rosin containing a steroid skeleton-containing compound.Type: GrantFiled: June 17, 2013Date of Patent: October 11, 2016Assignee: DENKA COMPANY LIMITEDInventors: Sachiyo Kishi, Hiroyuki Yashima, Hidehiro Matsuda
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Patent number: 9394454Abstract: Provided is a polychloroprene latex that shows favorable low-temperature stability without deterioration in the rubber agglutinating property during production of the dip-molded article, a rubber composition, and a dip-molded article, prepared by using the same. Prepared is a polychloroprene latex of a chloroprene copolymer obtained by polymerization of raw monomers at least containing chloroprene and 2,3-dichloro-1,3-butadiene, which is dispersed in water, wherein the 2,3-dichloro-1,3-butadiene content in the raw monomers is controlled to 1 to 30 mass % and the potassium ion content is adjusted to 0.7 to 1.5 parts by mass and the sodium ion content to 0.2 part or less by mass with respect to 100 parts by mass of the solid matter. In addition, a metal oxide: 1 to 10 parts by mass, sulfur: 0.1 to 3 parts by mass, an aging inhibitor: 0.1 to 5 parts by mass and a surfactant: 0.Type: GrantFiled: March 29, 2012Date of Patent: July 19, 2016Assignee: DENKA COMPANY LIMITEDInventors: Ikuka Hashimoto, Hiroyuki Yashima, Takeo Mori
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Patent number: 9328228Abstract: An object of the invention is to provide a chloroprene polymer composition resistant to discoloration under heat or light. Provided is a chloroprene rubber composition, prepared by carrying out emulsion polymerization in the presence of 0.5 to 7.0 parts by mass of a rosin acid salt as emulsifier and terminating the emulsion polymerization by addition of a polymerization inhibitor and a phosphorus- or phenol-based compound as antioxidant. It is possible according to the invention to obtain a chloroprene polymer composition superior in discoloration resistance under heat or light. The chloroprene polymer composition according to the present invention can be used favorably for adhesion of cloths, leathers, foamed sheets, papers, woods, shoe parts, and others.Type: GrantFiled: February 7, 2013Date of Patent: May 3, 2016Assignee: DENKA COMPANY LIMITEDInventors: Hiroyuki Yashima, Sachiyo Kishi, Kunihiko Otsuka, Yuhei Ishigaki
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Publication number: 20160017130Abstract: An object of the invention is to provide a chloroprene polymer composition resistant to discoloration under heat or light. Provided is a chloroprene rubber composition, prepared by carrying out emulsion polymerization in the presence of 0.5 to 7.0 parts by mass of a rosin acid salt as emulsifier and terminating the emulsion polymerization by addition of a polymerization inhibitor and a phosphorus- or phenol-based compound as antioxidant. It is possible according to the invention to obtain a chloroprene polymer composition superior in discoloration resistance under heat or light. The chloroprene polymer composition according to the present invention can be used favorably for adhesion of cloths, leathers, foamed sheets, papers, woods, shoe parts, and others.Type: ApplicationFiled: February 7, 2013Publication date: January 21, 2016Inventors: Hiroyuki YASHIMA, Sachiyo KISHI, Kunihiko OTSUKA, Yuhei ISHIGAKI
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Publication number: 20150183900Abstract: Provided are a chloroprene rubber that is less adhesive to rolls and gives a vulcanized product superior in physical properties, a production method thereof, a chloroprene rubber composition and a vulcanized product thereof. A chloroprene rubber comprising a steroid skeleton-containing compound. The chloroprene rubber may contain a steroid skeleton-containing compound in an amount of 0.01 to 1 mass %. A vulcanized product is prepared by vulcanizing a composition containing the chloroprene rubber. The chloroprene rubber can be prepared, for example, by emulsion-polymerizing chloroprene alone or chloroprene and other monomers in combination in the presence of a rosin containing a steroid skeleton-containing compound.Type: ApplicationFiled: June 17, 2013Publication date: July 2, 2015Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Sachiyo Kishi, Hiroyuki Yashima, Hidehiro Matsuda
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Publication number: 20140011936Abstract: Provided is a polychloroprene latex that shows favorable low-temperature stability without deterioration in the rubber agglutinating property during production of the dip-molded article, a rubber composition, and a dip-molded article, prepared by using the same. Prepared is a polychloroprene latex of a chloroprene copolymer obtained by polymerization of raw monomers at least containing chloroprene and 2,3-dichloro-1,3-butadiene, which is dispersed in water, wherein the 2,3-dichloro-1,3-butadiene content in the raw monomers is controlled to 1 to 30 mass % and the potassium ion content is adjusted to 0.7 to 1.5 parts by mass and the sodium ion content to 0.2 part or less by mass with respect to 100 parts by mass of the solid matter. In addition, a metal oxide: 1 to 10 parts by mass, sulfur: 0.1 to 3 parts by mass, an aging inhibitor: 0.1 to 5 parts by mass and a surfactant: 0.Type: ApplicationFiled: March 29, 2012Publication date: January 9, 2014Applicant: Denki Kagaku Kogyo Kabushiki KaishaInventors: Ikuka Hashimoto, Hiroyuki Yashima, Takeo Mori
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Publication number: 20120022196Abstract: Provided is a polychloroprene elastomer composition superior in extrusion processability and mechanical properties, a production method thereof, and vulcanized and molded articles thereof. A polychloroprene elastomer composition, comprising 100 parts by mass of a polychloroprene elastomer containing a polychloroprene sol and a polychloroprene gel and 0.2 to 5 parts by mass of a thiuram compound, wherein the blending rate of the polychloroprene sol to the polychloroprene gel (sol/gel) is 30/70 to 80/20 by mass.Type: ApplicationFiled: January 21, 2010Publication date: January 26, 2012Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Toshiaki Miyauchi, Hiroyuki Yashima, Toshiaki Otsu
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Patent number: 7589146Abstract: A water base adhesive and a latex composition being a base of water base primer are provided. The latex composition comprises 100 parts by mass of a polychloroprene latex and from 1 to 70 parts by mass of an EVA resin having a mass ratio of ethylene being at least 40%, as main components.Type: GrantFiled: April 18, 2003Date of Patent: September 15, 2009Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Yashima, Kenji Mochizuki
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Patent number: 7514487Abstract: To provide a polychloroprene latex excellent in stability, a process for its production, and an aqueous adhesive composition employing it, excellent in the adhesive performance. A polychloroprene latex obtained by emulsion-polymerizing chloroprene, or chloroprene and a monomer copolymerizable with chloroprene, in the presence of from 0.5 to 15 parts by mass of a specific nonionic emulsifier and from 0.05 to 2 parts by mass of a specific anionic emulsifier, per 100 parts by mass of the whole monomer.Type: GrantFiled: December 19, 2003Date of Patent: April 7, 2009Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Yashima, Kenji Mochizuki
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Patent number: 7214634Abstract: A laminated product is provided which has no problems concerning hygienic safety or environment accompanying the use of solvent-based adhesives and which has been tenaciously bonded in a degree equal or superior to that attainable with conventional CR solvent-based adhesives. The laminated product is obtained by bonding a porous organic material and a cloth with an adhesive comprising, as major ingredients, a polychloroprene latex which is obtained by polymerizing 100 parts by mass of chloroprene with more than 0 part by mass and less than 2 parts by mass of an ethylenically unsaturated carboxylic acid in the presence of from 0.5 to 4 parts by mass of a polyvinyl alcohol and then adding a pH adjustor and a radical scavenger and which has a gel content in the chloroprene polymer of from 10 to 60 mass % and a pH of from 6 to 10, a tackifier resin and a metal oxide.Type: GrantFiled: April 9, 2002Date of Patent: May 8, 2007Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Yashima, Kosuke Watanabe
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Publication number: 20060063885Abstract: To provide a polychloroprene latex excellent in stability, a process for its production, and an aqueous adhesive composition employing it, excellent in the adhesive performance. A polychloroprene latex obtained by emulsion-polymerizing chloroprene, or chloroprene and a monomer copolymerizable with chloroprene, in the presence of from 0.5 to 15 parts by mass of a specific nonionic emulsifier and from 0.05 to 2 parts by mass of a specific anionic emulsifier, per 100 parts by mass of the whole monomer.Type: ApplicationFiled: December 19, 2003Publication date: March 23, 2006Applicant: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Yashima, Kenji Mochizuki
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Publication number: 20050182173Abstract: A water base adhesive and a latex composition being a base of water base primer are provided. The latex composition comprises 100 parts by mass of a polychloroprene latex and from 1 to 70 parts by mass of an EVA resin having a mass ratio of ethylene being at least 40%, as main components.Type: ApplicationFiled: April 18, 2003Publication date: August 18, 2005Applicant: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Yashima, Kenji Mochizuki
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Publication number: 20040096644Abstract: A laminated product is provided which has no problems concerning hygienic safety or environment accompanying the use of solvent-based adhesives and which has been tenaciously bonded in a degree equal or superior to that attainable with conventional CR solvent-based adhesives. The laminated product is obtained by bonding a porous organic material and a cloth with an adhesive comprising, as major ingredients, a polychloroprene latex which is obtained by polymerizing 100 parts by mass of chloroprene with more than 0 part by mass and less than 2 parts by mass of an ethylenically unsaturated carboxylic acid in the presence of from 0.5 to 4 parts by mass of a polyvinyl alcohol and then adding a pH adjustor and a radical scavenger and which has a gel content in the chloroprene polymer of from 10 to 60 mass % and a pH of from 6 to 10, a tackifier resin and a metal oxide.Type: ApplicationFiled: October 9, 2003Publication date: May 20, 2004Inventors: Hiroyuki Yashima, Kosuke Watanabe
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Patent number: 6633414Abstract: An apparatus has a printer unit, a scanner unit, a front cover that opens upward in the direction of the back surface and forms a transport path of scanner paper discharged by the scanner unit, and mounting members provided on the front cover for detachably mounting the scanner unit in such an attitude that the main scanning direction becomes horizontal. Furthermore, as the need arises, the apparatus may have a scanner paper tray member rotatably connected to the front cover at a location higher than the mounting members for feeding scanner paper to the scanner unit.Type: GrantFiled: June 30, 1999Date of Patent: October 14, 2003Assignees: PFU Limited, Fujitsu LimitedInventors: Yasuhiro Matsuda, Ryou Iwamoto, Hiroyuki Yashima, Yoshiki Tsutiyama, Yasuhiko Kitagawa, Kazuya Yoshida, Satoshi Ishida, Yasuhiro Abe, Akira Yamada, Makoto Mochizuki, Yoshitomo Sasaki
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Patent number: 5554688Abstract: A thermoplastic resin composition comprising (A) 100 parts by weight of a diene rubber-containing styrene resin, (B) from 1 to 50 parts by weight of a vinyl resin-containing acrylic rubber polymer obtained by polymerizing from 1 to 200 parts by weight of at least one vinyl monomer in the presence of 100 parts by weight of an acrylic rubber polymer, and (C) from 0 to 48 parts by weight of a polymer of a vinyl monomer having a weight average molecular weight of at least 200,000, provided that the sum of components (B) and (C) is from 1 to 60 parts by weight.Type: GrantFiled: August 3, 1995Date of Patent: September 10, 1996Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Yashima, Katsuji Horio
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Patent number: 4802018Abstract: A marking apparatus has a marking designation switch which is depressed when an image of interest appears on a monitor while a plurality of image data from a photographic unit are displayed on the monitor. In response to a marking designation signal generated upon depression of the marking switch, a mark signal is added to the image data corresponding to the marking designation signal and is stored in a frame memory.Type: GrantFiled: December 1, 1987Date of Patent: January 31, 1989Assignee: Olympus Optical Co., Ltd.Inventors: Kowji Tanikawa, Tadashi Kato, Masahide Kanno, Hiroyuki Yashima, Akira Matsueda, Takao Rokutan, Hisayuki Harada, Isao Hirosawa, Hiroki Hibino
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Patent number: 4463269Abstract: In a pump drive circuit, a power source voltage signal supplied to the pump is phase-controlled by a triac connected between the pump and the power source. The period of triggering the triac is determined by a time constant circuit of a UJT, a capacitor and a resistor circuit. The power source voltage signal has its frequency determined by a frequency discrimination circuit. The resistance value of the resistor circuit is selected in accordance with the result of the discrimination. Accordingly, the pump is applied with a voltage signal the phase of which is controlled in accordance with the power source frequency, and is thus driven to maintain a predetermined output.Type: GrantFiled: October 28, 1982Date of Patent: July 31, 1984Assignee: Olympus Optical Co., Ltd.Inventor: Hiroyuki Yashima