Abstract: The present invention relates to a process of recovering aromatic dicarboxylic acids with low metal contaminants from manufactured articles and/or articles contaminated with PVC or chlorinated compounds, made of or containing aromatic polyester resins, such as beverage bottles, fibers and films, or from waste from processing of these resins. In particular, the invention relates to the recovery of terephthalic acid, isophthalic acid and 2,6-naphthalene dicarboxylic acid from bottles for recycling which are made of PET, PEN or aromatic polyester copolymers.

Abstract: The present invention relates to a process of recovering aromatic dicarboxylic acids with low metal contaminants from manufactured articles, such as beverage bottles, fibers and films, comprising aromatic polyesters, whether or not those articles are contaminated with PVC or chlorinated compounds, or from waste from processing of these polyesters. In particular, the invention relates to the recovery of terephthalic acid, isophthalic acid and 2,6-naphthalene dicarboxylic acid from bottles for recycling which are made of PET, PEN or aromatic polyester copolymers.

Abstract: The present invention relates to a process for preparing high purity terephthalic acid by catalytic, liquid phase oxidation of p-xylene utilizing a partially homogeneous reaction in the presence of a very specific catalyst. The process produces a high purity terephthalic acid without the secondary purification step currently practiced.

Abstract: Flexible, liquid fillable bottles of polyester resin are provided which have a capacity in liters relative to the weight thereof in grams excluding the neck of from 0.15 to 0.5 and from 0.2 to 1.5 for larger capacities. The bottles are obtained by blowing parisons freely or in a rigid container, the shape of which the bottles assume, said parisons being of polyester resin with suitable rheological properties.

Abstract: An oxygen scavenging composition is set forth in which the composition contains a protic solvent hydrolysable halogen compound which is deposited upon oxidizable metal particles, contacting the metal with an essentially moisture free liquid containing the protic solvent hydrolysable halogen compound and then evaporating, if necessary, any remaining solvent from the solid. Also set forth are walls of containers and preforms which contain this composition.

Abstract: Compositions suitable for preparing transparent articles comprising an aromatic polyester resin selected from a copolyalkylene terephthalate containing from 3 to 15% by moles of units derived from isophtalic acid and/or a naphtalene dicarboxylic acid and a polyxylylene amide, preferably poly (m.xylylene adipamide), in which the polymide is dispersed in the polyester resin as domains with average numeral size of 30 to 200 nm. The compositions are obtained by premelt-mixing the polyester with a dianhydride of a tetracarboxylic acid prior mixing the polyxylylene amide using melt viscosity ration between the polyester resin and the polyxylylene amide higher that 1.5:1, preferably from 3:1 to 8:1.

Abstract: Compositions suitable for preparing transparent articles comprising an aromatic polyester resin selected from a copolyalkylene terephthalate containing from 3 to 15% by moles of units derived from isophtalic acid and/or a naphtalene dicarboxylic acid and a polyxylylene amide, preferably poly (m.xylylene adipamide), in which the polymide is dispersed in the polyester resin as domains with average numeral size of 30 to 200 nm. The compositions are obtained by premelt-mixing the polyester with a dianhydride of a tetracarboxylic acid prior mixing the polyxylylene amide using melt viscosity ration between the polyester resin and the polyxylylene amide higher that 1.5:1, preferably from 3:1 to 8:1.

Abstract: Flexible, liquid-fillable bottles of polyester resin are provided, which have a capacity in litres relative to the weight thereof in grams excluding the neck of from 0.15 to 0.5 for capacities up to 5 l and from 0.2 to 1.5 for larger capacities.

Abstract: Use of masterbatches of polyarylene amides in polyester resins containing from 10 to 40% by weight of polyamide resin in the preparation of mixtures of aromatic polyester rensins added with the polyamide resin at a concentration of less than 15% by weight.

Abstract: A method for the recovery of dicarboxylic aromatic acids, in particular terephthalic acid, from manufactured aromatic polyester-resin articles for recycling, wherein the article, fragmented into chip form, is reacted in solution in a carboxylic acid with 2-6 carbon atoms and with a pKa from 4 to 6, preferably glacial acetic acid, in the presence of catalytic quantities of a strong acid with a pKa of less than 1, preferably aqueous hydrochloric acid or sulfuric acid, operating at temperatures from 160° to 250° C.

Abstract: Treatment for the dimensional stabilization of containers in PET or COPET obtained by injection-blow molding consisting in subjecting to beat treatment during the blowing phase, preforms obtained from PET or COPET upgraded in the solid state in the presence of small quantities (0.01-0.2% by weight) of a dianhydride of an aromatic tettacarboxylic acid, preferably pyromellitic dianhydride.

Abstract: Flame retardant compositions comprising a polyester resin having a melt strength higher than 8 centinewton an intrinsic viscosity greater than 0.8 dl/g, suitable for the preparation of foamed cellular material and a flame retardant compound capable of not reducing below 3 Nm the torque intake of the resin in a heating test at 280° C. under nitrogen for 10 minutes in the presence of 10% by weight of the flame retardant compound.

Abstract: A method for the recovery of dicarboxylic aromatic acids, in particular terephthalic acid, from manufactured aromatic polyester-resin articles for recycling, wherein the article, fragmented into chip form, is reacted in solution in a carboxylic acid with 2-6 carbon atoms and with a pKa from 4 to 6, preferably glacial acetic acid, in the presence of catalytic quantities of a strong acid with a pKa of less than 1, preferably aqueous hydrochloric acid or sulphuric acid, operating at temperatures from 160° to 250° C.

Abstract: Use of masterbatches of polyarylene amides in polyester resins containing from 10 to 40% by weight of polyamide resin in the preparation of mixtures of aromatic polyester rensins added with the polyamide resin at a concentration of less than 15% by weight.

Abstract: Transparent, articles, in particular sheets, having a thickness greater than 5 mm obtained from polyalkylene terephthalate/isophthalate resin containing 5-20% of isophthalic, acid units,. characterised by an intrinsic viscosity greater than 0.8 dl/g; a melt strength at 280° C. greater than 1 cN and a melt viscosity at 280° C. greater than 2000 Pa·s for shear rates tending to zero and not less than 200 Pa·s for shear rates of 1000 sec−1.

Abstract: Process for the production of aromatic polyester resins starting from resins with an IV from 0.1 to 0.4 dl/g comprising the steps of blending the resin with a dianhydride of a tetracarboxylic acid, extruding the resin under the form of a strand, cooling the strand or the chips obtainable by cutting the strand, at a temperature between 150° C. and 210° C. and maintaining the same temperature for sufficient time to obtain a crystalline product wherein the DSC curves of the same do not show presence of premelt peaks or only so in a negligible amount.

Abstract: Process for the crystallization of aromatic polyester resins having IV between 0,5 and 0.7 dl/g wherein the resin is extruded in the form of a strand at extruder exit or the chips obtained by cutting the strand are crystallized maintaining them at temperature between 160° C. and 220° C. for sufficient time to obtain a crystallized product wherein the DSC curves do not show the presence of practically any premelt peaks.

Abstract: Aromatic polyester resins, having improved mechanical and hydrolysis resistant properties, by mixing said aromatic polyester resin with a phenoxy resin, a dianhydride of a tetracarboxylic acid and liquid crystals.

Abstract: A process for the preparation of aromatic polyester resins, in which the resin obtained from the polycondensation phase in the molten state conducted by utilizing a titanium based compound as a catalyst, is subjected to a solid state polycondensation reaction in the presence of a dianhydride of a tetracarboxylic acid.

Abstract: A foamed cellular material which can be obtained from foamed aromatic polyester resins with a bulk density of 50 to 700 kg/m3 by heating in vacuum to temperatures which are higher than the Tg of the material and lower than its melting point. The foamed material, generally in the form of a sheet or panel, has high-level characteristics in terms of flexibility and dimensional thermostability depending on the degree of crystallinity after the vacuum treatment.