Abstract: Various embodiments disclosed relate to a surfacing film. The surfacing film includes a base layer. The base layer includes a thermoplastic polyurethane film comprising a reaction product of a reaction mixture of a diisocyanate, a polyester polyol having a melting temperature of at least about 30° C.; and a diol chain extender. There are many reasons to use the surfacing film including easier and more cost effective manufacturing of the surfacing film by directly extruding the base layer by mixing the reaction mixture in an extruder. Another reason to use the surfacing film is that the film has improved resistance to discoloration. Another reason to use the film is that the film shows good toughness.

Abstract: Described herein is a multilayered article (10) and methods of making and using such articles. The multilayered article (10) comprises: ?(a) a microsphere layer (11) comprising a plurality of microspheres disposed in a monolayer; ?(b) a bead bonding layer (12) comprising a first major surface and a second opposing major surface and the plurality of microspheres is partially embedded in the first major surface of the bead bonding layer, and comprises a thermoset polyurethane having a glass transition temperature of at least 35° C.; ?(c) a primer layer (14) disposed on the second major surface of the bead bonding layer wherein the primer layer comprises a copolymer of polyurea and polyurethane and wherein the primer layer is covalently attached to the bead bonding layer via urea linkages; and ?(d) an elastomeric layer (16) disposed on the primer layer opposite the bead bonding layer, wherein the elastomeric layer comprises a polyurethane thermoplastic elastomer.

Abstract: The present disclosure provides an extrudable article and a composition, each including at least one polyurethane including hydroxyl groups and latent isocyanate groups in the form of uretdione groups. The hydroxyl groups are present on a first polyurethane and the latent isocyanate groups are present on either the first polyurethane or a second polyurethane and a ratio of the latent isocyanate groups to the hydroxyl groups is greater than 1.2:1. A method of making the extrudable article is provided including reacting in an extruder a polymerizable composition including a uretdione-containing material including a reaction product of a diisocyanate reacted with itself, a hydroxyl-containing compound, and an isocyanate-containing compound. A method of making a core-sheath filament is provided including forming a core composition of the at least one polyurethane and wrapping a sheath composition including an ethylene copolymer or a polyolefin around the core composition.

Abstract: Provided is a surfacing film that includes a plurality of layers. The layers include a first clear coat layer made from a crosslinked polyurethane that is a reaction product of a reactive mixture including an isocyanate and a polyol containing a styrene repeat unit and a hydroxyl-containing (meth)acrylate repeat unit. The surfacing film further includes a bulk layer made from a thermoplastic polyurethane and an adhesive layer. Optionally, the surfacing film includes second clear coat layer, which can be made from a polyurethane that is at least partially crosslinked. The resulting surfacing film can display high stain resistance, high peel strength, superior scratch resistance and self-healing properties.

Abstract: The present disclosure relates to polyurethanes comprising a reaction product of a reactive mixture including a polyol having a number average molecular weight of at least 400 Daltons, a diol chain extender having a molecular weight less than 400 Daltons, a diisocyanate; and a multifunctional amine. The present disclosure further provides polishing layers and polishing pads fabricated therefrom. Additionally, the present disclosure provides polishing systems and polishing methods employing said polishing layers and polishing pads.

Abstract: A solar cell assembly is described that comprises a barrier assembly disposed on or around a photovoltaic cell, wherein the barrier assembly comprises a barrier film and a polyurethane outer protective film layer bonded directly to exposed major surface of the barrier film, wherein the barrier assembly disposed above the photovoltaic cell and the polyurethane outer protective film layer forms a top surface of the solar cell assembly that is exposed to incoming light.

Abstract: The present disclosure relates to polyurethane comprising a reaction product of a reactive mixture including a polyester polyol, a diol chain extender, a diisocyanate; and a reactive, tertiary amine. The present disclosure further provides polishing layers and polishing pads fabricated therefrom. Additionally, the present disclosure provides polishing systems and polishing methods employing said polishing layers and polishing pads.

Abstract: This disclosure describes co-extruded multilayer articles including at least one continuous layer and one discontinuous layer, as well as systems and techniques for the manufacture of co-extruded multilayer articles. For example, a co-extruded multilayer article is described that includes a body having a plurality of layers, where a first layer of the plurality of layers is formed from a first material and is continuous along a longitudinal axis of the body, and a second layer of the plurality of layers is formed from a second material and is discontinuously co-extruded along the longitudinal axis.

Abstract: This disclosure describes co-extruded multilayer articles including at least one continuous layer and one discontinuous layer, as well as systems and techniques for the manufacture of co-extruded multilayer articles. For example, a co-extruded multilayer article is described that includes a body having a plurality of layers, where a first layer of the plurality of layers is formed from a first material and is continuous along a longitudinal axis of the body, and a second layer of the plurality of layers is formed from a second material and is discontinuously co-extruded along the longitudinal axis.

Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35° C. and less than 70° C.

Abstract: Blend compositions include at least one polydiorganosiloxane polyoxamide copolymer, and at least 70% by weight of at least one silicone tackifying resin. The blend composition is non-tacky at room temperature up to a temperature of at least 100° C. The polydiorganosiloxane polyoxamide copolymer can be a linear or branched copolymer. The blend compositions provide solid, non-powdery, and non-tacky delivery vehicles for silicone tackifying resin.

Abstract: An adhesive article including: a coextruded polymeric backing that includes: a first layer including an amorphous polyamide, the first layer having first and second opposing major surfaces; and a second layer including a polar-modified polyolefin, the second layer having first and second opposing major surfaces; wherein the first major surface of the second layer is in contact with the second major surface of the first layer; and an acrylic pressure sensitive adhesive layer in contact with the first major surface of the first layer of the backing.

Abstract: A method includes reactively extruding a polymeric composition to form a film. The polymeric composition includes a polyisocyanate and at least one dimer fatty diol.

Abstract: A dental appliance includes a polymeric shell with an arrangement of one or more cavities configured to receive one or more teeth, and the polymeric shell includes an antimicrobial lipid, such as monolaurin, and optionally an enhancer.

Abstract: A display system including a lightguide and first and second reflective layers disposed on opposite sides of the lightguide is provided. The lightguide has opposing first and second major surfaces and includes a light extraction pattern for extracting light that would otherwise be confined and propagate within the lightguide primarily by total internal reflection. Light extracted by the light extraction pattern exits the lightguide through at least one of the first and second major surfaces of the lightguide. Each of the first and second reflective layers has an average specular reflectance of at least 50% in a predetermined wavelength range. The light extraction pattern may be repeatedly imaged by the first and second reflective layers to produce three-dimensional stacked images of the light extraction pattern.

Abstract: Blend compositions include at least one polydiorganosiloxane polyoxamide copolymer, and at least 70% by weight of at least one silicone tackifying resin. The blend composition is non-tacky at room temperature up to a temperature of at least 100° C. The polydiorganosiloxane polyoxamide copolymer can be a linear or branched copolymer. The blend compositions provide solid, non-powdery, and non-tacky delivery vehicles for silicone tackifying resin.

Abstract: Various embodiments disclosed relate to a surfacing film. The surfacing film includes a base layer. The base layer includes a thermoplastic polyurethane film comprising a reaction product of a reaction mixture of a diisocyanate, a polyester polyol having a melting temperature of at least about 30° C.; and a diol chain extender. There are many reasons to use the surfacing film including easier and more cost effective manufacturing of the surfacing film by directly extruding the base layer by mixing the reaction mixture in an extruder. Another reason to use the surfacing film is that the film has improved resistance to discoloration. Another reason to use the film is that the film shows good toughness.

Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35° C. and less than 70° C.

Abstract: The disclosed aliphatic thermoplastic polyurethane composition is well suited for use in thin, flexible light directing articles to impart flexibility, toughness, or protection to the light directing articles that contain optically active elements. The disclosed aliphatic thermoplastic polyurethanes have improved thermostability at higher temperatures. Specifically, the disclosed aliphatic thermoplastic polyurethanes have a cross-over temperature greater than 110° C. In one embodiment, the cross-over temperature is greater than 130° C. In one embodiment, the cross-over temperature is less than 170° C. and a Tg greater than 35 C and less than 70 C.

Abstract: This disclosure describes co-extruded multilayer articles including at least one continuous layer and one discontinuous layer, as well as systems and techniques for the manufacture of co-extruded multilayer articles. For example, a co-extruded multilayer article is described that includes a body having a plurality of layers, where a first layer of the plurality of layers is formed from a first material and is continuous along a longitudinal axis of the body, and a second layer of the plurality of layers is formed from a second material and is discontinuously co-extruded along the longitudinal axis.