Abstract: The present invention comprises a solar cell module and a method of encapsulating the module. The solar cell module comprises a rigid or flexible superstrate and/or substrate having one or more solar cells, and an encapsulent which is a cured liquid silicone encapsulant. The encapsulant composition preferably comprises a liquid diorganopolysiloxane having at least two Si-alkenyl groups per molecule, a silicone resin containing at least two alkenyl groups; a cross-linking agent in the form of a polyorganosiloxane having at least two silicon-bonded hydrogen atoms per molecule, in an amount such that the ratio of the number of moles of silicon-bonded hydrogen to the total number of moles of silicon-bonded alkenyl groups is from 0.1:1 to 5:1; and a hydrosilylation catalyst, preferably a platinum based catalyst.

Abstract: The present invention comprises a solar cell module and a method of encapsulating the module. The solar cell module comprises a rigid or flexible superstrate and/or substrate having one or more solar cells, and an encapsulant which is a cured liquid silicone encapsulant. The encapsulant composition preferably comprises a liquid diorganopolysiloxane having at least two Si-alkenyl groups per molecule, a silicone resin containing at least two alkenyl groups; a cross-linking agent in the form of a polyorganosiloxane having at least two silicon-bonded hydrogen atoms per molecule, in an amount such that the ratio of the number of moles of silicon-bonded hydrogen to the total number of moles of silicon-bonded alkenyl groups is from 0.1:1 to 5:1; and a hydrosilylation catalyst. The continuous solar cell module encapsulation process comprises uniformly applying a predetermined volume of a liquid silicone encapsulant onto a solar cell module and curing said encapsulant.

Abstract: The present invention comprises a solar cell module and a method of encapsulating the module. The solar cell module comprises a rigid or flexible superstrate and/or substrate having one or more solar cells, and an encapsulant which is a cured liquid silicone encapsulant. The encapsulant composition preferably comprises a liquid diorganopolysiloxane having at least two Si-alkenyl groups per molecule, a silicone resin containing at least two alkenyl groups; a cross-linking agent in the form of a polyorganosiloxane having at least two silicon-bonded hydrogen atoms per molecule, in an amount such that the ratio of the number of moles of silicon-bonded hydrogen to the total number of moles of silicon-bonded alkenyl groups is from 0.1:1 to 5:1; and a hydrosilylation catalyst. The continuous solar cell module encapsulation process comprises uniformly applying a predetermined volume of a liquid silicone encapsulant onto a solar cell module and curing said encapsulant.

Abstract: The specification describes preparation of materials comprising selected boron anions and processes using them as catalysts for condensation reaction of compounds having silicon-bonded hydroxy or alkoxy groups. Preferred anion compounds comprise borates incorporating quadri-substituted boron in which the substituents include highly halogenated hydrocarbon groups for example pentafluorinated phenyl groups or bis (trifluoromethyl) phenyl groups. Preferred anions are {B(C6F5)4}− and {B(C6(CF3)2H3)4}−.

Abstract: A moisture curable composition is claimed comprising (a) a condensation product of a polyacid chloride with an alkylene or oxyalkylene polymer having substituent groups condensible therewith with an organosilicon compound having at least one silicon-bonded group --R(NHR.sup.1).sub.m NH.sub.2 e.g. a material of the general formula ##STR1## wherein each R may be the same or different and represent a linking group, each R' represents a group --R(NHR.sup.1).sub.m NH.sub.2, a hydrolysable group R", a group R'" or a group R'Si(OSiR.sup.1.sub.2).sub.s --O-- where R'" is a hydrocarbon group, m is from 0 to 10 and s is from 0 to 1500 and (b) a curative. Preferred materials are amino silanes in which R" is an oximo, alkoxy, alkenyloxy or alkoxyalkoxy group, --R(NHR.sup.1).sub.m NH.sub.2 is aminopropyl and m is 0. The aminosilane is preferably .gamma.-aminopropyltrimethoxysilane or .gamma.-aminopropyltriethoxysilane and the organic polymer is a polyoxyalkylene glycol.

Abstract: Polymers are prepared by reaction between a polymer prepared by reaction between (A) an OH terminated reaction product of a polyacid chloride and an organic polymer having substituent groups condensable therewith and (B) a silane or siloxane having a group capable of reaction with substituent groups of the reaction product (A). Reaction product (A) is preferably derived from a polyoxyalkylene glycol and a diacid chloride. Silane or siloxane (B) is preferably an epoxy silane and preferably has at least one silicon- bonded hydrolysable group. Preferred polymers are employed in moisture curable composition, e.g. as sealants.

Abstract: A method is provided for the direct synthesis of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or of tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.

Abstract: A method of making organopolysiloxanes comprises contacting organosilicon compounds having at least one unit ##EQU1## wherein R.degree. is hydrogen, hydroxyl, a C.sub.1-18 hydrocarbon, substituted hydrocarbon or hydrocarbonoxy group and a has a value of from 0 to 4 with a phosphonitrile halide AB, wherein A is a phosphonitrile halide cation [X(PX.sub.2 .dbd.N).sub.n PX.sub.3 ].sup.+, wherein X is halide and n is from 1 to 8 and B is an anion derived from a Lewis acid not containing a P atom, e.g. [MX.sub.(v-t+1) R.sup.2 .sub.t ].sup.-. The method is particularly useful for condensation of silanol end-blocked siloxanes.

Abstract: A method of making a dispersion of a high viscosity siloxane in a volatile, especially cyclic siloxane, comprises first dispersing organopolysiloxanes having at least 2 Si--OR groups, wherein R is H or alkyl in a volatile siloxane and adding a catalyst which is either a phosphonitrile halide having the general formula [X(PX.sub.2 .dbd.N).sub.n PX.sub.3 ].sup.+ [MX.sub.(v-t+1) R.sub.t ].sup.-, or a heterogeneous catalyst selected from Li, Mg, Ca, Sr or Ba hydroxide, Na or K borate or phosphate, Rb or Cs carbonate or carboxylates of Rb or Cs wherein M is an element having an electronegativity of from 1.0 to 2.0, R is alkyl, X is halide, n is 1 to 6, v is the valence of M and t is from 0 to (v-1).