Abstract: The invention relates to plastic films and a silicone containing polymer blend composition that can be used in the production of the plastic films which is a polymer composition obtainable from, per 100 parts by weight of the composition, 99.99 to 90 parts by weight of a polyolefin polymer (P) and 0.01 to 10 parts by weight of a masterbatch (M).

Abstract: The invention relates to plastic films and a silicone containing polymer blend composition that can be used in the production of the plastic films which is a polymer composition obtainable from, per 100 parts by weight of the composition, 99.99 to 90 parts by weight of a polyolefin polymer (P) and 0.01 to 10 parts by weight of a masterbatch (M).

Abstract: A polymer composition comprises a thermoplastic polymer (A) and a copolymer (B). The thermoplastic polymer (A) is selected from a polyacetal and a polyolefin. The copolymer (B) is of a polysiloxane (B1) and an olefin polymer (B2). The copolymer (B) is a branched block copolymer and is free of any siloxane homopolymer. The copolymer (B) is useful as a friction reducing additive in the polymer composition.

Abstract: A process for increasing the scratch resistance of a composition comprising a thermoplastic organic polymer and a scratch resistant polymer composition per se. The process for increasing the scratch resistance of a composition comprising a thermoplastic organic polymer (P) comprises reactively mixing a thermoplastic organic polymer (A) and an organopolysiloxane (B) in a first step (I) at a temperature at which the thermoplastic organic polymer (A) and the organopolysiloxane (B) are in liquid phases to form a masterbatch. The organopolysiloxane (B) contains at least one functionality capable of reacting with the thermoplastic organic polymer (A) so that a copolymer of components (A) and (B) is formed in the masterbatch during the reactive mixing. The process further comprises a second step (II) of mixing the masterbatch with the composition comprising the thermoplastic organic polymer (P).

Abstract: A polymer composition comprises a thermoplastic polymer (A) and a copolymer (B). The thermoplastic polymer (A) is selected from a polyacetal and a polyolefin. The copolymer (B) is of a polysiloxane (B1) and an olefin polymer (B2). The copolymer (B) is a branched block copolymer and is free of any siloxane homopolymer. The copolymer (B) is useful as a friction reducing additive in the polymer composition.

Abstract: A process for increasing the scratch resistance of a composition comprising a thermoplastic organic polymer and a scratch resistant polymer composition per se. The process for increasing the scratch resistance of a composition comprising a thermoplastic organic polymer (P) comprises reactively mixing a thermoplastic organic polymer (A) and an organopolysiloxane (B) in a first step (I) at a temperature at which the thermoplastic organic polymer (A) and the organopolysiloxane (B) are in liquid phases to form a masterbatch. The organopolysiloxane (B) contains at least one functionality capable of reacting with the thermoplastic organic polymer (A) so that a copolymer of components (A) and (B) is formed in the masterbatch during the reactive mixing. The process further comprises a second step (II) of mixing the masterbatch with the composition comprising the thermoplastic organic polymer (P).

Abstract: A release coating composition is prepared comprising a polyorganosiloxane (A) having alkenyl groups, a crosslinking agent (B) having organohydrogensiloxane groups, a catalyst for the hydrosilylation reaction between (A) and (B), and an anchorage additive for enhancing the adhesion of the composition to a polymer film substrate. The anchorage additive is the reaction product of a fluid polyorganosiloxane (C) containing at least one alkenyl group and at least one silanol group with a hydrolysable silane (D) containing at least one epoxide group. The curable silicone release coating composition can be applied to a substrate known as a ‘liner’ retaining a label, which liner can for example be paper or a polymer film, and cured.

Abstract: A process for the production of a polymer composition is disclosed. The polymer composition comprises an organopolysiloxane dispersed in a thermoplastic organic polymer liable to thermo-radical degradation or cross-linking when subjected to a high compounding energy at a temperature above its melting point. In a first step (I), a thermoplastic organic polymer and an organopolysiloxane are mixed at a temperature at which both the thermoplastic organic polymer and the organopolysiloxane are in liquid phases to form a masterbatch. In a second step (II), the masterbatch is mixed with further thermoplastic organic polymer to form a polymer composition having a lower concentration of organopolysiloxane than that in the masterbatch. In the first step (I), the thermoplastic organic polymer and the organopolysiloxane are mixed in the presence of an additive capable of inhibiting the thermo-radical degradation or cross-linking of the thermoplastic organic polymer.

Abstract: The invention provides a process for grafting silane or silicone functionality onto a polyolefin, comprising reacting the polyolefin with an unsaturated monomer (A) containing an olefinic —C?C— bond or acetylenic —C?C— bond and a reactive functional group X in the presence of means capable of generating free radical sites in the polyolefin and with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A), characterized in that the unsaturated monomer (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation of the unsaturated monomer (A).

Abstract: A process for the production of a polymer composition is disclosed. The polymer composition comprises an organopolysiloxane dispersed in a thermoplastic organic polymer liable to thermo-radical degradation or cross-linking when subjected to a high compounding energy at a temperature above its melting point. In a first step (I), a thermoplastic organic polymer and an organopolysiloxane are mixed at a temperature at which both the thermoplastic organic polymer and the organopolysiloxane are in liquid phases to form a masterbatch. In a second step (II), the masterbatch is mixed with further thermoplastic organic polymer to form a polymer composition having a lower concentration of organopolysiloxane than that in the masterbatch. In the first step (I), the thermoplastic organic polymer and the organopolysiloxane are mixed in the presence of an additive capable of inhibiting the thermo-radical degradation or cross-linking of the thermoplastic organic polymer.

Abstract: The invention provides a process for grafting silane or silicone functionality onto a polyolefin, comprising reacting the polyolefin with an unsaturated monomer (A) containing an olefinic —C?C— bond or acetylenic —C?C— bond and a reactive functional group X in the presence of means capable of generating free radical sites in the polyolefin and with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A), characterized in that the unsaturated monomer (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation of the unsaturated monomer (A).

Abstract: A composition containing (A) a compound having at least one aliphatic unsaturation; (B) a cyclic organohydrogen-silicon crosslinking compound containing at least one silicon-bonded hydrogen atom (Sift) per molecule, prepared by a platinum catalyzed coupling reaction of a methylhydrogen cyclosiloxane, with a reactant containing aliphatic unsaturation, hydroxy functionalities, or a mixture of both; and (B1) a linear or branched acyclic organohydrogensilicon Crosslinking compound containing at least one silicon-bonded hydrogen atom per molecule. The composition can be used to prepare release coating compositions by adding (C) a platinum group metal-containing catalyst. Release coating compositions containing Components (B) and (B1) have better cure, better adhesion, and lower release forces, than release coating compositions containing only Component (B).

Abstract: A release coating composition is prepared comprising a polyorganosiloxane (A) having alkenyl groups, a crosslinking agent (B) having organohydrogensiloxane groups, a catalyst for the hydrosilylation reaction between (A) and (B), and an anchorage additive for enhancing the adhesion of the composition to a polymer film substrate. The anchorage additive is the reaction product of a fluid polyorganosiloxane (C) containing at least one alkenyl group and at least one silanol group with a hydrolysable silane (D) containing at least one epoxide group. The curable silicone release coating composition can be applied to a substrate known as a ‘liner’ retaining a label, which liner can for example be paper or a polymer film, and cured.

Abstract: A composition containing (A) a compound having at least one aliphatic unsaturation; (B) a cyclic organohydrogen-silicon crosslinking compound containing at least one silicon-bonded hydrogen atom (Sift) per molecule, prepared by a platinum catalyzed coupling reaction of a methylhydrogen cyclosiloxane, with a reactant containing aliphatic unsaturation, hydroxy functionalities, or a mixture of both; and (B1) a linear or branched acyclic organohydrogensilicon Crosslinking compound containing at least one silicon-bonded hydrogen atom per molecule. The composition can be used to prepare release coating compositions by adding (C) a platinum group metal-containing catalyst. Release coating compositions containing Components (B) and (B1) have better cure, better adhesion, and lower release forces, than release coating compositions containing only Component (B).

Abstract: The specification describes preparation of materials comprising selected boron anions and processes using them as catalysts for condensation reaction of compounds having silicon-bonded hydroxy or alkoxy groups. Preferred anion compounds comprise borates incorporating quadri-substituted boron in which the substituents include highly halogenated hydrocarbon groups for example pentafluorinated phenyl groups or bis (trifluoromethyl) phenyl groups. Preferred anions are {B(C6F5)4}− and {B(C6(CF3)2H3)4}−.

Abstract: A method is provided for the direct synthesis of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.