Patents by Inventor Jean F. Grollier

Jean F. Grollier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5605680
    Abstract: The invention relates to a photostable screening cosmetic composition for protecting human skin against UV rays, comprising, in a cosmetically acceptable substrate containing at least one fatty phase, 1 to 3% by weight of 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane and at least 4.5% by weight of p-methylbenzylidenecamphor, the weight ratio of p-methylbenzylidenecamphor to 4-(1,1-dimethyl-ethyl)-4'-methoxydibenzoylmethane being higher than or equal to 3.It also relates to a process for protecting the skin against UV radiation and to a process for stabilizing 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane against UV radiation.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 25, 1997
    Assignee: L'Oreal
    Inventors: Andre Deflandre, Serge Forestier, Gerard Lang, Jean F. Grollier, Jean Cotteret
  • Patent number: 5567702
    Abstract: Combination of pyrimidine derivatives and retinoids, as separate components, for inducing and stimulating hair growth and reducing its loss.Combination designed to induce and stimulate hair growth and reduce its loss, characterized in that it comprises in separated form:a) a component (A) containing at least one retinoid in a physiologically acceptable medium, andb) a component (B) containing at least one pyrimidine derivative in a physiologically acceptable medium.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: October 22, 1996
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5567701
    Abstract: A composition for inducing and stimulating hair growth and/or reducing hair loss comprises at least one alkylpolyglycoside and at least one compound having formula (I) in a physiologically acceptable medium. ##STR1## In compound (I) , R.sub.1 represents the group ##STR2## where in R.sub.3 and R.sub.4 may be selected from hydrogen, alkyl, alkenyl or cycloalkyl. R.sub.3 and R.sub.4 may also form a heterocycle with the nitrogen atom to which they are bonded. The heterocycle may be an aziridinyl, azetidinyl, pyrrolidinyl, piperidinyl, hexahydroazepinyl, heptamethyleneimine, octamethyleneimine, morpholine or 4-low alkylpiperazidinyl group. These heterocycles may be substituted at the carbon atoms by one to three alkyl, hydroxy or alkoxy groups. R.sub.2 is selected from hydrogen, alkyl, alkenyl, alkylalkoxy, cycloalkyl, aryl, alkylaryl, arylalkyl, alkylarylalkyl, alkoxyarylalkyl and/or haloarylalkyl. The physiologically acceptable acid addition salts of the compound may also be used.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: October 22, 1996
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5549886
    Abstract: The invention relates to a photostable filtering emulsion containing in association, in the aqueous phase, a photostable filter with a wide absorption band constituted by partially or totally neutralized benzene-1,4-[di(3-methylidene-10-camphosulphonic)] acid, and in the oily phase a photostable system which filters the UV-A rays containing at least one of the following compounds: N-(2-ethylhexyl)-3-[(3'-methoxy-4'-n-butoxy)benzylidene]-10-camphosulphona mide (compound 2), 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane (compound 3) and 4-isopropyldibenzoylmethane (compound 4), these two latter compounds 3 and 4 being photochemically stabilized by at least one fat-soluble filter of .lambda..sub.max less than 330 nm chosen from the following benzylidene camphor derivatives: benzylidene camphor (compound 5), p-methylbenzylidene camphor (compound 6), N-(2-ethylhexyl)-4-(3'-methylidene camphor)benzene sulphonamide (compound 7) and 3-methoxy-4-n-butoxybenzylidene camphor (compound 8).
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: August 27, 1996
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5478360
    Abstract: Process for preserving the dyeing capacity of 5,6-dihydroxyindole or of its derivatives corresponding to the formula (I): ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which are identical or different, denote hydrogen or a C.sub.1 -C.sub.4 lower alkyl, R.sub.1, R.sub.2 and R.sub.3 denoting hydrogen when R.sub.4 denotes alkyl in an aqueous medium, characterized in that the pH of the aqueous medium is adjusted to a value pH.sub.C of between 5 and 10 by employing a pH-regulating agent containing two components (A) and (B), the component (A) being chosen from pH-regulating agents which have a dissociation constant K.sub.CA in aqueous solution at 25.degree. C., such as pk.sub.CA, that is:0<pk.sub.CA -pH.sub.C .ltoreq.2.5and the component (B) being chosen from pH-regulating agents which have a dissociation constant K.sub.CB in aqueous solution at 25.degree. C., such as pk.sub.CB, that is:2<pk.sub.CB <pH.sub.C.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: December 26, 1995
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Marie F. Bosq, Jean Cotteret, Arnaud De Labbey
  • Patent number: 5427771
    Abstract: The invention relates to a transparent cosmetic composition that protects the human epidermis, containing, in a cosmetically acceptable vehicle, by way of an agent that reflects infrared radiation, 0.5 to 10% by weight of titanium dioxide flakes of dimensions between 1.5 and 25 microns, dispersible in the cosmetic medium used, possessing a reflectance (R) of infrared radiation equal to at least 45%, and of which a 2% strength dispersion in vaseline possesses an optical transmission in the visible of at least 85%.This cosmetic composition can also contain 0.5 to 20% by weight of UV-A, UV-B or broad-band screening agents.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: June 27, 1995
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Georges Rosenbaum, Jean Cotteret
  • Patent number: 5393515
    Abstract: The invention relates to a photostable filtering emulsion containing in association, in the aqueous phase, a photostable filter with a wide absorption band constituted by partially or totally neutralized benzene-1,4-[di(3-methylidene-10-camphosulphonic)] acid, and in the oily phase a photostable system which filters the UV-A rays containing at least one of the following compounds: N-(2-ethylhexyl)-3-[(3'-methoxy-4'-n-butoxy)benzylidene]-10-camphosulphona mide (compound 2), 4-(1,1-dimethylethyl)-4'-methoxydibenzoylmethane (compound 3) and 4-isopropyldibenzoylmethane (compound 4), these two latter compounds 3 and 4 being photochemically stabilized by at least one fat-soluble filter of .lambda..sub.max less than 330 nm chosen from the following benzylidene camphor derivatives: benzylidene camphor (compound 5), p-methylbenzylidene camphor (compound 6), N-(2-ethylhexyl)-4-(3'-methylidene camphor)benzene sulphonamide (compound 7) and 3-methoxy-4-n-butoxybenzylidene camphor (compound 8).
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: February 28, 1995
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5373006
    Abstract: A composition comprising a combination intended to induce and to stimulate hair growth and to reduce its loss, characterized in that it comprises:(a) a component (A) containing at least one derivative of 1,8-dihydroxy-, 1,8-diacyloxy- or 1-hydroxy-8-acyloxyanthracene or anthrone, in a physiologically acceptable medium,(b) a component (B) containing, in a physiologically acceptable medium, at least one pyrimidine derivative corresponding to the formula: ##STR1## in which R.sub.1 denotes a group ##STR2## in which R.sub.30 and R.sub.31 may, independently of each other, denote hydrogen or an alkyl, alkenyl, alkylaryl or cycloalkyl group; R.sub.30 and R.sub.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: December 13, 1994
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5275626
    Abstract: The present invention relates to a method for dyeing keratinous fibers, characterized in that the following are applied to the fibers:a) a composition (A) containing, in a medium appropriate for dyeing, at least one monohydroxyindole or dihydroxyindole, this application being preceded or followed by the application ofb) a composition (B) containing, in a medium appropriate for dyeing, at least one aromatic carbonyl derivative chosen from hydroxyacetophenones, hydroxybenzophenones, 2-hydroxy-1,4-benzoquinones, hydroxy-1,4-naphthoquinones,amino-1,4-naphthoquinones,hydroxy-9,10-anthraq uinones and amino-9,10-anthraquinones.It also relates to the dyeing agents for carrying it out.
    Type: Grant
    Filed: February 4, 1992
    Date of Patent: January 4, 1994
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5275810
    Abstract: Cosmetic composition designed to maintain the hair in place, containing, in a cosmetically medium, at least one oxazoline polymer of formula (I): ##STR1## in which R.sub.1 denotes a C.sub.1 -C.sub.4 lower alkyl radical and n has a value such that the molecular weight is equal to at least 10,000 and at least one 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid or its cosmetically acceptable salts.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: January 4, 1994
    Assignee: L'Oreal
    Inventors: Christine Dupuis, Jean F. Grollier
  • Patent number: 5259849
    Abstract: The invention relates to compositions, which are stable on storage, of certain benzoquinone and naphthoquinone dyestuffs in an anhydrous solvent containing a non-ionic surface-active agent.
    Type: Grant
    Filed: June 10, 1992
    Date of Patent: November 9, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret
  • Patent number: 5240695
    Abstract: Use of 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid or its salts of protecting the hair against environmental attacking agents, and especially against light, and process for protecting the hair using this compound.Use for preserving the mechanical properties of the hair from degradation by environmental attacking agents, and especially by light, of at least 0.3% by weight of 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid, in a cosmetically acceptable aqueous, alcoholic or aqueous-alcoholic vehicle.The acid is optionally salified with a metal hydroxide, ammonia solution or an amine.The invention also relates to a process for protecting the keratin of the hair against light, consisting in applying on the hair at least 30 mg/g of hair of a cosmetic composition containing at least 0.3% by weight of 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: August 31, 1993
    Assignee: L'Oreal
    Inventors: Claude Dubief, Jean F. Grollier
  • Patent number: 5227153
    Abstract: Use of 4-(2-oxo-3-bornylidenemethyl)benzenesulphonic acid or its salts for the protection of hair against environmental attacking agents, and in particular against light and process for the protection of hair using this compound.Use of 4-(2-oxo-3-bornylidenemethyl)benzenesulphonic acid or of its salts to preserve the mechanical properties of hair for degradation by environmental attacking agents, and in particular by light.The compound is used in proportions of at least 0.3% by weight of free acid, in a cosmetically acceptable, aqueous, alcoholic or aqueous-alcoholic support, and particularly in proportions of 0.4 to 9% by weight.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: July 13, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Claude Dubief, Chantal Fourcadier
  • Patent number: 5192534
    Abstract: The invention relates to a composition intended for inducing and stimulating hair growth and decreasing its loss, containing, in a physiologically acceptable medium, at least one pyrimidine derivative corresponding to the formula: ##STR1## in which R.sub.1 denotes ##STR2## where R.sub.3 and R.sub.4 are hydrogen, lower cycloalkyl, alkyl, alkenyl or alkylaryl, it also being possible for R.sub.3 and R.sub.4, with the nitrogen atom to which they are attached, to form a heterocycle, preferably piperidyl, and R.sub.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: March 9, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Isabelle Richoux
  • Patent number: 5180397
    Abstract: A process for dyeing keratinous fibers involves applying to the fibers a dye composition (A) containing an oxidation dye which is a mixture of a coupler and a "rapid" oxidation dye or a "rapid" oxidation dye, in combination with iodide ions. Also applied to the fibers, preceding or following the application of composition (A) is a composition (B) containing hydrogen peroxide having a pH ranging from 2 to 12.
    Type: Grant
    Filed: October 17, 1990
    Date of Patent: January 19, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
  • Patent number: 5180396
    Abstract: Process for dyeing keratinous fibres, characterized in that at least one composition (A) containing, in a medium suitable for dyeing, at least one indole derivative and at least one oxidation dye chosen from rapid oxidation dyes and couplers in combination, either (a) with iodide ions, or (b) with hydrogen peroxide, is applied on these fibres at a pH of between 2 and 7, and preferably between 2 and 5, the application of the composition (A) being preceded or followed by the application of a composition (B) which contains, in a medium suitable for dyeing:either (a) hydrogen peroxide at a pH of between 2 and 12 and preferably between 2 and 7 when (A) contains iodide ions;or (b) iodide ions at a pH of between 3 and 11 when the composition (A) contains hydrogen peroxide.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: January 19, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
  • Patent number: 5180399
    Abstract: A process for dyeing keratinous fibers employs a dye composition containing an oxidation base selected from a paraphenylenediamine, an N,N'-diphenylalkylene diamine, a para-aminophenol, an ortho-aminophenol, an ortho-phenylenediamine or a heterocyclic oxidation base, in combination with iodide ions. The application of this dyeing composition to the keratinous fibers is preceded or followed by the application to the fibers of a composition containing hydrogen peroxide.
    Type: Grant
    Filed: June 18, 1991
    Date of Patent: January 19, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
  • Patent number: 5167669
    Abstract: Dyeing composition for keratinous fibers, especially for human keratinous fibers, characterized in that it contains, in an aqueous medium suitable for dyeing:a) an indole dye; andb) a para-phenylenediamine monosubstituted on one of the amino groups, corresponding to the formula: ##STR1## in which: R.sub.12 denotes a hydrogen atom or a lower alkyl group;R.sub.13 denotes a hydrogen atom, a lower alkyl group, a lower alkoxy group or a halogen atom; andR.sub.14 denotes a hydrogen atom, a lower alkyl group, a lower alkoxy group or a halogen atom; R.sub.14 occupying any one of the remaining positions of the benzene ring; as well as the addition salts with an acid, this composition not containing an oxidizing agent other than air.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: December 1, 1992
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5157036
    Abstract: The subject of the invention is a new composition comprising a nicotinic ester with a pyrimidine derivative, to produce hair regrowth much more rapidly than with the pyrimidine derivative alone, the nicotinic ester for its part having no action in respect of hair regrowth. Furthermore, the combination makes it possible to use smaller quantities of pyrimidine derivatives or a lower frequency of application.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: October 20, 1992
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5139037
    Abstract: Cosmetic compositions for treating the hair, nails and skin are described which contain, in a solvent medium, at least one amphoteric polymer of betainised dialkylaminoalkyl (meth)acrylate or dialkylaminoalkyl(meth)acrylamide, containing at least units of the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a methyl group, R.sub.2 denotes an alkylene group having 1 to 4 carbon atoms, Y denotes O or NH and R.sub.3 and R.sub.4 independently of one another denote hydrogen or alkyl having 1 to 4 carbon atoms, and at least one cationic derivative.
    Type: Grant
    Filed: September 2, 1986
    Date of Patent: August 18, 1992
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Claude Dubief