Abstract: The invention relates to a process for removing hydrogen sulfide and carbon dioxide from a feed gas stream. H2S in the feed gas stream is converted to elemental sulfur in a Claus unit. At least a part of the gas stream obtained is contacted with an aqueous lean absorbing medium in an absorption zone at a pressure between 0.9 and 2 bara. The aqueous lean absorbing medium used comprises one or more amines chosen from: —a polyamine in the absence of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, the polyamine having at least one primary amine functionality having a pKa smaller than 10.0 at 25° C., —a polyamine in the absence of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, the polyamine having at least one secondary amine functionality having a pKa for each sorbing nitrogen smaller than 10.0 at 25° C. The process is improved as compared to a process involving Claus off-gas treatment with (activated) MDEA.

Abstract: The invention relates to a process for removing hydrogen sulfide and carbon dioxide from a feed gas stream. H2S in the feed gas stream is converted to elemental sulfur in a Claus unit. At least a part of the gas stream obtained is contacted with an aqueous lean absorbing medium in an absorption zone at a pressure between 0.9 and 2 bara. The aqueous lean absorbing medium used comprises one or more amines chosen from: —a polyamine in the absence of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, the polyamine having at least one primary amine functionality having a pKa smaller than 10.0 at 25° C., —a polyamine in the absence of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, the polyamine having at least one secondary amine functionality having a pKa for each sorbing nitrogen smaller than 10.0 at 25° C. The process is improved as compared to a process involving Claus off-gas treatment with (activated) MDEA.

Abstract: A process for the regeneration of an acid gas absorbent comprising an amine and heat stable salts by phase separation, comprising a) mixing the acid gas absorbent with an alkaline solution, to form a mixture with a pH above the pH equivalence point of the amine; b) cooling the mixture to a temperature below 500 C; c) separating the mixture into a regenerated acid gas absorbent and a waste stream; d) collecting the regenerated acid gas absorbent separate from the waste stream.

Abstract: A method of producing sulphuric acid from a sour tail gas comprises (a) obtaining a sour tail gas stream comprising H2S or reduced sulphur species or a combination thereof from an oil and gas facility; (b) subjecting the sour tail gas stream to oxidation and obtaining an oxidized gas stream comprising SO2; and, (c) utilizing the oxidized gas stream to obtain sulphuric acid and a SO2 reduced tail gas stream. The method may further comprise subjecting the oxidized gas stream to a regenerable absorption process. The sulphuric acid may be used to produce fertilizer.

Abstract: A method of producing sulphuric acid from a sour tail gas comprises (a) obtaining a sour tail gas stream comprising H2S or reduced sulphur species or a combination thereof from an oil and gas facility; (b) subjecting the sour tail gas stream to oxidation and obtaining an oxidized gas stream comprising SO2; and, (c) utilizing the oxidized gas stream to obtain sulphuric acid and a SO2 reduced tail gas stream. The method may further comprise subjecting the oxidized gas stream to a regenerable absorption process. The sulphuric acid may be used to produce fertilizer.

Abstract: A process for the regeneration of an acid gas absorbent comprising an amine and heat stable salts by phase separation, comprising a) mixing the acid gas absorbent with an alkaline solution, to form a mixture with a pH above the pH equivalence point of the amine; b) cooling the mixture to a temperature below 500 C; c) separating the mixture into a regenerated acid gas absorbent and a waste stream; d) collecting the regenerated acid gas absorbent separate from the waste stream.