Abstract: Electrolyte solutions including at least one anhydrous fluoride salt and at least one non-aqueous solvent are presented. The fluoride salt includes an organic cation having a charge center (e.g., N, P, S, or O) that does not possess a carbon in the ?-position or does not possess a carbon in the ?-position having a bound hydrogen. This salt structure facilitates its ability to be made anhydrous without decomposition. Example anhydrous fluoride salts include (2,2-dimethylpropyl)trimethylammonium fluoride and bis(2,2-dimethylpropyl)dimethylammonium fluoride. Combining these fluoride salts with at least one fluorine-containing non-aqueous solvent (e.g., bis(2,2,2-trifluoroethyl)ether; (BTFE)) promotes solubility of the salt within the non-aqueous solvents. The solvent may be a mixture of at least one non-aqueous, fluorine-containing solvent and at least one other non-aqueous, fluorine or non-fluorine containing solvent (e.g., BTFE and propionitrile or dimethoxyethane).

Abstract: An anode for a fluoride ion electrochemical cell is provided and includes a layered material of hard carbon, nitrogen doped graphite, boron doped graphite, TiS2, MoS2, TiSe2, MoSe2, VS2, VSe2, electrides of alkali earth metal nitrides, electrides of metal carbides, or combinations thereof. The anode may be included in a fluoride ion electrochemical cell, which additionally includes a cathode and a fluoride ion electrolyte arranged between the cathode and the anode. At least one of the cathode and the anode reversibly exchange the fluoride ions with the electrolyte during charging or discharging of the electrochemical cell.

Abstract: An anode for a fluoride ion electrochemical cell is provided and includes a layered material of hard carbon, nitrogen doped graphite, boron doped graphite, TiS2, MoS2, TiSe2, MoSe2, VS2, VSe2, electrides of alkali earth metal nitrides, electrides of metal carbides, or combinations thereof. The anode may be included in a fluoride ion electrochemical cell, which additionally includes a cathode and a fluoride ion electrolyte arranged between the cathode and the anode. At least one of the cathode and the anode reversibly exchange the fluoride ions with the electrolyte during charging or discharging of the electrochemical cell.

Abstract: Electrolyte solutions including at least one anhydrous fluoride salt and at least one non-aqueous solvent are presented. The fluoride salt includes an organic cation having a charge center (e.g., N, P, S, or O) that does not possess a carbon in the ?-position or does not possess a carbon in the ?-position having a bound hydrogen. This salt structure facilitates its ability to be made anhydrous without decomposition. Example anhydrous fluoride salts include (2,2-dimethylpropyl)trimethylammonium fluoride and bis(2,2-dimethylpropyl)dimethylammonium fluoride. Combining these fluoride salts with at least one fluorine-containing non-aqueous solvent (e.g., bis(2,2,2-trifluoroethyl)ether; (BTFE)) promotes solubility of the salt within the non-aqueous solvents. The solvent may be a mixture of at least one non-aqueous, fluorine-containing solvent and at least one other non-aqueous, fluorine or non-fluorine containing solvent (e.g., BTFE and propionitrile or dimethoxyethane).

Abstract: The present disclosure is directed to fluoride (F) ion batteries and F shuttle batteries comprising an anode with a solid electrolyte interphase (SEI) layer, a cathode comprising a core shell structure, and a liquid fluoride battery electrolyte. According to some aspects, the components therein enable discharge and recharge at room-temperature.

Abstract: The present disclosure relates to fluoride ion batteries and structures of metal based electrode materials for various fluoride ion batteries. The structures of the metal based electrode materials comprise one or more shells or interfaces, enabling the electrodes to operate at room temperature with a liquid electrolyte.

Abstract: The present disclosure relates to a fluoride shuttle battery and nanostructures of copper based cathode materials in the fluoride shuttle battery. The F-shuttle batteries of present disclosure comprise a liquid electrolyte, which allows the F-shuttle batteries to operate under room temperature. The minimum thickness of copper layer within the copper nanostructures is no more than 20 nm. The thickness of copper layer within the copper nanostructures is controlled and reduced to ensure the energy densities of F-shuttle batteries.

Abstract: An anode for a fluoride ion electrochemical cell is provided and includes a layered material of hard carbon, nitrogen doped graphite, boron doped graphite, TiS2, MoS2, TiSe2, MoSe2, VS2, VSe2, electrides of alkali earth metal nitrides, electrides of metal carbides, or combinations thereof. The anode may be included in a fluoride ion electrochemical cell, which additionally includes a cathode and a fluoride ion electrolyte arranged between the cathode and the anode. At least one of the cathode and the anode reversibly exchange the fluoride ions with the electrolyte during charging or discharging of the electrochemical cell.

Abstract: The present disclosure relates to a method of making core-shell and yolk-shell nanoparticles, and to electrodes comprising the same. The core-shell and yolk-shell nanoparticles and electrodes comprising them are suitable for use in electrochemical cells, such as fluoride shuttle batteries. The shell may protect the metal core from oxidation, including in an electrochemical cell. In some embodiments, an electrochemically active structure includes a dimensionally changeable active material forming a particle that expands or contracts upon reaction with or release of fluoride ions. One or more particles are at least partially surrounded with a fluoride-conducting encapsulant and optionally one or more voids are formed between the active material and the encapsulant using sacrificial layers or selective etching. The fluoride-conducting encapsulant may comprise one or more metals.

Abstract: The present disclosure relates to an electrochemical cell which may be used, for example, in a rechargeable battery based on the reversible transfer of halide anions, and a method for making an electrolyte composition for use in the same. The electrochemical cell includes a positive electrode, a negative electrode, and an electrolyte composition positioned between the two electrodes, where the electrolyte composition contains a crown ether-metal halide complex in a solvent.

Abstract: The present disclosure relates to a method of making core-shell and yolk-shell nanoparticles, and to electrodes comprising the same. The core-shell and yolk-shell nanoparticles and electrodes comprising them are suitable for use in electrochemical cells, such as fluoride shuttle batteries. The shell may protect the metal core from oxidation, including in an electrochemical cell. In some embodiments, an electrochemically active structure includes a dimensionally changeable active material forming a particle that expands or contracts upon reaction with or release of fluoride ions. One or more particles are at least partially surrounded with a fluoride-conducting encapsulant and optionally one or more voids are formed between the active material and the encapsulant using sacrificial layers or selective etching. When the electrochemically active structures are used in secondary batteries, the presence of voids can accommodate dimensional changes of the active material.

Abstract: Electrolyte solutions including at least one anhydrous fluoride salt and at least one non-aqueous solvent are presented. The fluoride salt includes an organic cation having a charge center (e.g., N, P, S, or O) that does not possess a carbon in the ?-position or does not possess a carbon in the ?-position having a bound hydrogen. This salt structure facilitates its ability to be made anhydrous without decomposition. Example anhydrous fluoride salts include (2,2-dimethylpropyl)trimethylammonium fluoride and bis(2,2-dimethylpropyl)dimethylammonium fluoride. Combining these fluoride salts with at least one fluorine-containing non-aqueous solvent (e.g., bis(2,2,2-trifluoroethyl)ether; (BTFE)) promotes solubility of the salt within the non-aqueous solvents. The solvent may be a mixture of at least one non-aqueous, fluorine-containing solvent and at least one other non-aqueous, fluorine or non-fluorine containing solvent (e.g., BTFE and propionitrile or dimethoxyethane).

Abstract: Provided is a positive electrode active material capable of obtaining high capacity density and also capable of obtaining sufficient charge-discharge characteristics in a region which involves high current density, when the positive electrode active material is used in a non-aqueous electrolyte secondary battery. The positive electrode active material for the non-aqueous electrolyte secondary battery includes FeF3 in which at least a part of a surface thereof is coated with an electroconductive metal oxide.

Abstract: Provided is a cathode material capable of obtaining high energy density and superior instantaneous output characteristics in a lithium ion secondary battery. The cathode material is used in a lithium ion secondary battery (1), and includes FeF3 and LiV3O8 as a cathode active material. A mass ratio of FeF3 to LiV3O8 of the cathode material is in a range of 86:14 to 43:57. The cathode material further comprises a conductive auxiliary.

Abstract: A cathode active material is provided by which excellent charge and discharge properties in a high-current range can be obtained when used in non-aqueous electrolyte secondary batteries. The cathode active material consists of a mixed metal fluoride represented by the general formula Fe(1-x)MxF3. M is a metal element selected from the group consisting of Y, Mn, Cu, Zn, and Cr. x is 0.01?x?0.15.

Abstract: Provided is a cathode material capable of obtaining high energy density and superior instantaneous output characteristics in a lithium ion secondary battery. The cathode material is used in a lithium ion secondary battery (1), and includes FeF3 and LiV3O8 as a cathode active material. A mass ratio of FeF3 to LiV3O8 of the cathode material is in a range of 86:14 to 43:57. The cathode material further comprises a conductive auxiliary.

Abstract: Provided is a positive electrode active material capable of obtaining high capacity density and also capable of obtaining sufficient charge-discharge characteristics in a region which involves high current density, when the positive electrode active material is used in a non-aqueous electrolyte secondary battery. The positive electrode active material for the non-aqueous electrolyte secondary battery includes FeF3 in which at least a part of a surface thereof is coated with an electroconductive metal oxide.

Abstract: The present invention provides a cathode material that can achieve a high energy density and excellent instantaneous output characteristics in lithium ion secondary batteries. The cathode material is used in a lithium ion secondary battery 1, and contains FeF3 and carbon-coated LiFePO4 as cathode active materials.

Abstract: A cathode active material is provided by which excellent charge and discharge properties in a high-current range can be obtained when used in non-aqueous electrolyte secondary batteries. The cathode active material consists of a mixed metal fluoride represented by the general formula Fe(1?x)MxF3. M is a metal element selected from the group consisting of Y, Mn, Cu, Zn, and Cr. x is 0.01?x?0.15.

Abstract: A method for producing an alloy catalyst for redox reaction comprising alloy particles of platinum and nickel, wherein the alloy particles are equipped at an outer surface with a crystal lattice plane represented by a Miller index {111} and have an average particle diameter in a range of 6 to 20 nm, the method comprising: dissolving, in an alcohol, a salt and/or complex of platinum, a salt and/or complex of nickel, and a polymer containing a plurality of salt structures comprising an organic cation and a halogen anion in a polymer chain and heating the resulting solution to reflux under an inert atmosphere.