Patents by Inventor Karl-Heinz Etzbach

Karl-Heinz Etzbach has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6036883
    Abstract: The use of low molecular-weight or polymeric organic compounds which are present in the columnar-helical phase and have liquid-crystalline properties, as photoconductors or in electronic components, corresponding photoconductive layers, an electrophotographic recording material and a method for enhancing the photoconductivity.
    Type: Grant
    Filed: May 21, 1998
    Date of Patent: March 14, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Paulus, Lukas Haussling, Karl Siemensmeyer, Karl-Heinz Etzbach, Dieter Adam, Juergen Simmerer, Helmut Ringsdorf, Peter Schuhmacher, Dietrich Haarer, Sundeep Kumar
  • Patent number: 5962691
    Abstract: Pyridone dyes of the formula I ##STR1## where X is nitrogen or CH,R.sup.1 is a 5-membered or 6-membered carbocyclic or heterocyclic radical,R.sup.2 is cyano, carbamoyl, C.sub.1 -C.sub.6 -alkoxycarbonyl or C.sub.1 -C.sub.4 -alkanoyl andR.sup.3 is unsubstituted or substituted C.sub.1 -C.sub.13 -alkyl, unsubstituted or substituted phenyl or unsubstituted or substituted amino,a method for their thermal transfer and a method for coloring or printing synthetic materials by means of the novel dyes.The invention concerns pyridone dyes of the formula (I) in which X is nitrogen or CH, R.sup.1 is a five-membered or six-membered carbocyclic or heterocyclic group, R.sup.2 is cyano, carbamoyl, C.sub.1 -C.sub.6 alkoxycarboyl or C.sub.1 -C.sub.4 alkanoyl and R.sup.3 is optionally substituted C.sub.1 -C.sub.13 alkyl, optionally substituted phenyl or optionally substituted amino.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: October 5, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Johann Schmidt, Rudiger Sens, Karl-Heinz Etzbach
  • Patent number: 5922481
    Abstract: An electroluminescent arrangement contains one or more organic layers, at least one of which is obtained by thermal or radiation-induced crosslinking and contains at least one charge-transporting compound which can carry crosslinkable groups per layer, one of the layers being completely or partially composed of a crosslinkable fluorescent compound which emits fluorescent light in the wavelength range from 400 to 800 nm.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: July 13, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Frank Meyer, Wolfgang Paulus, Hans-Werner Schmidt
  • Patent number: 5886242
    Abstract: The invention relates to chiral compounds containing at least one divalent or polyvalent chiral group, at least one polymerizable group, at least one spacer and at least one mesogenic group, and to their use as polymerizable, chiral dopes for the preparation of cholesteric networks.The novel compounds are suitable for use in electro-optical displays or as chiral dopes for nematic or cholesteric liquid crystals in order to produce layers which reflect in colors.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: March 23, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Paul Delavier, Karl Siemensmeyer, Gerhard Wagenblast, Lothar Laupichler, Volkmar Vill
  • Patent number: 5853432
    Abstract: Dye mixtures comprising one or more pyridone dyes of the formula ##STR1## where M is a pyridone or triazolopyridone radical which is bonded to the thiazole ring via CH and the other radicals are each as defined in the description, and one or more dyes based on 1-aminoanthraquinone are useful for thermal transfer.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: December 29, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Rudiger Sens
  • Patent number: 5849361
    Abstract: Methine dyes of the formula ##STR1## where K is a carbocyclic or heterocyclic radical,X is nitrogen or a radical of the formula C--Q.sup.1, andQ.sup.1, Q.sup.2 and Q.sup.3 are hydrogen, substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.6 -alkoxy, benzyloxy, substituted or unsubstituted phenoxy, C.sub.1 -C.sub.6 -alkylthio, halogen, cyano, formylamino or a radical of the formula R.sup.3, --CO--OR.sup.1, --CO--NHR.sup.1, --CO--NH--CO--R.sup.1, --CO--NH--CO--R.sup.3, --CO--NH--SO.sub.2 R.sup.3, --NH--CO--R.sup.1, --NH--CO--OR.sup.1, --NH--CO--NR.sup.1 R.sup.2, NH--CS--OR.sup.1, --NH--CS--NR.sup.1 R.sup.2, --NH--CO--R.sup.3, --NH--SO.sub.2 --R.sup.1, --NH--SO.sub.2 --R.sup.3 or --NH--SO.sub.2 --NR.sup.1 R.sup.2, wherein R.sup.1 and R.sup.2 are substituted or unsubstituted C.sub.1 -C.sub.13 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl or substituted or unsubstituted phenyl, or else --NR.sup.1 R.sup.2 is amino, and R.sup.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: December 15, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudiger Sens, Andreas Johann Schmidt, Friedrich-Wilhelm Raulfs, Karl-Heinz Etzbach
  • Patent number: 5833880
    Abstract: Mixtures of liquid-crystalline compounds comprising at least two different substances of the formula I ##STR1## where Z.sup.1 and Z.sup.2, independently of one another, are polymerizable groups,Y.sup.1 and Y.sup.2, independently of one another, are each a direct bond, --O--, --COO--, --OCO-- or --S--,A.sup.1 and A.sup.2, independently of one another, are spacers, andR.sup.1, R.sup.2 and R.sup.3 are conventional substituents,and novel compounds of the above formula where at least two of Z.sup.1, Z.sup.2, Y.sup.1, Y.sup.2, A.sup.1 and A.sup.2 are not identical, are described. The novel mixtures and compounds are suitable, inter alia, as base material for color-effect materials and piezomaterials, preferably in chirally doped form.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: November 10, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Siemensmeyer, Karl-Heinz Etzbach, Paul Delavier, Frank Meyer
  • Patent number: 5811370
    Abstract: Azamethine dyes of the formula ##STR1## where W is oxygen, sulfur or a radical of the formula --NH--CO--, --NH--COO-- oder --NH--SO.sub.2 --,Z.sup.1 is C.sub.1 -C.sub.4 -alkyl with or without substitution, phenyl or C.sub.1 -C.sub.4 -alkoxy,Z.sup.2 and Z.sup.3 are each hydrogen or C.sub.1 -C.sub.4 -alkyl with or without substitution, provided --CZ.sup.1 Z.sup.2 Z.sup.3 is not linear and is not isopropyl,Z.sup.4 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,Z.sup.5 and Z.sup.6 are each C.sub.1 -C.sub.10 -alkyl with or without substitution, C.sub.3 -C.sub.4 -alkenyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or tolyl, or together with the nitrogen atom joining them together a heterocyclic radical or Z.sup.4 and Z.sup.5 are together a bridge member, andT is a radical of a cyclic acidic--CH compound H.sub.2 T,are useful for thermal transfer.
    Type: Grant
    Filed: May 8, 1997
    Date of Patent: September 22, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudiger Sens, Andreas Johann Schmidt, Stefan Beckmann, Karl-Heinz Etzbach
  • Patent number: 5804097
    Abstract: Liquid-crystalline compounds of the formula IX(--Y--A--Y--M--Y--B).sub.n I,whereX is an aromatic or aliphatic ring system,n is an integer from 2 to 6,each Y, independently of the others, is a direct bond, --COO--, --OCO--, --O--, --CONH-- or --CON(R)--, where R is C.sub.1 -- to C.sub.4 -alkyl,A is a spacer,M is a mesogenic group andB is a side chain,are particularly suitable for use in displays or for the production of light-reflecting coatings.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: September 8, 1998
    Assignee: BASF Aktiengsellschaft
    Inventors: Paul Delavier, Karl-Heinz Etzbach, Andreas Johann Schmidt, Karl Siemensmeyer, Gerhard Wagenblast
  • Patent number: 5798197
    Abstract: The use of low molecular-weight or polymeric organic compounds which are present in the columnar-helical phase and have liquid-crystalline properties, as photoconductors or in electronic components, corresponding photoconductive layers, an electrophotographic recording material and a method for enhancing the photoconductivity.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: August 25, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Paulus, Lukas Haussling, Karl Siemensmeyer, Karl-Heinz Etzbach, Dieter Adam, Juergen Simmerer, Helmut Ringsdorf, Peter Schuhmacher, Dietrich Haarer, Sundeep Kumar
  • Patent number: 5798147
    Abstract: A process for coating or printing substrates with a coating or printing composition comprises applying a polymerizable material containing liquid-crystalline, polymerizable monomers which carryat least two polymerizable groups for coating andat least one polymerizable group for printing,to the substrate, and subsequently carrying out the polymerization, where the coating composition or the printing composition comprisesa.sub.1) a chiral liquid-crystalline monomer andb) a polymeric binder and/or monomeric compounds which can be converted into the polymeric binder by polymerization, or, in the case of emulsion coatings and printing inks, a dispersion auxiliary d),or the coating composition or the printing composition comprisesa.sub.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: August 25, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Erich Beck, Frank Meyer, Ulrich Poth, Karl Siemensmeyer, Claudia Sierakowski, Norbert Greif, Werner Ostertag, Michael Zirnstein, Reinhold Leyrer, Ekkehard Jahns, Karl-Heinz Etzbach, Peter Schuhmacher
  • Patent number: 5789560
    Abstract: Azo dyes of the formula ##STR1## where D is the radical of a diazo component of the aniline series or the series of the aromatic heterocyclic amines,R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.10 -alkyl, which may be substituted, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.4 -alkenyl, substituted or unsubstituted phenyl, or are together with the nitrogen atom joining them together a heterocyclic radical, andR.sup.3 is tert-butyl or tert-pentyl,are useful for thermal transfer and for dyeing or printing synthetic materials.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: August 4, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Rudiger Sens
  • Patent number: 5785719
    Abstract: Dye mixtures include one or more pyridone dyes of the formula ##STR1## where M is a pyridone or triazolopyridone radical which is linked to the thiazole ring via nitrogen or CH and the rest of the radicals are each as defined in the description,and one or more azo dyes of the formulaD--N=N--K,where D is the radical of a diazo component of the pyrrole, thiophene, pyrazole, thiazole, isothiazole, triazole, thiadiazole, benzothiophene, benzothiazole, benzisothiazole, pyridothiophene, pyrimidothiophene, thienothiophene or aniline series, andK is the radical of a coupling component of the aminothiazole, aniline or tetrahydroquinoline series, and are useful for thermal transfer.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: July 28, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Rudiger Sens
  • Patent number: 5783649
    Abstract: Polymerizable azo dyes I ##STR1## in which R.sup.1 is an aryl group,R.sup.2 is cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl or nitro,R.sup.3 and R.sup.4 are hydrogen, C.sub.1 -C.sub.12 -alkyl or C.sub.1 -C.sub.6 -alkoxy,R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.6 is hydrogen or methyl,Y is C.sub.2 -C.sub.10 -alkylene which can be interrupted by 1 to 3 nonadjacent oxygen atoms or imino or C.sub.1 -C.sub.4 -alkylimino groups, andW is oxygen, imino or C.sub.1 -C.sub.4 -alkyliminoare used to prepare copolymers which show nonlinear-optical properties.
    Type: Grant
    Filed: June 10, 1996
    Date of Patent: July 21, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Rudiger Sens
  • Patent number: 5780629
    Abstract: The invention relates to chiral compounds containing at least one divalent or polyvalent chiral group, at least one polymerizable group, at least one spacer and at least one mesogenic group, and to their use as polymerizable, chiral dopes for the preparation of cholesteric networks. The novel compounds are suitable for use in electro-optical displays or as chiral dopes for nematic or cholesteric liquid crystals in order to produce layers which reflect in colors.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: July 14, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Paul Delavier, Karl Siemensmeyer, Gerhard Wagenblast, Lothar Laupichler, Volkmar Vill
  • Patent number: 5777089
    Abstract: Phenol derivatives of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, X, Y and Z have the meanings stated in the description, are used in particular in nonlinear optics.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: July 7, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Rudiger Sens
  • Patent number: 5766679
    Abstract: Chiral nematic polyesters comprise as alcohol component chiral diol structural units and as acid component dicarboxylic acid residues comprising mesogenic groups. The polyesters are particularly suitable for surface coating.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: June 16, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Siemensmeyer, Frank Meyer, Karl-Heinz Etzbach, Hans R. Kricheldorf, Nicolas Probst
  • Patent number: 5756753
    Abstract: Naphthalene derivatives of the formula ##STR1## where the rings A and B may be benzofused,X is nitrogen or a radical of the formula CH or CH.dbd.CH--CH,Z is a heterocyclic radical or additionally, when x is CH.dbd.CH--CH, a 5- or 6-membered aromatic carbocyclic radical, andR.sup.1, R.sup.2 and R.sup.3 are hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.5 -C.sub.7 -cycloalkyl, are useful in nonlinear optics.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: May 26, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Rudiger Sens
  • Patent number: 5744057
    Abstract: A polymerizable, chiral compound of the formula (I):(Z--Y.sup.1 -A-O--CO--O-M-Y.sup.2).sub.n X (I)where:A, M, Y.sup.1 and Y.sup.2, X, n and Z are as defined herein; and which compound is suitable for use in electro-optical displays or as chiral dopes for nematic or cholesteric liquid crystals for the production of layers which reflect in colors.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: April 28, 1998
    Assignee: BASF Aktiengesellshaft
    Inventors: Frank Meyer, Karl Siemensmeyer, Karl-Heinz Etzbach, Peter Schuhmacher
  • Patent number: 5738806
    Abstract: Use of azo dyes having a diazo component derived from an aminothienothiophene and a coupling component of the aniline series in nonlinear optics, polymers derived from these azo dyes, the use thereof in nonlinear optics, and novel phenylthienothienylazoanilines.
    Type: Grant
    Filed: May 8, 1996
    Date of Patent: April 14, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Ruediger Sens