Abstract: A rechargeable lithium-ion battery includes a positive electrode that includes a first current collector and a first active material. The battery also includes an electrolyte and a negative electrode that includes a second current collector and a second active material, where the second active material includes a lithium titanate material. The positive electrode has a first capacity and the negative electrode has a second capacity, the second capacity being less than the first capacity such that the rechargeable lithium-ion battery is negative-limited.

Abstract: Single-phase lithium-transition metal oxide compounds containing cobalt, manganese and nickel can be prepared by wet milling cobalt-, manganese-, nickel- and lithium-containing oxides or oxide precursors to form a finely-divided slurry containing well-distributed cobalt, manganese, nickel and lithium, and heating the slurry to provide a lithium-transition metal oxide compound containing cobalt, manganese and nickel and having a substantially single-phase O3 crystal structure. Wet milling provides significantly shorter milling times than dry milling and appears to promote formation of single-phase lithium-transition metal oxide compounds. The time savings in the wet milling step more than offsets the time that may be required to dry the slurry during the heating step.

Abstract: A method of producing Liy[NixCo1−2xMnx]O2 wherein 0.025≦x≦0.5 and 0.9≦y≦1.3. The method includes mixing [NixCo1−2xMnx]OH2 with LiOH or Li2CO3 and one or both of alkali metal fluorides and boron compounds, preferably one or both of LiF and B2O3. The mixture is heated sufficiently to obtain a composition of Liy[NixCo1−2xMnx]O2 sufficiently dense for use in a lithium-ion battery cathode. Compositions so densified exhibit a minimum reversible volumetric energy characterized by the formula [1833−333x] measured in Wh/L.

Abstract: An electrode composition that includes a plurality of composite particles and a plurality of electrically conductive diluent particles admixed with the composite particles. Each of the composite particles includes an electrochemically active metal particle and an electrically conductive layer partially covering the particle. In one aspect, the layer is present in an amount no greater than about 75 wt. % of the composite, while in another aspect the layer is present in an amount no greater than about 75 vol. % of the composite. Also featured are lithium ion batteries featuring electrodes made from these compositions.

Abstract: An electrode composition that includes a plurality of composite particles and a plurality of electrically conductive diluent particles admixed with the composite particles. Each of the composite particles includes an electrochemically active metal particle and an electrically conductive layer partially covering the particle. In one aspect, the layer is present in an amount no greater than about 75 wt. % of the composite, while in another aspect the layer is present in an amount no greater than about 75 vol. % of the composite. Also featured are lithium ion batteries featuring electrodes made from these compositions.

Abstract: An electrode composition that includes a plurality of composite particles and a plurality of electrically conductive diluent particles admixed with the composite particles. Each of the composite particles includes an electrochemically active metal particle and an electrically conductive layer partially covering the particle. In one aspect, the layer is present in an amount no greater than about 75 wt. % of the composite, while in another aspect the layer is present in an amount no greater than about 75 vol. % of the composite. Also featured are lithium ion batteries featuring electrodes made from these compositions.