Abstract: A method for producing an electrophotographic photosensitive member has a charge transporting layer, including preparing a first solution containing a specified first liquid, a charge transporting substance and a binder resin, preparing a second solution containing a specified second liquid and water, preparing an emulsion from the first and second solutions, forming the emulsion coating, and heating the coat to form the charge transporting layer, and a method for producing an organic device has a charge transporting layer, including preparing a first solution containing a specified first liquid and a charge transporting substance, preparing a second solution containing a specified second liquid and water, preparing an emulsion from the first and second solutions, forming the emulsion coating, and heating the coat to form the charge transporting layer are used.

Abstract: A member for electrophotography having a multilayer structure or a single-layer structure, including an outermost layer which satisfies the following A, B and C: A: the outermost layer has perfluoropolyether and a binder resin, and in the outermost layer, the ratio of the number of fluorine atoms to the number of carbon atoms is 0.10 or more and 0.40 or less; B: in a 19F-NMR spectrum of the outermost layer, the relaxation time T2 of a peak derived from CF2 moieties of perfluoropolyether is 13 milliseconds or more at 22° C.; and C: the total sum of the contents of CF3 moieties, CF2 moieties, and CF moieties in the binder resin is 5% by mass or less.

Abstract: The present invention relates to an electrophotographic intermediate transfer member that, even if an image is repeatedly and continuously transferred, can retain its transfer performance and can obtain an excellent image for a long time. The electrophotographic intermediate transfer member has a base layer and a surface layer, the surface layer has a matrix-domain structure in the cross section in the thickness direction, the matrix is formed of a binder resin, the domains contains a perfluoropolyether, and a microhardness of a surface of the electrophotographic intermediate transfer member measured by an ultramicro-hardness meter is 50 MPa or more.

Abstract: There are provided an electrophotographic photosensitive member and an intermediate transfer member each having good lubricity and good cleaning property on its surface, a process cartridge and an electrophotographic apparatus each including the electrophotographic photosensitive member, and an electrophotographic apparatus including the intermediate transfer member. Therefore, a surface layer of the electrophotographic photosensitive member or intermediate transfer member of the present invention contains a matrix component and a rotatably-retained spherical particle that is not bound with the matrix component and is rotatably retained in a pore in the matrix component.

Abstract: A core of a cyclic structure represented by (—N—(CH2)n—)k is bonded to a dendrimer-type side chain with a specific branched structure at all nitrogen atoms in the core to produce a compound with a specific structure for producing a metal complex that exhibits a T1-reducing effect, and the resulting compound is coordinated to a metal ion that has a T1-reducing effect to obtain a metal complex that exhibits an excellent T1-reducing effect which is useful as an effective component of an MRI contrast agent and an MRI contrast agent using the same.

Abstract: The present invention relates to an electrophotographic photosensitive member including a support and a photosensitive layer formed on the support. The electrophotographic photosensitive member has a surface layer containing a polyarylate resin and acicular inorganic fillers. The acicular inorganic fillers are basic and have a number-average aspect ratio of 5 to 50 and a Mohs hardness of 2 to 6.

Abstract: The invention has a process of preparing a dispersion liquid by dispersing particles containing a charge transporting substance and a binder resin in liquid medium containing a specific liquid to prepare a dispersion liquid and a process of forming a coat of the dispersion liquid, and heating and drying the coat to dissolve the particles containing the charge transporting substance and the binder resin with liquid medium to form a charge transporting layer.

Abstract: An object of the present invention is to provide a substrate probe capable of detecting enzyme activity with high accuracy and a method for detecting the enzyme activity by a multi nuclear magnetic resonance method using the substrate probe. Multi-dimensional nuclear magnetic resonance is performed by using a substrate probe, which is used for measuring enzyme activity by a multi-dimensional nuclear magnetic resonance method and characterized by containing a enzyme recognition site that is selectively recognized by an active-state enzyme, as at least one constitutional unit, and a group to which at least three nuclear magnetic resonance active nuclei each having a nuclear spin and a different resonance frequency are connected, being present specifically to the enzyme recognition, thereby detecting presence of the substrate probe and the enzyme activity. Alternatively, imaging of the enzyme activity is performed by a multi-dimensional nuclear resonance imaging method.

Abstract: A member for electrophotography having a multilayer structure or a single-layer structure, including an outermost layer which satisfies the following A, B and C: A: the outermost layer has perfluoropolyether and a binder resin, and in the outermost layer, the ratio of the number of fluorine atoms to the number of carbon atoms is 0.10 or more and 0.40 or less; B: in a 19F-NMR spectrum of the outermost layer, the relaxation time T2 of a peak derived from CF2 moieties of perfluoropolyether is 13 milliseconds or more at 22° C.; and C: the total sum of the contents of CF3 moieties, CF2 moieties, and CF moieties in the binder resin is 5% by mass or less.

Abstract: An intermediate transfer member for electrophotography comprising a substrate and a surface layer provided on the substrate. The surface layer comprises a binder resin and a perfluoropolyether. An extraction amount of the perfluoropolyether per 10 mm3 of the surface layer, is 0.10 mg or more and 5.00 mg or less, the extraction amount of the perfluoropolyether obtained by immersing the intermediate transfer member into a solvent that can dissolve the perfluoropolyether at 25 degrees in Celsius for 24 hours. A surface of the intermediate transfer member that is not subjected to first and second treatments, has a n-hexadecane contact angle of 55 degrees or more. A surface of the intermediate transfer member that has been subjected to the first treatment, has a n-hexadecane contact angle of 40 degrees or less. A surface of the intermediate transfer member that has been subjected to the second treatment, has a n-hexadecane contact angle of 50 degrees or more.

Abstract: In a process for producing an electrophotographic photosensitive member, in particular, a process of forming a charge transporting layer, a production process is provided by which the stability of a charge transporting layer coating fluid even after its storage for a long time is improved so as to form a coat for a charge transporting layer having a high uniformity.

Abstract: A method for producing an electrophotographic photosensitive member has a charge transporting layer, including preparing a first solution containing a specified first liquid, a charge transporting substance and a binder resin, preparing a second solution containing a specified second liquid and water, preparing an emulsion from the first and second solutions, forming the emulsion coating, and heating the coat to form the charge transporting layer, and a method for producing an organic device has a charge transporting layer, including preparing a first solution containing a specified first liquid and a charge transporting substance, preparing a second solution containing a specified second liquid and water, preparing an emulsion from the first and second solutions, forming the emulsion coating, and heating the coat to form the charge transporting layer are used.

Abstract: Provided are a method of producing an electrophotographic photosensitive member, particularly, a method of producing an electrophotographic photosensitive member and an organic device by which, in a method of forming a charge transporting layer, the stability of an application liquid for the layer after long-term storage is improved while the usage of an organic solvent in the application liquid is curtailed, and the layer having high uniformity is formed. The method is a method of producing an electrophotographic photosensitive member which includes a support and a charge transporting layer formed thereon, the method including: preparing a solution including: a first liquid whose solubility in water under 25° C. and 1 atmosphere is 1.0 mass % or less; a second liquid whose solubility in water under 25° C. and 1 atmosphere is 5.

Abstract: A core of a cyclic structure represented by (—N—(CH2)n—)k is bonded to a dendrimer-type side chain with a specific branched structure at all nitrogen atoms in the core to produce a compound with a specific structure for producing a metal complex that exhibits a T1-reducing effect, and the resulting compound is coordinated to a metal ion that has a T1-reducing effect to obtain a metal complex that exhibits an excellent T1-reducing effect which is useful as an effective component of an MRI contrast agent and an MRI contrast agent using the same.

Abstract: The present invention provides a method for measuring nuclear magnetic resonance that employs a compound in which a plurality of nuclei is labeled with isotopes as a probe agent, highly selectively and highly sensitively obtains a nuclear magnetic resonance signal of the above described probe agent, and can attach a spatial positional information to the above described nuclear magnetic resonance signal, and an apparatus therefore.

Abstract: A core of a cyclic structure represented by (—N—(CH2)n—)k is bonded to a dendrimer-type side chain with a specific branched structure at all nitrogen atoms in the core to produce a compound with a specific structure for producing a metal complex that exhibits a T1-reducing effect, and the resulting compound is coordinated to a metal ion that has a T1-reducing effect to obtain a metal complex that exhibits an excellent T1-reducing effect which is useful as an effective component of an MRI contrast agent and an MRI contrast agent using the same.

Abstract: There are provided an electrophotographic photosensitive member and an intermediate transfer member each having good lubricity and good cleaning property on its surface, a process cartridge and an electrophotographic apparatus each including the electrophotographic photosensitive member, and an electrophotographic apparatus including the intermediate transfer member. Therefore, a surface layer of the electrophotographic photosensitive member or intermediate transfer member of the present invention contains a matrix component and a rotatably-retained spherical particle that is not bound with the matrix component and is rotatably retained in a pore in the matrix component.

Abstract: The present invention relates to an electrophotographic photosensitive member including a support and a photosensitive layer formed on the support. The electrophotographic photosensitive member has a surface layer containing a polyarylate resin and acicular inorganic fillers. The acicular inorganic fillers are basic and have a number-average aspect ratio of 5 to 50 and a Mohs hardness of 2 to 6.

Abstract: There is provided a film having resistance to an increase in the friction coefficient resulting from wearing. The film has a first portion having hardness of 0.01 to 3 GPa and a second portion. The hardness ratio of the second portion to the first portion is of 1.2 to 30. The first portion and the second portion form a first surface portion and a second surface region of the film, respectively. Each of the first portion and the second portion extends to a depth of 75% or more of the thickness of the film. In a 1 mm×1 mm square region disposed on an arbitrary position of the surface of the film, the second surface region accounts for 10% to 80% by area of the square region, and the first surface region and the second surface region account for 50% or more by area of the square region.

Abstract: An object of the present invention is to provide a substrate probe capable of detecting enzyme activity with high accuracy and a method for detecting the enzyme activity by a multi nuclear magnetic resonance method using the substrate probe. Multi-dimensional nuclear magnetic resonance is performed by using a substrate probe, which is used for measuring enzyme activity by a multi-dimensional nuclear magnetic resonance method and characterized by containing a enzyme recognition site that is selectively recognized by an active-state enzyme, as at least one constitutional unit, and a group to which at least three nuclear magnetic resonance active nuclei each having a nuclear spin and a different resonance frequency are connected, being present specifically to the enzyme recognition, thereby detecting presence of the substrate probe and the enzyme activity. Alternatively, imaging of the enzyme activity is performed by a multi-dimensional nuclear resonance imaging method.