Abstract: A method for the removal of CO2 from exhaust gases, e.g., exhaust gases from plants for pig-iron production or exhaust gases from synthesis-gas plants, includes removing CO2 using chemical and/or physical absorption, wherein the heat for regenerating the absorbent is obtained at least partially from an air separation plant. As a result, the CO2 can be separated from the exhaust gases to a greater extent than in the pressure-swing adsorption of other gases, but a lower-order energy carrier can additionally be used for this purpose.

Abstract: A process and an installation for reducing particulate material containing iron oxide are shown, wherein the material containing iron oxide is at least partially reduced with reducing gas in a reducing zone and the waste gas produced during the reduction is drawn off and subsequently subjected to CO2 cleaning in a CO2 separating device (1), in which a tail gas containing CO2 is separated. The tail gas is subjected to combustion and subsequent dewatering in a dewatering device (5), the substitute gas thereby formed being used as a substitute for inert gas.

Abstract: An injector insert pipe is arranged in the gas channel of a nozzle for injecting oxygen-containing gas into a pig iron production unit, wherein an interspace which surrounds the pipe is present over the entire pipe length between the wall of the gas channel and the pipe outer wall . The pipe extends at least as far as the nozzle end face which contains the mouth of the gas channel. The pipe space is connected to an oxygen-containing gas feed line, and the interspace is connected to a protective gas supply line. In a process, oxygen-containing gas is fed into the pipe space, which after it has flowed through the pipe, enters the production unit at an entry velocity, and the interspace is simultaneously flowed through by a gas which exits into the production unit at an exit velocity, wherein the entry velocity is greater than the exit velocity.

Abstract: In a method and a device for operating a smelting reduction process, at least part of an export gas from a blast furnace or a reduction unit is thermally utilized in a gas turbine and the exhaust gas of this gas turbine is used in a waste heat steam generator to generate steam. The remaining part of the export gas is fed to a CO2 separation apparatus, the tail gas thereby obtained being fed to a waste heat steam generator and burned for additional steam generation. The combustible components of the tail gas are sent for thermal utilization in a steam generator, so that the overall energy balance of the thermal use of the export gas is improved. In addition, a further part of the export gas is qualitatively improved by the CO2 separation apparatus, so as to generate a high-quality reduction gas which can be supplied for metallurgical use.

Abstract: A method for controlling a transformation process in which the conversion of charge materials to a product takes place along a transformation interface from the crystal and/or grain and/or phase and/or pore surface into the charge material, wherein one or more chemical elements in the charge materials is released and/or incorporated and/or rearranged and wherein the conversion of the charge materials takes place along advancing transformation interfaces. The charge materials are identified on the basis of at least one optical, in particular microscopic, analysis with respect to their phases and/or phase components and/or their phase morphology, structure, texture and/or their chemical composition. On the basis of these variables, reference functions for the charge materials, which describe the conversion of the charge materials in the process, are assigned and used for establishing the process parameters of the transformation process.

Abstract: Process gas purification device (2) for a melt reduction system (1) comprising at least one reduction reactor (3) and a melting gasification reactor (4), a first line system (5) for discharging a furnace gas (6) from the reduction reactor (3) and a second line system (7) for discharging a generator gas (8) from the melting gasification reactor (4) wherein both line systems (5,7) lead to a respective wet scrubbing system (11, 12). The furnace gas or generator gas flow can be throttled preferably by way of a control element (41) that varies a control gap (40) and the scrubber or cooling liquid (49) can be collected and drained. The first wet scrubber system (11) of the first line system (5) for routing the furnace gas (6) and the second Venturi scrubber system (12) of the second line system (7) for routing the generator gas (8) both discharge into a common mist elimination device (14).

Abstract: A process and an apparatus for producing liquid pig iron or liquid primary steel products from charge materials formed by iron ores and additions. The charge materials are subjected to a further reduction in a reducing zone (1) and are then fed to a smelting zone or a smelting unit (2), in particular a fusion gasifier, for smelting with the addition of carbon carriers and oxygen-containing gas to form a fixed bed. A CO- and H2-containing reduction gas is formed, which gas is introduced into the reducing zone converted there and drawn off as top gas. The hot top gas, laden with solid matter, after separation of the solids, is subjected at least to a dry coarse separation and at least parts of the hot solids segregated by the separation are returned into the smelting zone or the smelting unit (2) or the reducing unit (1). In addition, the top gas is treated in a further fine separation stage (13A).

Abstract: A method for the melting of pig iron in a blast furnace (1) operated with oxygen or in a melt-reduction plant, with a reduction region. Purified crude gas is discharged from the reduction region and is recirculated into the reduction region with the addition of hydrocarbons. The purified crude gas is mixed with hydrocarbons and is also blended with a reduction gas which has a temperature of above 1000° C. and which is generated by partial oxidation of hydrocarbons by means of oxygen gas having an oxygen content of above 90% by volume, in order to form a recirculation gas with a temperature of above 800° C. The recirculation gas is recirculated into the reduction region according to an auto-reforming process.

Abstract: A method for producing moldings, in particular briquettes, from fine-grained to medium-grained mixed material using organic binders. In a first stage, the mixed material is heated to a temperature necessary for the molding operation. In a second, atmospherically separate stage, mixing of the mixed material with binder is performed, as well as downstream steps of the process. The method allows hazardous emissions to be avoided.

Abstract: In a method for the production of molten metal, oxygen, a reducing agent and iron reduced in a reduction reactor are introduced into a melt gasifier, the reducing agent is gasified with oxygen and reduced iron is melted by means of the heat which occurs, the cupola gas being used as at least a fraction of the reduction gas. Reacted top gas is drawn off from the reduction reactor. For increased efficiency in terms of energy and raw materials, there is in this case provision for at least part of the heat energy of the top gas and/or of the fraction of the reduction gas which is provided for use as cooling gas and as excess gas to be utilized for the indirect heating of at least one further gas used in the method. For this purpose, at least one heat exchanger in a line for top gas and/or the fraction of the reduction gas which is provided for use as cooling gas and as excess gas is provided, at least one further gas used in the method flowing through said heat exchanger.

Abstract: A method for producing molten material, wherein oxygen, reducing agents and iron that has been reduced in a reduction reactor are introduced into a melter gasifier. The reducing agent is gasified with the oxygen and the heat thereby produced melts the reduced iron. Cupola gas from the melter gasifier is used at least as a portion of the reduction gas, and reacted top gas is withdrawn from the reduction reactor. The aim of the invention is to increase energy efficiency and raw material efficiency as well as productivity while at the same time obtaining metallurgically improved properties of the product. For this purpose, at least a portion of the top gas is branched off from the line for the withdrawal of the top gas from the reduction reactor and is returned via at least one return line leading to the melter gasifier and is introduced into the melter gasifier.

Abstract: Apparatus and process for producing a fixed bed in a metallurgical unit, preferably for producing pig iron or primary steel products from iron-containing charge materials, in particular in a melted gasifier, in which a lumpy bulk material, which contains ore-containing and carbon-containing constituents, prereduced iron ore, preferably sponge iron, and preferably lumpy, coal, is charged onto a surface. Through mixing of the ore-containing constituent with the carbon-containing constituent of the bulk material takes place. The entire ore-containing constituent is charged onto an active circumferential or peripheral region of the fixed bed, at which the thorough, preferably uniform mixing of the ore-containing constituent with the carbon-containing constituent of the bulk material takes place preferably outward of the center. A device scatters the stream of bulk material aver the surface and less of the material is scattered at the center, so that heavier grain lumps segregate themselves toward the center.

Abstract: To distribute charging material evenly in an enclosure such as a furnace or reactor to ensure its best operation, a charging material distribution inside the enclosure 30 of the furnace is used. It has a movable charging device 4 in the form of a spout through which the charging material is fed into the enclosure. The distribution device is small in size and light in weight. It has a moveable charging device 4 in the form of a spout which is suspended on a gimbal suspension 2 on a fixed charging device, which is in the form of a chute 3 inside the enclosure.

Abstract: A method is for feeding a gas into a metallurgical vessel having a condensable and/or evaporable component entrained by the gas. The gas is fed to the metallurgical vessel via one or more gas supply means. According to the method, if there are a number of the gas supply means, in a first section, the gas velocity is continuously increased, in a turbulence zone, the gas is intimately mixed with the condensable and/or evaporable component, in an exit section, the gas velocity is kept substantially constant, and the gas which has been intimately mixed with the entrained component is blown into the metallurgical vessel. A gas supply device for carrying out the method is also disclosed. The method and apparatus according t the invention make it possible to prevent or reduce nozzle damage.

Abstract: Apparatus and process for producing a fixed bed in a metallurgical unit, preferably for producing pig iron or primary steel products from iron-containing charge materials, in particular in a melted gasifier, in which a lumpy bulk material, which contains ore-containing and carbon-containing constituents, prereduced iron ore, preferably sponge iron, and preferably lumpy, coal, is charged onto a surface. Through mixing of the ore-containing constituent with the carbon-containing constituent of the bulk material takes place. The entire ore-containing constituent is charged onto an active circumferential or peripheral region of the fixed bed, at which the thorough, preferably uniform mixing of the ore-containing constituent with the carbon-containing constituent of the bulk material takes place preferably outward of the center. A device scatters the stream of bulk material aver the surface and less of the material is scattered at the center, so that heavier grain lumps segregate themselves toward the center.

Abstract: Process and apparatus for producing liquid pig iron or primary steel products from iron-containing material in lump form in a fusion gasifier (1), in which, with lump coal and oxygen-containing gas being fed in, and with simultaneous formation of a reduction gas, the iron-containing material is fused, lump coal being fed to the fusion gasifier (1) from above and, together with the iron-containing material, forming a fixed bed (6) in the fusion gasifier (1) and thereby giving off its fraction of volatile hydrocarbons into the dome space (11) located above the fixed bed (6), and pulverized-fuel burners (15) being directed obliquely from above towards the surface of the fixed bed (6). The operation of the pulverized-fuel burners (15) is in this case controlled in such a way that the combustion of the carbon fraction of the carbon carriers in fine particle form takes place in a proportion of at least 40% to form CO2.

Abstract: The invention relates to a shaft furnace, in particular a direct-reduction shaft furnace, with a charge composed of particulate material, in particular a particulate material containing iron oxide and/or sponge iron, the said material being capable of being fed into the shaft furnace from above, and with, arranged in one plane, a multiplicity of gas-inlet orifices for a reduction gas in the region of the lower third of the shaft furnace, the shaft contour having a diametral widening and a cavity being formed between the gas-inlet orifices and the charge. The shaft furnace according to the invention makes it possible to supply gas to the shaft furnace so as to be distributed uniformly over its circumference.

Abstract: A device for producing sponge iron from iron oxide lumps consists of a reduction shaft in which a hot dust laden reducing gas is delivered. The gas is produced in a gas generator by means of partial oxidation of solid carbon carriers and passes into the lower end of the reduction zone via lateral reduction gas inlets. The iron oxide lumps are fed to the upper area of the reduction shaft and are radially fed as sponge iron to the lower end of said reduction shaft via delivery organs. The delivery organs are arranged in such a manner that the sponge iron is conveyed only radially outwardly.

Abstract: The invention relates to a shaft furnace (1), in particular a direct-reduction shaft furnace, having a bed (2) of lumpy material, in particular lumpy material containing iron oxide and/or iron sponge, having worm conveyors (3) which penetrate through the shell of the shaft furnace for discharging the lumpy material from the shaft furnace (1), which conveyors are arranged above the base area of the shaft furnace (1) and are mounted in the shell of the shaft furnace.