Patents by Inventor Marco KRUEGER

Marco KRUEGER has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20180065102
    Abstract: An apparatus for producing pulverulent poly(meth)acrylate in a reactor for droplet polymerization having an apparatus for dropletization of a monomer solution for the production of the poly(meth)acrylate having holes through which the monomer solution is introduced, an addition point for a gas above the apparatus for dropletization, at least one gas withdrawal point on the circumference of the reactor and a fluidized bed, and above the gas withdrawal point the reactor has a region having a constant hydraulic internal diameter and below the gas withdrawal point the reactor has a hydraulic internal diameter that steadily decreases. The reactor has a heating means in the region having a steadily decreasing hydraulic internal diameter.
    Type: Application
    Filed: February 25, 2016
    Publication date: March 8, 2018
    Inventors: Robert Bayer, Jürgen Freiberg, Rudolf Schliwa, Marco Krüger
  • Publication number: 20180028999
    Abstract: An apparatus for producing pulverulent poly(meth)acrylate in a reactor for droplet polymerization having an apparatus for dropletization of a monomer solution for the production of the poly(meth)acrylate having holes through which the monomer solution is introduced, an addition point for a gas above the apparatus for dropletization, at least one gas withdrawal point on the circumference of the reactor and a fluidized bed, and above the gas withdrawal point the reactor has a region having a constant hydraulic internal diameter and below the gas withdrawal point the reactor has a hydraulic internal diameter that steadily decreases.
    Type: Application
    Filed: March 1, 2016
    Publication date: February 1, 2018
    Inventors: Robert Bayer, Jürgen Freiberg, Rudolf Schliwa, Marco Krüger
  • Patent number: 9809686
    Abstract: The invention relates to a process for producing polyarylene ether beads from a polyarylene ether solution, comprising the steps of i) dividing the polyarylene ether solution in a division apparatus which is made to vibrate with a frequency of 10 to 1400 Hz to obtain droplets, ii) transferring the droplets into a precipitation bath to form polyarylene ether beads in the precipitation bath which (A) comprises at least one aprotic solvent (component (1)) and at least one protic solvent (component (2)), (B) has a temperature of 0° C. to Tc, where the critical temperature Tc in [° C.] can be determined by the numerical equation Tc=(77?c)/0.58 in which c is the concentration of component (1) in the precipitation bath in [% by weight] and (C) has component (1) in concentrations of 5% by weight to cc, where the critical concentration cc in [% by weight] can be determined by the numerical equation cc=77?0.58*T in which T is the temperature in the precipitation bath in [° C.
    Type: Grant
    Filed: July 16, 2014
    Date of Patent: November 7, 2017
    Assignee: BASF SE
    Inventors: Joerg Erbes, Stefan Muessig, Tobias Kortekamp, Marco Krueger, Markus Steffen, Angela Ulzhoefer, Cecile Schneider, Alexandra Wiedemann, Simon Gramlich
  • Publication number: 20170246607
    Abstract: An apparatus for production of pulverulent poly(meth)acrylate, comprising a reactor or droplet polymerization, having an apparatus for dropletization of a monomer solution for the production of the poly(meth)acrylate, having holes through which the solution is dropletized, an addition point for a gas above the apparatus for dropletization, at least one gas withdrawal point on the periphery of the reactor and a fluidized bed. The outermost holes through which the solution is dropletized are positioned such that a droplet falling vertically downward falls into the fluidized bed and the hydraulic diameter at the level of the midpoint between the apparatus for dropletization and the gas withdrawal point is at least 10% greater than the hydraulic diameter of the fluidized bed.
    Type: Application
    Filed: June 10, 2015
    Publication date: August 31, 2017
    Applicant: BASF SE
    Inventors: Andreas Daiss, Robert Bayer, Rudolf Schliwa, Jürgen Freiberg, Karl J. Possemiers, Marco Krüger
  • Publication number: 20170232418
    Abstract: An apparatus for introducing droplets of a monomer solution for production of poly(meth)acrylate into a reactor for droplet polymerization, comprising at least one channel or a dropletizer head, the channel or the dropletizer head being sealed at its base by a dropletizer plate, the dropletizer plate having holes through which the monomer solution is introduced into the reactor, and the dropletizer plate being configured such that holes that, in an axially symmetric dropletizer plate or in an annular dropletizer plate or in one configured as a ring segment, are not on a center line of the dropletizer plate or, in the case of a circular dropletizer plate, are not at the center of the dropletizer plate are aligned such that monomer solution is introduced through the holes into the reactor at an angle to the vertical, and the holes in the case of a radial alignment of axially symmetric dropletizer plates being aligned such that the angle at which the monomer solution is introduced into the reactor decreases in t
    Type: Application
    Filed: June 23, 2015
    Publication date: August 17, 2017
    Applicant: BASF SE
    Inventors: Andreas Daiss, Robert Bayer, Rudolf Schliwa, Jürgen Freiberg, Karl J. Possemiers, Marco Krüger
  • Publication number: 20170225138
    Abstract: An apparatus for addition of droplets of a monomer solution for production of poly(meth)acrylate to a reactor for droplet polymerization, comprising at least one channel or a dropletizer head having, at its base, holes through which the solution is dropletized into the reactor, at least one of the following features being fulfilled: (a) the ratio of the area covered by the channels or the dropletizer head in the reactor relative to the area which is defined by the circumference of a line along the outermost holes is less than 50%, (b) the number of holes relative to the area which is defined by the circumference of a line along the outermost holes is within a range from 100 to 1000 holes/m2.
    Type: Application
    Filed: June 16, 2015
    Publication date: August 10, 2017
    Inventors: Andreas Daiss, Robert Bayer, Rudolf Schliwa, Jürgen Freiberg, Karl J. Possemiers, Marco Krüger
  • Publication number: 20170037172
    Abstract: A process for preparing water-absorbing polymer beads with high permeability by polymerizing droplets of a monomer solution, comprising monomers bearing acid groups, in a gas phase surrounding the droplets, wherein the monomer solution comprises polyvalent cations and the polymer beads have a mean diameter of at least 150 ?m.
    Type: Application
    Filed: October 21, 2016
    Publication date: February 9, 2017
    Inventors: Uwe Stueven, Matthias Weismantel, Wilfried Heide, Marco Krüger, Volker Seidl, Stefan Blei, Dennis Loesch, Rüdiger Funk, Annemarie Hillebrecht
  • Patent number: 9480968
    Abstract: The present invention relates to a process for producing fluid-absorbent cores, comprising mixing a fibrous material and fluid-absorbent polymer particles having low moisture content and low apparent density and pressing the obtained mixture under specific conditions.
    Type: Grant
    Filed: June 19, 2014
    Date of Patent: November 1, 2016
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Ulrich Schröder, Marco Krüger, Sylvia Bertha, John Joseph Louden
  • Publication number: 20160159990
    Abstract: The invention relates to a process for producing polyarylene ether beads from a polyarylene ether solution, comprising the steps of i) dividing the polyarylene ether solution in a division apparatus which is made to vibrate with a frequency of 10 to 1400 Hz to obtain droplets, ii) transferring the droplets into a precipitation bath to form polyarylene ether beads in the precipitation bath which (A) comprises at least one aprotic solvent (component (1)) and at least one protic solvent (component (2)), (B) has a temperature of 0° C. to Tc, where the critical temperature Tc in [° C.] can be determined by the numerical equation Tc=(77?c)/0.58 in which c is the concentration of component (1) in the precipitation bath in [% by weight] and (C) has component (1) in concentrations of 5% by weight to cc, where the critical concentration cc in [% by weight] can be determined by the numerical equation cc=77?0.58*T in which T is the temperature in the precipitation bath in [° C.
    Type: Application
    Filed: July 16, 2014
    Publication date: June 9, 2016
    Applicant: BASF SE
    Inventors: Joerg ERBES, Stefan MUESSIG, Tobias KORTEKAMP, Marco KRUEGER, Markus STEFFEN, Angela ULZHOEFER, Cecile SCHNEIDER, Alexandra WIEDEMANN, Simon GRAMLICH
  • Patent number: 9073040
    Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, wherein the temperature of the gas leaving the polymerization chamber is 130° C. or less, the gas velocity inside the polymerization chamber is at least 0.5 m/s, and the droplets are generated by using a droplet plate having a multitude of bores.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: July 7, 2015
    Assignee: BASF SE
    Inventors: Rainer Dobrawa, Thomas Daniel, Uwe Stueven, Marco Krüger, Francisco Javier Lopez Villanueva, Norbert Herfert, Karin Flore, Stefan Blei, Michael A. Mitchell
  • Patent number: 9029485
    Abstract: A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution in a surrounding gas phase in a reaction chamber, wherein the monomer solution is metered into the reaction chamber via at least one bore, and the diameter is from 210 to 290 ?m per bore and the metering rate is from 0.9 to 5 kg/h per bore.
    Type: Grant
    Filed: August 29, 2013
    Date of Patent: May 12, 2015
    Assignee: BASF SE
    Inventors: Marco Krüger, Stefan Blei, Wilfried Heide, Matthias Weismantel, Uwe Stueven
  • Patent number: 8895800
    Abstract: The present invention relates to fluid-absorbent articles, comprising an upper liquid-pervious layer, a lower liquid-impervious layer and a fluid-absorbent core, wherein the fluid-absorbent core comprises a fibrous material and 10 to 95% by weight of spherical fluid-absorbent polymer particles having a moisture content of at least 8% by weight.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: November 25, 2014
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Ulrich Schröder, Marco Krüger, John Joseph Louden
  • Patent number: 8865828
    Abstract: A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution in a surrounding gas phase, wherein the polymer particles are coated with a permeability improver.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: October 21, 2014
    Assignee: BASF SE
    Inventors: Thomas Daniel, Uwe Stueven, Marco Krüger, Stefan Blei, Francisco Javier Lopez Villanueva, Norbert Herfert
  • Publication number: 20140302321
    Abstract: A process for preparing water-absorbing polymer beads with high permeability by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, wherein a water-insoluble inorganic salt is suspended in the monomer solution and the polymer beads have a mean diameter of at least 150 ?m.
    Type: Application
    Filed: April 30, 2014
    Publication date: October 9, 2014
    Applicant: BASF SE
    Inventors: Uwe Stueven, Matthias Weismantel, Wilfried Heide, Marco Krüger, Volker Seidl, Stefan Blei, Dennis Lösch, Rüdiger Funk, Annemarie Hillebrecht
  • Publication number: 20140302985
    Abstract: The present invention relates to a process for producing fluid-absorbent cores, comprising mixing a fibrous material and fluid-absorbent polymer particles having low moisture content and low apparent density and pressing the obtained mixture under specific conditions.
    Type: Application
    Filed: June 19, 2014
    Publication date: October 9, 2014
    Applicant: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Ulrich Schröder, Marco Krüger, Sylvia Bertha, John Joseph Louden
  • Patent number: 8796174
    Abstract: The present invention relates to a process for producing fluid-absorbent cores, comprising mixing a fibrous material and fluid-absorbent polymer particles having low moisture content and low apparent density and pressing the obtained mixture under specific conditions.
    Type: Grant
    Filed: August 3, 2009
    Date of Patent: August 5, 2014
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Ulrich Schröder, Marco Krüger, Sylvia Bertha, John Joseph Louden
  • Patent number: 8748000
    Abstract: A process for preparing water-absorbing polymer beads with high permeability by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, wherein a water-insoluble inorganic salt is suspended in the monomer solution and the polymer beads have a mean diameter of at least 150 ?m.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: June 10, 2014
    Assignee: BASF SE
    Inventors: Uwe Stueven, Matthias Weismantel, Wilfried Heide, Marco Krüger, Volker Seidl, Stefan Blei, Dennis Loesch, Rüdiger Funk, Annemarie Hillebrecht
  • Patent number: 8748512
    Abstract: A process for producing polymer particles by polymerizing liquid droplets in a gas phase surrounding the droplets, said droplets comprising at least one monomer and being coated with particulate solids during the polymerization.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: June 10, 2014
    Assignee: BASF SE
    Inventors: Dennis Lösch, Annemarie Hillebrecht, Marco Krüger, Stefan Blei, Matthias Weismantel, Wilfried Heide
  • Patent number: 8697779
    Abstract: A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution in a surrounding gas phase, the resulting polymer particles having a water content of at least 5% by weight, and being aftertreated thermally in the fluidized state in the presence of steam at a temperature of at least 60° C.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: April 15, 2014
    Assignee: BASF SE
    Inventors: Dennis Lösch, Marco Krüger, Stefan Blei, Matthias Weismantel, Wilfried Heide
  • Patent number: 8669410
    Abstract: The present invention relates to fluid-absorbent articles, comprising an upper liquid-pervious layer, a lower liquid-impervious layer, a fluid-absorbent core, wherein the fluid-absorbent core comprises a fibrous material and 10 to 95% by weight of spherical fluid-absorbent polymer particles, and an acquisition distribution layer, wherein the acquisition distribution layer comprises a fibrous material and 0 to 20% by weight of spherical fluid-absorbent polymer particles.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: March 11, 2014
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Ulrich Schröder, Marco Krüger, John Joseph Louden