Abstract: A method and device of nanostructured titania that is crack free. A method in accordance with the present invention comprises depositing a Ti film on a surface, depositing a masking layer on the Ti film, etching said masking layer to expose a limited region of the Ti film, the limited region being of an area less than a threshold area, oxidizing the exposed limited region of the Th.ucsbi film, and annealing the exposed limited region of the Ti film.

Abstract: A method and device of nanostructured titania that is crack free. A method in accordance with the present invention comprises depositing a Ti film on a surface, depositing a masking layer on the Ti film, etching said masking layer to expose a limited region of the Ti film, the limited region being of an area less than a threshold area, oxidizing the exposed limited region of the Th.ucsbi film, and annealing the exposed limited region of the Ti film.

Abstract: In general, in one aspect, the invention features an apparatus that includes a plurality of optical elements arranged to form an image of an object. The elements include a first element comprising one or more regions of a polarizing material, the regions being shaped as one or more visual features, a polarizer, and a mounting assembly including a first mount for the first element and a second mount for the polarizer. At least the first or second mount is rotatable with respect to an optical axis between a first orientation and a second orientation. In the first orientation, the visual features are visible in the image of the object and, in the second orientation, the visual features are not visible in the image of the object.

Abstract: Methods of analysis, and compositions relating to such, to determine the presence or absence of an analyte in a sample utilizing a composite substrate which facilitates surface enhanced Raman spectroscopy through the use of ‘hot spots’ of the form ‘metal/analyte/metal’ are presented. Additionally, substrates which contain ‘hot spots’ of the form ‘metal/analyte/metal’ and substrates which facilitate the formation of ‘hot spots’ of the form ‘metal/analyte/metal’ are presented as well as methods for making these substrates.

Abstract: A perpendicular-mode near-field scanning optical microscope (NSOM) utilizing a piezoelectric micro tuning fork as its height-sensing element is described. The present invention provides a method and apparatus for modifying and attaching an optical fiber to the tuning fork that allows the assembly to retain Q-factors up to 9000, substantially higher than those described so far in the literature for tuning-fork-based instruments. The method involves reducing the diameter of the cladding of the optical fiber down to the 17-25 &mgr;m using several chemical etching steps, before the fiber is attached to the tuning fork. A sharp upturn in the Q-factor is observed when the fiber diameter d drops below ˜25 &mgr;m. An analysis, which shows that the stretching force constant of a bent fiber is proportional to d4, is used to account for the great sensitivity of the Q-factor to the fiber diameter.

Abstract: The present invention provides a powerful new method for producing, uniform sized and uniformly aligned nanotubes through catalytic pyrolysis of a hydrocarbon within the dense, uniform and parallel pores of alumina nano-templates. The catalyst, Co, Fe, Ni or another suitable substance is deposited electrochemically into the bottom of the channel of the alumina template. The nanotubes with any desired diameter in the range 5-500 nm and lengths up to .about.100 .mu.m, are generated by the pyrolysis of a suitable hydrocarbon inside the pores of the alumina template with at least one end open at the alumina/air interface. The nanotubes may be filled by metals using for example electroless deposition.

Abstract: A method of growing single crystal diamonds in excess of 10 .mu.m in diameter from industrial diamond "seeds" having mean diameters of approximately 1.5 .mu.m is disclosed. The diamonds are grown by exposing the seed diamonds to C.sub.70 in the presence of elemental reducing agents such as phosphorus or selenium in evacuated cells at moderate temperatures and pressures. In another aspect the invention diamonds are grown by exposing diamond seed particles to vapour phase C.sub.70 in the presence of a gas phase metal carbonyl, such as F.sub.5 e(CO) in a temperature range of 400.degree. C. to 700.degree. C. to cause at least some of the diamond seed particles to grow.

Abstract: A method of growing diamond crystals in excess of 10 .mu.m in diameter from industrial diamond "seeds" having mean diameters of approximately 1.5 .mu.m is disclosed. The diamonds are grown by exposing the seed diamonds to C.sub.70 in the presence of reducing agents such as phosphorus or selenium in evacuated cells at moderate temperatures and pressures.

Abstract: Single-electron devices useful as diodes, transistors or other electronic components are prepared by anodizing a metal substrate in sheet or foil form electrolytically in an acid bath, to deposit thereon an oxide film having axially disposed micropores of substantially uniform diameter in the range of from about 1 to about 500 nanometers and substantially uniform depth less than the thickness of the oxide film, leaving an ultra thin oxide layer between the bottom of each pore in the metal substrate. The conductive material is deposited in the pores to form nanowires contacting the oxide layer at the bottom of the pores. Macro metal is deposited over the ends of the nanowires for external electrical contact purposes. Devices can be made according to the present invention which are suitable to exhibit single-electron tunnelling effects and arrays of tunnel junction devices can be prepared having a density up to the order of 10.sup.10 per square cm.

Abstract: Quantum dot and quantum wire semiconductors in the nanosize range are produced by a process which utilizes a microporous aluminum oxide surface layer on an aluminum metal substrate as a template for the semiconducting material. The microporous surface layer is prepared by anodizing an aluminum substrate in an acid bath. Then a metal capable of forming a semiconductor compound is electrodeposited into the surface micropores, the oxide is partially or wholly etched away, and the deposited metal is reacted with a liquid or gaseous reagent to convert it chemically to a semiconducting compound. By the process of the invention, there are produced quantum dot or quantum wire semiconductors in the form of an array of substantially mutually parallel, substantially uniform-sized rods of semiconductor material protruding from an electrically conductive substrate, each rod having a diameter less than 100 nanometers.

Abstract: The invention provides a process for preparing magnetic recording material by depositing ferromagnetic material in particulate form into an aluminum substrate. The aluminum substrate is prepared by cleaning an aluminum or aluminum metal containing substrate; anodizing the cleaned metal substrate, to produce a suitably pitted or porous oxide substrate surface; and rinsing the anodized substrate, substantially to remove therefrom acid residues remaining from the anodizing step. The substrate in contact with a liquid solution of a salt of at least one ferromagnetic metal is then subjected to electrolysis with alternating current, to deposit the metal into the pores of the oxide in small-particle, ferromagnetic form while adjusting and controlling the frequency of the alternating current to obtain discrete particles in the pores assembled in an anisotropic configuration. Excess liquid solution is subsequently removed from the so-treated substrate.

Abstract: Catalysts for use in promoting heterogeneous chemical reactions, such as hydrogenation, cracking, dehydrogenation and Fischer-Tropsch reactions, are prepared by depositing a catalytically active metal such as nickel electrolytically onto an aluminum substrate in such a manner that the metal particles are deposited in micro-particulate form to enhance their catalytic activity. The aluminum substrate is prepared by cleaning and anodizing it, so as to deposit thereon an aluminum oxide surface film having micro porosity. Then the substrate is immersed into an electrolysis bath of solution of salt of the metal to be deposited, and subjected to alternating current electrolysis to cause the required deposition. Prior to use, the catalysts so prepared should be heated to remove absorbed gases from their porous surfaces.