Patents by Inventor Matthew W. Copel
Matthew W. Copel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20110081754Abstract: Methods of forming complementary metal oxide semiconductor (CMOS) structures with tunable threshold voltages are provided. The methods disclose a technique of obtaining selective placement of threshold voltage adjusting materials on a semiconductor substrate by using a block mask prior to deposition of the threshold voltage adjusting materials. The block mask is subsequently removed to obtain a patterned threshold voltage adjusting material on the semiconductor substrate. The methods are material independent and can be used in sequence for both nFET threshold voltage adjusting materials and pFET threshold voltage adjusting materials.Type: ApplicationFiled: October 6, 2009Publication date: April 7, 2011Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Hemanth Jagannathan, Sivananda K. Kanakasabapathy, Matthew W. Copel
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Publication number: 20110042759Abstract: A field effect transistor (FET) includes a body region and a source region disposed at least partially in the body region. The FET also includes a drain region disposed at least partially in the body region and a molybdenum oxynitride (MoNO) gate. The FET also includes a dielectric having a high dielectric constant (k) disposed between the body region and the MoNO gate.Type: ApplicationFiled: August 21, 2009Publication date: February 24, 2011Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Nestor A. Bojarczuk, Michael P. Chudzik, Matthew W. Copel, Supratik Guha, Richard A. Haight, Vijay Narayanan, Martin P. O'Boyle, Vamsi K. Paruchuri
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Patent number: 7858500Abstract: A semiconductor structure, particularly a pFET, which includes a dielectric material that has a dielectric constant of greater than that of SiO2 and a Ge or Si content of greater than 50% and at least one other means for threshold/flatband voltage tuning by material stack engineering is provided. The other means contemplated in the present invention include, for example, utilizing an insulating interlayer atop the dielectric for charge fixing and/or by forming an engineered channel region. The present invention also relates to a method of fabricating such a CMOS structure.Type: GrantFiled: April 4, 2008Date of Patent: December 28, 2010Assignee: International Business Machines CorporationInventors: Eduard A. Cartier, Matthew W. Copel, Martin M. Frank, Evgeni P. Gousev, Paul C. Jamison, Rajarao Jammy, Barry P. Linder, Vijay Narayanan
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Patent number: 7745278Abstract: A method of forming a CMOS structure, and the device produced therefrom, having improved threshold voltage and flatband voltage stability. The inventive method includes the steps of providing a semiconductor substrate having an nFET region and a pFET region; forming a dielectric stack atop the semiconductor substrate comprising an insulating interlayer atop a high k dielectric; removing the insulating interlayer from the nFET region without removing the insulating interlayer from the pFET region; and providing at least one gate stack in the pFET region and at least one gate stack in the nFET region. The insulating interlayer can be AlN or AlOxNy. The high k dielectric can be HfO2, hafnium silicate or hafnium silicon oxynitride. The insulating interlayer can be removed from the nFET region by a wet etch including a HCl/H2O2 peroxide solution.Type: GrantFiled: September 16, 2008Date of Patent: June 29, 2010Assignee: International Business Machines CorporationInventors: Nestor A. Bojarczuk, Jr., Cyril Cabral, Jr., Eduard A. Cartier, Matthew W. Copel, Martin M. Frank, Evgeni P. Gousev, Supratik Guha, Rajarao Jammy, Vijay Narayanan, Vamsi K. Paruchuri
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Publication number: 20100040866Abstract: A method of depositing a film of a metal chalcogenide including the steps of: contacting an isolated hydrazinium-based precursor of a metal chalcogenide and a solvent having therein a solubilizing additive to form a solution of a complex thereof; applying the solution of the complex onto a substrate to produce a coating of the solution on the substrate; removing the solvent from the coating to produce a film of the complex on the substrate; and thereafter annealing the film of the complex to produce a metal chalcogenide film on the substrate. Also provided is a process for preparing an isolated hydrazinium-based precursor of a metal chalcogenide as well as a thin-film field-effect transistor device using the metal chalcogenides as the channel layer.Type: ApplicationFiled: August 27, 2009Publication date: February 18, 2010Applicant: International Business Machines CorporationInventors: David B. Mitzi, Matthew W. Copel
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Publication number: 20100040891Abstract: A method of depositing a film of a metal chalcogenide including the steps of: contacting an isolated hydrazinium-based precursor of a metal chalcogenide and a solvent having therein a solubilizing additive to form a solution of a complex thereof; applying the solution of the complex onto a substrate to produce a coating of the solution on the substrate; removing the solvent from the coating to produce a film of the complex on the substrate; and thereafter annealing the film of the complex to produce a metal chalcogenide film on the substrate. Also provided is a process for preparing an isolated hydrazinium-based precursor of a metal chalcogenide as well as a thin-film field-effect transistor device using the metal chalcogenides as the channel layer.Type: ApplicationFiled: August 27, 2009Publication date: February 18, 2010Applicant: International Business Machines CorporationInventors: David B. Mitzi, Matthew W. Copel
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Publication number: 20100041907Abstract: A method of depositing a film of a metal chalcogenide including the steps of: contacting an isolated hydrazinium-based precursor of a metal chalcogenide and a solvent having therein a solubilizing additive to form a solution of a complex thereof; applying the solution of the complex onto a substrate to produce a coating of the solution on the substrate; removing the solvent from the coating to produce a film of the complex on the substrate; and thereafter annealing the film of the complex to produce a metal chalcogenide film on the substrate. Also provided is a process for preparing an isolated hydrazinium-based precursor of a metal chalcogenide as well as a thin-film field-effect transistor device using the metal chalcogenides as the channel layer.Type: ApplicationFiled: August 27, 2009Publication date: February 18, 2010Applicant: International Business Machines CorporationInventors: David B. Mitzi, Matthew W. Copel
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Publication number: 20100019238Abstract: A method of depositing a film of a metal chalcogenide including the steps of: contacting an isolated hydrazinium-based precursor of a metal chalcogenide and a solvent having therein a solubilizing additive to form a solution of a complex thereof; applying the solution of the complex onto a substrate to produce a coating of the solution on the substrate; removing the solvent from the coating to produce a film of the complex on the substrate; and thereafter annealing the film of the complex to produce a metal chalcogenide film on the substrate. Also provided is a process for preparing an isolated hydrazinium-based precursor of a metal chalcogenide as well as a thin-film field-effect transistor device using the metal chalcogenides as the channel layer.Type: ApplicationFiled: August 27, 2009Publication date: January 28, 2010Applicant: International Business Machines CorporationInventors: David B. Mitzi, Matthew W. Copel
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Publication number: 20090302399Abstract: The present invention is directed to CMOS structures that include at least one nMOS device located on one region of a semiconductor substrate; and at least one pMOS device located on another region of the semiconductor substrate. In accordance with the present invention, the at least one nMOS device includes a gate stack comprising a gate dielectric, a low workfunction elemental metal having a workfunction of less than 4.2 eV, an in-situ metallic capping layer, and a polysilicon encapsulation layer and the at least one pMOS includes a gate stack comprising a gate dielectric, a high workfunction elemental metal having a workfunction of greater than 4.9 eV, a metallic capping layer, and a polysilicon encapsulation layer. The present invention also provides methods of fabricating such a CMOS structure.Type: ApplicationFiled: August 17, 2009Publication date: December 10, 2009Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Eduard A. Cartier, Matthew W. Copel, Bruce B. Doris, Rajarao Jammy, Young-Hee Kim, Barry P. Linder, Vijay Narayanan, Vamsi K. Paruchuri, Keith Kwong Hon Wong
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Patent number: 7618841Abstract: A method of depositing a film of a metal chalcogenide including the steps of: contacting an isolated hydrazinium-based precursor of a metal chalcogenide and a solvent having therein a solubilizing additive to form a solution of a complex thereof; applying the solution of the complex onto a substrate to produce a coating of the solution on the substrate; removing the solvent from the coating to produce a film of the complex on the substrate; and thereafter annealing the film of the complex to produce a metal chalcogenide film on the substrate. Also provided is a process for preparing an isolated hydrazinium-based precursor of a metal chalcogenide as well as a thin-film field-effect transistor device using the metal chalcogenides as the channel layer.Type: GrantFiled: August 21, 2006Date of Patent: November 17, 2009Assignee: International Business Machines CorporationInventors: David B Mitzi, Matthew W Copel
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Patent number: 7598545Abstract: The present invention is directed to CMOS structures that include at least one nMOS device located on one region of a semiconductor substrate; and at least one pMOS device located on another region of the semiconductor substrate. In accordance with the present invention, the at least one nMOS device includes a gate stack comprising a gate dielectric, a low workfunction elemental metal having a workfunction of less than 4.2 eV, an in-situ metallic capping layer, and a polysilicon encapsulation layer and the at least one pMOS includes a gate stack comprising a gate dielectric, a high workfunction elemental metal having a workfunction of greater than 4.9 eV, a metallic capping layer, and a polysilicon encapsulation layer. The present invention also provides methods of fabricating such a CMOS structure.Type: GrantFiled: April 21, 2005Date of Patent: October 6, 2009Assignee: International Business Machines CorporationInventors: Eduard A. Cartier, Matthew W. Copel, Bruce B. Doris, Rajarao Jammy, Young-Hee Kim, Barry P. Linder, Vijay Narayanan, Vamsi K. Paruchuri, Keith Kwong Hon Wong
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Publication number: 20090152642Abstract: The present invention provides a semiconductor structure including a semiconductor substrate having a plurality of source and drain diffusion regions located therein, each pair of source and drain diffusion regions are separated by a device channel. The structure further includes a first gate stack of pFET device located on top of some of the device channels, the first gate stack including a high-k gate dielectric, an insulating interlayer abutting the gate dielectric and a fully silicided metal gate electrode abutting the insulating interlayer, the insulating interlayer includes an insulating metal nitride that stabilizes threshold voltage and flatband voltage of the p-FET device to a targeted value and is one of aluminum oxynitride, boron nitride, boron oxynitride, gallium nitride, gallium oxynitride, indium nitride and indium oxynitride.Type: ApplicationFiled: January 16, 2009Publication date: June 18, 2009Applicant: International Business Machines CorporationInventors: Nestor A. Bojarczuk, JR., Cyril Cabral, JR., Eduard A. Cartier, Matthew W. Copel, Martin M. Frank, Evgeni P. Gousev, Supratik Guha, Rajarao Jammy, Vijay Narayanan, Vamsi K. Paruchuri
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Publication number: 20090039447Abstract: A method for fabricating an FET device is disclosed. The FET device has a gate insulator with a high-k dielectric portion, and a threshold modifying material. The method introduces a stabilizing material into the gate insulator in order to hinder one or more metals from the threshold modifying material to penetrate across the high-k portion of the gate insulator. The introduction of the stabilizing material may involve disposing a stabilizing agent over a layer which contains an oxide of the one or more metals. A stabilizing material may also be incorporated into the high-k dielectric. Application of the method may lead to FET devices with unique gate insulator structures.Type: ApplicationFiled: August 6, 2007Publication date: February 12, 2009Inventors: Matthew W. Copel, Bruce B. Doris, Vijay Narayanan, Yun-Yu Wang
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Patent number: 7488656Abstract: The present invention provides a method for removing charged defects from a material stack including a high k gate dielectric and a metal contact such that the final gate stack, which is useful in forming a pFET device, has a threshold voltage substantially within the silicon band gap and good carrier mobility. Specifically, the present invention provides a re-oxidation procedure that will restore the high k dielectric of a pFET device to its initial, low-defect state. It was unexpectedly determined that by exposing a material stack including a high k gate dielectric and a metal to dilute oxygen at low temperatures will substantially eliminate oxygen vacancies, resorting the device threshold to its proper value. Furthermore, it was determined that if dilute oxygen is used, it is possible to avoid undue oxidation of the underlying semiconductor substrate which would have a deleterious effect on the capacitance of the final metal-containing gate stack.Type: GrantFiled: April 29, 2005Date of Patent: February 10, 2009Assignee: International Business Machines CorporationInventors: Eduard A. Cartier, Matthew W. Copel, Supratik Guha, Richard A. Haight, Fenton R. McFeely, Vijay Narayanan
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Patent number: 7479683Abstract: The present invention provides a semiconductor structure including a semiconductor substrate having a plurality of source and drain diffusion regions located therein, each pair of source and drain diffusion regions are separated by a device channel. The structure further includes a first stack of a pFET device located on top of some of the device channels, the first gate stack including a high-k gate dielectric, an insulating interlayer abutting the gate dielectric and a fully silicided metal gate electrode abutting the insulating interlayer, the insulating interlayer includes an insulating metal nitride that stabilizes threshold voltage and flatband voltage of the p-FET device to a targeted value and is one of aluminum oxynitride, boron nitride, boron oxynitride, gallium nitride, gallium oxynitride, indium nitride and indium oxynitride.Type: GrantFiled: October 1, 2004Date of Patent: January 20, 2009Assignee: International Business Machines CorporationInventors: Nestor A. Bojarczuk, Jr., Cyril Cabral, Jr., Eduard A. Cartier, Matthew W. Copel, Martin M. Frank, Evgeni P. Gousev, Supratik Guha, Rajarao Jammy, Vijay Narayanan, Vamsi K. Paruchuri
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Publication number: 20090011610Abstract: A method of forming a CMOS structure, and the device produced therefrom, having improved threshold voltage and flatband voltage stability. The inventive method includes the steps of providing a semiconductor substrate having an nFET region and a pFET region; forming a dielectric stack atop the semiconductor substrate comprising an insulating interlayer atop a high k dielectric; removing the insulating interlayer from the nFET region without removing the insulating interlayer from the pFET region; and providing at least one gate stack in the pFET region and at least one gate stack in the nFET region. The insulating interlayer can be AlN or AlOxNy. The high k dielectric can be HfO2, hafnium silicate or hafnium silicon oxynitride. The insulating interlayer can be removed from the nFET region by a wet etch including a HCl/H2O2 peroxide solution.Type: ApplicationFiled: September 16, 2008Publication date: January 8, 2009Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Nestor A. Bojarczuk, JR., Cyril Cabral, JR., Eduard A. Cartier, Matthew W. Copel, Martin M. Frank, Evgeni P. Gousev, Supratik Guha, Rajarao Jammy, Vijay Narayanan, Vamsi K. Paruchuri
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Patent number: 7452767Abstract: A method of forming a CMOS structure, and the device produced therefrom, having improved threshold voltage and flatband voltage stability. The inventive method includes the steps of providing a semiconductor substrate having an nFET region and a pFET region; forming a dielectric stack atop the semiconductor substrate comprising an insulating interlayer atop a high k dielectric; removing the insulating interlayer from the nFET region without removing the insulating interlayer from the pFET region; and providing at least one gate stack in the pFET region and at least one gate stack in the nFET region. The insulating interlayer can be AlN or AlOxNy. The high k dielectric can be HfO2, hafnium silicate or hafnium silicon oxynitride. The insulating interlayer can be removed from the nFET region by a wet etch including a HCl/H2O2 peroxide solution.Type: GrantFiled: August 7, 2006Date of Patent: November 18, 2008Assignee: International Business Machines CorporationInventors: Nestor A. Bojarczuk, Jr., Cyril Cabral, Jr., Eduard A. Cartier, Matthew W. Copel, Martin M. Frank, Evgeni P. Gousev, Supratik Guha, Rajarao Jammy, Vijay Narayanan, Vamsi K. Paruchuri
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Patent number: 7446380Abstract: The present invention provides a metal stack structure that stabilizes the flatband voltage and threshold voltages of material stacks that include a Si-containing conductor and a Hf-based dielectric. This present invention stabilizes the flatband voltages and the threshold voltages by introducing a rare earth metal-containing layer into the material stack that introduces, via electronegativity differences, a shift in the threshold voltage to the desired voltage. Specifically, the present invention provides a metal stack comprising a hafnium-based dielectric; a rare earth metal-containing layer located atop of, or within, said hafnium-based dielectric; an electrically conductive capping layer located above said hafnium-based dielectric; and a Si-containing conductor.Type: GrantFiled: April 29, 2005Date of Patent: November 4, 2008Assignee: International Business Machines CorporationInventors: Nestor A. Bojarczuk, Jr., Michael P. Chudzik, Matthew W. Copel, Supratik Guha, Rajarao Jammy, Vijay Narayanan, Vamsi K. Paruchuri
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Publication number: 20080258198Abstract: The present invention provides a metal stack structure that stabilizes the flatband voltage and threshold voltages of material stacks that include a Si-containing conductor and a Hf-based dielectric. This present invention stabilizes the flatband voltages and the threshold voltages by introducing a rare earth metal-containing layer into the material stack that introduces, via electronegativity differences, a shift in the threshold voltage to the desired voltage. Specifically, the present invention provides a metal stack comprising: a hafnium-based dielectric; a rare earth metal-containing layer located atop of, or within, said hafnium-based dielectric; an electrically conductive capping layer located above said hafnium-based dielectric; and a Si-containing conductor.Type: ApplicationFiled: July 2, 2008Publication date: October 23, 2008Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Nestor A. Bojarczuk, Michael P. Chudzik, Matthew W. Copel, Supratik Guha, Rajarao Jammy, Vijay Narayanan, Vamsi K. Paruchuri
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Publication number: 20080182389Abstract: A semiconductor structure, particularly a pFET, which includes a dielectric material that has a dielectric constant of greater than that of SiO2 and a Ge or Si content of greater than 50% and at least one other means for threshold/flatband voltage tuning by material stack engineering is provided. The other means contemplated in the present invention include, for example, utilizing an insulating interlayer atop the dielectric for charge fixing and/or by forming an engineered channel region. The present invention also relates to a method of fabricating such a CMOS structure.Type: ApplicationFiled: April 4, 2008Publication date: July 31, 2008Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Eduard A. Cartier, Matthew W. Copel, Martin M. Frank, Evgeni P. Gousev, Paul C. Jamison, Rajarao Jammy, Barry P. Linder, Vijay Narayanan