Abstract: Methods for forming dual-metal gate CMOS transistors are described. An NMOS and a PMOS active area of a semiconductor substrate are separated by isolation regions. A metal layer is deposited over a gate dielectric layer in each active area. Silicon ions are implanted into the metal layer in one active area to form an implanted metal layer which is silicided to form a metal silicide layer. Thereafter, the metal layer and the metal silicide layer are patterned to form a metal gate in one active area and a metal silicide gate in the other active area wherein the active area having the gate with the higher work function is the PMOS active area. Alternatively, both gates may be metal silicide gates wherein the silicon concentrations of the two gates differ. Alternatively, a dummy gate may be formed in each of the active areas and covered with a dielectric layer. The dielectric layer is planarized thereby exposing the dummy gates. The dummy gates are removed leaving gate openings to the semiconductor substrate.

Abstract: A method of bonding a bonding element to a metal bonding pad comprises the following steps. A semiconductor structure having an exposed, recessed metal bonding pad within a layer opening is provided. The layer has an upper surface. A conductive cap having a predetermined thickness is formed over the metal bonding pad. A bonding element is bonded to the conductive cap to form an electrical connection with the metal bonding pad.

Abstract: A method for cleaning a semiconductor structure using vapor phase condensation with a thermally vaporized cleaning agent, a hydrocarbon vaporized by pressure variation, or a combination of the two. In the thermally vaporized cleaning agent process, a semiconductor structure is lowered into a vapor blanket in a thermal gradient cleaning chamber at atmospheric pressure formed by heating a liquid cleaning agent below the vapor blanket and cooling the liquid cleaning agent above the vapor blanket causing it to condense and return to the bottom of the thermal gradient cleaning chamber. The semiconductor structure is then raised above the vapor blanket and the cleaning agent condenses on all of the surfaces of the semiconductor structure removing contaminants and is returned to the bottom of the chamber by gravity.

Abstract: A damascene structure with reduced capacitance dielectric stacking comprise a passivation, a first dielectric, an etch stop, a second dielectric and a cap layer over a first conductive layer formed on a semiconductor. The passivation, the etch stop, and the cap layers comprise low dielectric constant materials carbon nitride, boron nitride, or boron carbon nitride. The stack is patterned to form a via opening to the first conductive layer. A trench opening is formed stopping on the etch stop layer. A barrier layer of TaN, WN, TaSiN or Ta and a second conductive material is applied to the openings. Passivation, etch stop, or cap layers can be formed with carbon nitride by magnetron sputtering from a graphite target in a nitrogen atmosphere; boron carbon nitride by magnetron sputtering from a graphite target in a nitrogen and B2H6 atmosphere; or boron nitride by PECVD using B2H6, ammonia, and nitrogen.

Abstract: Method and product for forming a dual damascene interconnect structure, wherein depositing a copper sulfide interface layer as sidewalls to the opening deters migration or diffusing of copper ions into the dielectric material.

Abstract: Methods for forming dual-metal gate CMOS transistors are described. An NMOS and a PMOS active area of a semiconductor substrate are separated by isolation regions. A metal layer is deposited over a gate dielectric layer in each active area. Oxygen ions are implanted into the metal layer in one active area to form an implanted metal layer which is oxidized to form a metal oxide layer. Thereafter, the metal layer and the metal oxide layer are patterned to form a metal gate in one active area and a metal oxide gate in the other active area wherein the active area having the gate with the higher work function is the PMOS active area. Alternatively, both gates may be metal oxide gates wherein the oxide concentrations of the two gates differ. Alternatively, a dummy gate may be formed in each of the active areas and covered with a dielectric layer. The dielectric layer is planarized thereby exposing the dummy gates. The dummy gates are removed leaving gate openings to the semiconductor substrate.

Abstract: A method for forming a single gate having a dual work-function is described. A gate electrode is formed overlying a gate dielectric layer on a substrate. Sidewalls of the gate electrode are selectively doped whereby the doped sidewalls have a first work-function and whereby a central portion of the gate electrode not doped has a second work-function to complete formation of a single gate having multiple work-functions in the fabrication of integrated circuits.

Abstract: An EUV photolithographic mask device and a method of fabricating the same. The EUV photolithographic mask comprises a multi-layer over an EUV masking substrate and a patterned light absorbing layer formed on the multi-layer. The method comprises the steps of forming a multi-layer on an EUV mask substrate, forming a light absorbing layer on the multi-layer, and etching an opening through the light absorbing layer to the multi-layer. The light absorbing layer includes a metal selected from the group comprising nickel, chromium, cobalt, and alloys thereof, and is preferably nickel.

Abstract: A method for forming a copper containing microelectronic structure. There is first provided a substrate. There is then formed over the substrate a copper containing microelectronic structure comprising a copper containing layer and a non-copper containing layer, where the non-copper containing layer has formed thereupon a copper containing residue. Finally, there is then stripped from the non-copper containing layer the copper containing residue while employing a stripper composition comprising a non-aqueous coordinating solvent and a halogen radical producing specie. Additionally, the copper so dissolved may be recovered from a non-aqueously solvated copper halide compound dissolved within the non-aqueous solvent.

Abstract: A method of bonding a wire to a metal bonding pad, comprising the following steps. A semiconductor die structure having an exposed metal bonding pad within a chamber is provided. The bonding pad has an upper surface. A hydrogen-plasma is produced within the chamber from a plasma source. The metal bonding pad is pre-cleaned and passivated with the hydrogen-plasma to remove any metal oxide formed on the metal bonding pad upper surface. A wire is then bonded to the passivated metal bonding pad.

Abstract: A process for fabricating vertical CMOS devices, featuring variable channel lengths, has been developed. Channel region openings are defined in composite insulator stacks, with the channel length of specific devices determined by the thickness of the composite insulator stack. Selective removal of specific components of the composite insulator stack, in a specific region, allows the depth of the channel openings to be varied. A subsequent epitaxial silicon growth procedure fills the variable depth channel openings, providing the variable length, channel regions for the vertical CMOS devices.

Abstract: A method of structures having dual gate oxide thicknesses, comprising the following steps. A substrate having first and second pillars is provided. The first and second pillars each having an outer side wall and an inner side wall. At least one of the outer or inner side walls of at least one of the first and second pillars is/are masked leaving at least one of the outer or inner side walls of at least one of the first and second pillars exposed. Dopants are then implanted through the at least one of the exposed outer or inner side walls modifying the surface of the at least one of the doped exposed outer or inner side walls. The at least one of the masked outer or inner side walls of at least one of the first and second pillars is/are unmasked.

Abstract: A method of forming narrow gates comprising the following steps. A substrate is provided having an overlying Si3N4 or an SiO2/Si3N4 stack gate dielectric layer. A gate material layer is formed over the gate dielectric layer. A hard mask layer is formed over the gate material layer. The hard mask layer and the gate material layer are patterned to form a hard mask/gate material layer stack. A planarized dielectric layer is formed surrounding the hard mask/gate material layer stack. The patterned hard mask layer is removed from over the patterned gate material layer to form a cavity having exposed dielectric layer side walls. Masking spacers are formed on the exposed dielectric layer side walls over a portion of the patterned gate material layer. The patterned gate material layer is etched using the masking spacers as masks to expose a portion of the gate dielectric layer. The planarized dielectric layer is removed. The masking spacers are removed to form narrow gates comprising gate material.

Abstract: A method for forming a single gate having a dual work-function is described. A gate electrode is formed overlying a gate dielectric layer on a substrate. Sidewalls of the gate electrode are selectively doped whereby the doped sidewalls have a first work-function and whereby a central portion of the gate electrode not doped has a second work-function to complete formation of a single gate having multiple work-functions in the fabrication of integrated circuits.

Abstract: A method of forming small features, comprising the following steps. A substrate having a dielectric layer formed thereover is provided. A spacing layer is formed over the dielectric layer. The spacing layer has a thickness equal to the thickness of the small feature to be formed. A patterned, re-flowable masking layer is formed over the spacing layer. The masking layer having a first opening with a width “L”. The patterned, re-flowable masking layer is re-flowed to form a patterned, re-flowed masking layer having a re-flowed first opening with a lower width “1”. The re-flowed first opening lower width “1” being less than the pre-reflowed first opening width “L”. The spacing layer is etched down to the dielectric layer using the patterned, re-flowed masking layer as a mask to form a second opening within the etched spacing layer having a width equal to the re-flowed first opening lower width “1”. Removing the patterned, re-flowed masking layer.

Abstract: A method of fabricating dual gate oxide thicknesses comprising the following steps. A substrate is provided having a first pillar and a second pillar. A gate dielectric layer is formed over the substrate and the first and second pillars. First and second thin spacers are formed over the gate dielectric layer covered side walls of the first and second pillars respectively. The second pillar is masked leaving the first pillar unmasked. The first thin spacers are removed from the unmasked first pillar. The mask is removed from the masked second pillar. The structure is oxidized to convert the second thin spacers to second preliminary gate oxide over the previously masked second pillar and to form first preliminary gate oxide over the unmasked first pillar. The second gate oxide over the second pillar being thicker than the first gate oxide over the first pillar.

Abstract: A method of forming narrow gates comprising the following steps. A substrate is provided having an overlying Si3N4 or an SiO2/Si3N4 stack gate dielectric layer. A gate material layer is formed over the gate dielectric layer. A hard mask layer is formed over the gate material layer. The hard mask layer and the gate material layer are patterned to form a hard mask/gate material layer stack. A planarized dielectric layer is formed surrounding the hard mask/gate material layer stack. The patterned hard mask layer is removed from over the patterned gate material layer to form a cavity having exposed dielectric layer side walls. Masking spacers are formed on the exposed dielectric layer side walls over a portion of the patterned gate material layer. The patterned gate material layer is etched using the masking spacers as masks to expose a portion of the gate dielectric layer. The planarized dielectric layer is removed. The masking spacers are removed to form narrow gates comprising gate material.

Abstract: A new apparatus is provided that can be applied to clean outer edges of semiconductor substrates. Under the first embodiment of the invention, a brush is mounted on the surface of the substrate around the periphery of the substrate, chemicals are fed to the surface that is being cleaned by means of a hollow core on which the cleaning brush is mounted. The surface that is being cleaned rotates at a relatively high speed thereby causing the chemicals that are deposited on this surface (by the brush) to remain in the edge of the surface. Under the second embodiment of the invention, a porous roller is mounted between a chemical reservoir and the surface that is being cleaned, the surface that is being cleaned rotates at a relatively high speed. The chemicals that are deposited by the interfacing porous roller onto the surface that is being cleaned therefore remain at the edge of this surface thereby causing optimum cleaning action of the edge of the surface.

Abstract: A method for making low sheet resistance local metal interconnections and improved transistor performance is described. The method involves patterning a polysilicon layer and a silicon nitride (Si3N4) cap layer over device areas to form FET gate electrodes, and the patterned polysilicon extends over the field oxide regions to form portions of the local interconnections. After forming source/drain areas and sidewall spacers on the FET gate electrodes, a silicon oxide (SiO2) insulating layer is deposited and polished back to the Si3N4 cap. The Si3N4 is then selectively removed over the patterned polysilicon layer, leaving recesses in the SiO2 layer. After etching contact openings in the SiO2 layer to the substrate, a high electrically conducting metal layer, having a barrier layer, is deposited and patterned to complete the local interconnections.

Abstract: An inexpensive and safe copper removal method in the fabrication of integrated circuits is described. Copper is stripped or removed by a chemical mixture comprising an ammonium salt, an amine, and water. The rate of copper stripping can be controlled by varying the concentration of the ammonium salt component and the amount of water in the mixture. Also a novel chemical mixture for stripping copper and removing copper contamination is provided. The novel chemical mixture for removing or stripping copper comprises an ammonium salt, an amine, and water. For example, the novel chemical mixture may comprise ammonium fluoride, water, and ethylenediamine in a ratio of 1:1:1.