Patents by Inventor Michael Graetzel

Michael Graetzel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10038150
    Abstract: The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n-dopants, as over of electrochemical devices, in particular in organic semiconductors. The complexes are further useful as over-discharge prevention and overvoltage protection agents.
    Type: Grant
    Filed: April 14, 2016
    Date of Patent: July 31, 2018
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Julian Burschka, Florian Kessler, Etienne Baranoff, Mohammad Khaja Nazeeruddin, Michael Graetzel, Shaik Mohammed Zakeeruddin, Anders Hagfeldt, Marina Freitag, Fabrizio Giordano
  • Publication number: 20180190911
    Abstract: The present invention relates to a compound of formula (I) based on a structure including functionalized spirofluorene and fused aromatics or non-aromatic rings with at least one heteroatom, and used as hole transporting material in a optoelectronic and/or photoelectrochemical device.
    Type: Application
    Filed: June 20, 2016
    Publication date: July 5, 2018
    Inventors: Michael Saliba, Mohammad Khaja Nazeeruddin, Michael Graetzel, Klaus-Hermann Dahmen, Gianluca Pozzi, Simonetta Orlandi
  • Publication number: 20180033973
    Abstract: The present invention relates to a compound of formula (I) based on carbazole substituted by diphenylamine and used as organic hole conductors or hole transporting material in an optoelectronic or photoelectrochemical device, with (I), D being selected from formula (1) or (2):
    Type: Application
    Filed: March 1, 2016
    Publication date: February 1, 2018
    Inventors: Paul Gratia, Mohammad Khaja Nazeeruddin, Michael Graetzel, Vytautas Getautis, Artiom Magomedov, Tadas Malinauskas, Maryte Daskeviciene
  • Publication number: 20180023198
    Abstract: The present disclosure relates to electrochemical utilization of carbon dioxide. The teachings may be embodied in methods and electrolysis systems in which carbon dioxide is introduced into an electrolysis cell and reduced at a cathode. For example, a reduction method for carbon dioxide utilization by means of an electrolysis system may include: delivering carbon dioxide into a chamber containing a cathode; introducing a first material in the cathode chamber, enabling catalysis of a reduction reaction of carbon dioxide to a hydrocarbon compound or to carbon monoxide; and introducing a second material together with the electrolyte or a reactant/electrolyte mixture into the cathode chamber or metered separately into the cathode chamber. The second material enables cocatalysis of the reduction reaction by promoting charge transfer from the cathode to the first material.
    Type: Application
    Filed: February 5, 2016
    Publication date: January 25, 2018
    Applicant: Siemens Aktiengesellschaft
    Inventors: Michael Graetzel, Christian Reller, Guenter Schmid, Marcel Schreier
  • Publication number: 20180006241
    Abstract: The present invention provides novel triazatruxene derivatives that are useful as hole transport materials (HTM), particularly, in optoelectronic devices. The utility of the novel compounds was confirmed in solid-state, sensitized solar cells based on organic-inorganic perovskites used as light harvesters. The devices achieved high power conversion efficiencies.
    Type: Application
    Filed: November 27, 2015
    Publication date: January 4, 2018
    Inventors: Shahzada AHMAD, Francisco Javier RAMOS, Samrana KAZIM, Manuel DOBLARE CASTELLANO, Mohammad Khaja NAZEERUDDIN, Michael GRAETZEL, Kasparas RAKSTYS
  • Patent number: 9812658
    Abstract: The present invention relates to compounds of formula (I) based on a porphyrin core and a ?-conjugated linker or acceptor introduced between the porphyrin core and an anchoring group having a high absorption coefficient covering the whole UV-Visible and near-infrared spectral response, and their use as sensitizer or dye and an electrochemical or optoelectronic device including a compound of the invention.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: November 7, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Chenyi Yi, Fabrizio Giordano, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Publication number: 20170301479
    Abstract: The present invention concerns a device for room temperature reverse-bias operation photo-detection. The device comprising:—a planar first electrode extending in a planar direction;—a second electrode positioned above the first electrode in a direction substantially perpendicular to said planar direction; and—an active region sandwiched between the first and second electrode. The active region consists of a light absorbing perovskite and wherein the light absorbing perovskite is in direct contact with at least one of the first and second electrodes.
    Type: Application
    Filed: August 31, 2015
    Publication date: October 19, 2017
    Inventors: Thomas MOEHL, Mohammad Khaja NAZEERUDDIN, Michael GRÄTZEL, Jeong-Hyeok IM, Nam-Gyu PARK, Konrad DOMANSKI
  • Patent number: 9779879
    Abstract: The present invention provides an improved redox couple for electrochemical and optoelectronic devices. The redox couple is based on a complex of a first row transition metal, said complex containing at least one mono-, bi-, or tridentate ligand comprising a substituted or unsubstituted ring or ring system comprising a five-membered N-containing heteroring and/or a six-membered ring comprising at least two heteroatoms, at least one of which being a nitrogen atom, said five- or six-membered heteroring, respectively, comprising at least one double bond. The invention also relates to electrolytes and to the devices containing the complex, and to the use of the complex as a redox couple. The invention further provides electrochemical and/or optoelectronic devices comprising a first and a second electrode and, between said first and second electrode, a charge transport layer, said a charge transport layer comprising tetracyanoborate ([B(CN)4]?) and a cationic metal complex functioning as redox-couple.
    Type: Grant
    Filed: February 24, 2012
    Date of Patent: October 3, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Mohammad Khaja Nazeeruddin, Michael Graetzel, Etienne Baranoff, Florian Kessler, Jun-Ho Yum, Aswani Yella, Hoi Nok Tsao, Shaik Mohammad Zakeeruddin
  • Patent number: 9730795
    Abstract: Endosseous implant to be applied to a human or animal bone, wherein the surface of the implant is made from titanium or a titanium alloy, said implant having a smooth or rough surface texture, which is characterized in that said surface has been treated with at least one selected organic phosphonate compound or a pharmaceutically acceptable salt or ester or an amide thereof; process for producing said implants.
    Type: Grant
    Filed: June 30, 2014
    Date of Patent: August 15, 2017
    Assignees: UNIVERSITE DE GENEVE, ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
    Inventors: Pierre Descouts, Björn-Owe Aronsson, Michael Grätzel, Carine Viornery, Peter Péchy
  • Publication number: 20170213651
    Abstract: The invention discloses a perovskite solar cell and a method of fabrication thereof. The perovskite solar cell sequentially comprises a transparent electrode, a mesoporous P-I-N framework and a counter electrode from the bottom to top; the mesoporous P-I-N framework is composed of an n-type semiconductor layer, an insulating layer, and a p-type semiconductor layer in a sequentially stacked mode, and the n-type semiconductor layer, the insulating layer and the p-type semiconductor layer all comprise mesopores filled with a perovskite material. The preparation method sequentially includes preparing the mesoporous P-I-N framework on a transparent conductive substrate through a spin-coating method or a screen printing method, filling with the perovskite material and preparing the counter electrode layer.
    Type: Application
    Filed: July 24, 2015
    Publication date: July 27, 2017
    Inventors: Mingkui WANG, Kun CAO, Jin CUI, Zhixiang ZUO, Yan SHEN, Shaik Mohammad ZAKEERUDDIN, Michael GRAETZEL
  • Patent number: 9716240
    Abstract: The present invention relates to novel compounds that are useful as ligands in organometallic dyes. More particularly, the invention relates to dyes comprising the compounds, said dyes being sensitizing dyes useful in solar cell technology. According to an embodiment, the present invention discloses new ruthenium dyes and their application in dye-sensitized solar cells (DSC). The referred ruthenium dyes with new structural features can be easily synthesized, show more than 85% light-to-electricity conversion efficiency and a higher than 9% cell efficiency.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: July 25, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Feifei Gao, Yuan Wang, Jing Zhang, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 9697956
    Abstract: The present invention relates to compounds of formula (I) based on DPP moiety being useful as metal-free organic sensitizers or dyes of type D-?-A in electrochemical or optoelectronic devices, their use as sensitizer or dye and an electrochemical or optoelectronic device comprising a compound of the invention.
    Type: Grant
    Filed: August 14, 2013
    Date of Patent: July 4, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Thomas Wesley Holcombe, Jun Ho Yum, Mohammad Khaja Nazeeruddin, Michael Graetzel
  • Publication number: 20170162811
    Abstract: The present invention relates to a solid state photovoltaic device including an absorbing layer containing a light harvester and at least one templating agent, with the absorbing layer being prepared in a single step.
    Type: Application
    Filed: July 3, 2015
    Publication date: June 8, 2017
    Inventors: Xiong LI, Shaik Mohammad ZAKEERUDDIN, Michael GRAETZEL
  • Patent number: 9559321
    Abstract: The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n-dopants, as over of electrochemical devices, in particular in organic semiconductors. The complexes are further useful as over-discharge prevention and overvoltage protection agents.
    Type: Grant
    Filed: February 24, 2012
    Date of Patent: January 31, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Julian Burschka, Florian Kessler, Etienne Baranoff, Mohammad Khaja Nazeeruddin, Michael Graetzel
  • Publication number: 20160351342
    Abstract: The present invention relates to a compound of formula (I) based on compound derived from Acceptor-Donor-Acceptor (A-D-A) oligothiophenes based on heteroacene core and used as hole transporting material in a photovoltaic device, in particular in a solid state solar cell.
    Type: Application
    Filed: January 27, 2015
    Publication date: December 1, 2016
    Inventors: Shaik Mohammed Zakeeruddin, Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Qin, Amaresh Mishra, Hannelore Kast, Peter Bauerle
  • Publication number: 20160329162
    Abstract: The present invention relates to a compound of formula (I) based on quinozilino acridine and used as hole transporting and light absorbing material in a photovoltaic device, in particular in a solid state solar cell.
    Type: Application
    Filed: January 13, 2015
    Publication date: November 10, 2016
    Inventors: Peng Qin, Mohammad Khaja Nazeeruddin, Michael Graetzel, Jaejung Ko, Sanghyun Paek, Nara Cho
  • Publication number: 20160308150
    Abstract: The present invention relates to compounds of formula (I) based on a porphyrin core and a ?-conjugated linker or acceptor introduced between the porphyrin core and an anchoring group having a high absorption coefficient covering the whole UV-Visible and near-infrared spectral response, and their use as sensitizer or dye and an electrochemical or optoelectronic device including a compound of the invention.
    Type: Application
    Filed: December 4, 2014
    Publication date: October 20, 2016
    Applicant: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Chenyi Yi, Fabrizio Giordano, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 9460861
    Abstract: The present invention relates to modified surfaces. The surfaces comprise an inorganic material on which a phosphinic acid derivative is adsorbed. The phosphinic acid thus turns out to be a new anchoring group useful for surface derivatization. The invention has many applications for photoelectric conversion devices, batteries, capacitors, electrochromic displays, chemical sensors, biological sensors, light emitting diodes, electrodes, semiconductors, separation membranes, selective adsorbents, adsorbents for HPLC, catalysts, implants, nanoparticles, antiadhesives, and anticorrosion coatings, for example.
    Type: Grant
    Filed: June 30, 2014
    Date of Patent: October 4, 2016
    Assignee: Ecole Polytechnique Federale De Lausanne (EPFL)
    Inventors: Shaik Mohammad Zakeeruddin, Peter Pechy, Michael Graetzel
  • Publication number: 20160233439
    Abstract: The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n-dopants, as over of electrochemical devices, in particular in organic semiconductors. The complexes are further useful as over-discharge prevention and overvoltage protection agents.
    Type: Application
    Filed: April 14, 2016
    Publication date: August 11, 2016
    Inventors: Julian Burschka, Florian Kessler, Etienne Baranoff, Mohammad Khaja Nazeeruddin, Michael Graetzel, Shaik Mohammad Zakeeruddin, Anders Hagfeldt, Marina Freitag, Fabrizio Giordano
  • Publication number: 20160226011
    Abstract: The present invention relates to a method for producing a solid solar cells, including the steps of providing a hole collector layer, applying a conductive layer onto the hole collector layer, applying an electron blocking layer onto the conductive layer, applying a sensitizer layer onto the electron blocking layer, applying a hole blocking layer onto the sensitizer layer, and providing a current collector and/or a metal layer or a conductor. The sensitizer layer including an organic-inorganic perovskite is applied by co-deposition of one or more sublimated divalent or trivalent salts and of one or more sublimated organic ammonium salts to obtain the organic-inorganic perovskite. The invention also relates to solid state solar cells, wherein the charge flow is inverted compared to the charge flow in a solar cell of conventional architecture and/or obtained by the above method.
    Type: Application
    Filed: September 5, 2014
    Publication date: August 4, 2016
    Inventors: Mohammad Khaja Nazeeruddin, Michael Graetzel, Hendrik Jan Bolink, Olga Malinkiewicz, Alejandra Soriano Portillo