Abstract: Multi-layered golf balls having a core, intermediate layer, and cover are provided. The ball includes a non-foamed inner core (center) made of a thermoplastic or thermoset composition such as polybutadiene rubber. An intermediate layer comprising a foamed composition, such as polyurethane foam, is disposed about the inner core. The foamed intermediate layer may have a specific gravity gradient within the layer, wherein the outer surface specific gravity is greater than the midpoint specific gravity. Ball constructions having two intermediate layers, wherein at least one layer is a foamed layer can be made. A cover having at least one layer is disposed about the intermediate layer.

Abstract: Multi-piece golf balls containing a dual-layered core and dual-layered cover are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, and a surrounding outer core layer. The core layers may have different hardness gradients. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and combinations and alloys thereof preferably dispersed in a thermoplastic polymeric matrix. The outer core layer is preferably formed from a thermoset composition such as polybutadiene. The multi-layered cores and covers have selective specific gravity relationships between the different layers. This helps provide the ball with good flight distance and spin control. The resulting balls have good resiliency and other playing performance properties.

Abstract: The present invention generally relates to golf balls having an internal skeletal structure that can be self-supporting. The golf ball preferably contains a spherical hollow inner core that is gas or liquid-filled. The ball further comprises an outer shell skeletal structure having a spherical shape and containing apertures that form hollow compartments. In one version, the skeletal structure supports itself and the space inside and around the skeletal structure is hollow. In another embodiment, the space is solid, for example, it may be foam-filled. In yet another version, the hollow space is filled with liquid. Multi-piece golf balls having outer cores, inner covers, and intermediate layers can be made.

Abstract: Golf balls having a single or dual-layered solid core are provided. In one embodiment, the golf ball has dimensions and properties that do not conform to the rules of the United States Golf Association (USGA). For example, the ball weight; ball size; ball spherical symmetry; ball initial velocity; and/or ball overall distance may fall outside of the USGA standards. The dual-layered core can have an inner core comprising a thermoplastic composition and surrounding outer core comprising a thermoset composition. In another embodiment, the dual-layered core has an inner core comprising a thermoplastic composition and outer core comprising a thermoset composition. The thermoplastic composition preferably comprises an ethylene acid copolymer ionomer and plasticizer. The thermoset composition preferably comprises polybutadiene rubber. The ball further includes a cover of at least one layer.

Abstract: Multi-piece golf balls having a solid core made of a foamed composition and a cover are provided. Preferably, the core is dual-layered having has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition containing mineral filler particulate, for example, nanoclay particles, is used to form the foam center. The concentration of clay particulate is preferably in a range of 0.1 to 60% by weight. The surrounding outer core layer may be made from non-foamed or foamed compositions. For example, polybutadiene rubber or highly neutralized olefin acid copolymers may be used in the outer core layer. The core layers have different hardness gradients and specific gravity values.

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a center, an intermediate core layer, and an outer core layer. At least one layer of the multi-layer core is a high specific gravity layer.

Abstract: Low compression, multi-piece golf balls containing a solid core and two or three-layered cover assemblies are provided. Preferably, the ball has a compression of less than 60 and more preferably less than 50. At least one cover layer is made of a plasticized thermoplastic composition. For example, two-layered and three-layered covers may be made. Preferably, the plasticized thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate or butyl oleate is preferably used as the plasticizer. The cover assembly has good impact durability and helps provide the ball with relatively high resiliency at given compressions.

Abstract: Multi-piece golf balls containing a multi-layered core structure are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, an intermediate core layer, and a surrounding outer core layer. The layers of the core structure may have different hardness gradients. In one preferred embodiment, each core layer has a positive hardness gradient. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and alloys thereof. The intermediate core layer is preferably formed from a first thermoset composition such as polybutadiene rubber, and the outer core layer is preferably formed from a second thermoset composition. The resulting ball has high resiliency and good spin control.

Abstract: Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

Abstract: Golf balls including a spherical inner core shell layer formed from a thermoset or thermoplastic composition are provided. The shell layer has an outer surface, an inner surface, and an inner diameter to define a hollow center. A thermoset or thermoplastic outer core layer is formed about the shell layer and optional intermediate layer(s) disposed between the shell layer and the outer core layer. A cover is formed about the outer core layer.

Abstract: Golf balls comprising a core having at least one layer and a cover having at least one layer are provided. At least one of the layers is made from a thermoplastic composition preferably comprising a telechelic ionomer derived from alkyl-cis-cyclooctene and cis-cyclooctene. The telechelic ionomer composition also may be used to form intermediate layers. Blends of telechelic ionomers and polybutadiene rubbers or ethylene acid copolymers can be prepared. The telechelic ionomer compositions can be used to make a cover layer having good impact durability and shear resistance and that also helps provide the ball with high resiliency.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and acid copolymer ionomer. The cover composition also can contain hydroxyl-containing compounds. The golf ball having the thermoplastic polyurethane cover can be treated with an isocyanate compound. The golf ball also can be treated with a hydroxyl and/or silane-containing compound. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and multi-functional hydroxyl compound. Mixtures of multi-functional amines and imines, and multi-functional isocyanates, and solvent, can be applied to the outer cover to form at least a partially cross-linked cover. The cover composition can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a center, an intermediate core layer, and an outer core layer. At least one layer of the multi-layer core is a high specific gravity layer.

Abstract: A golf ball including a core; an inner cover layer formed from a first thermoplastic composition and having a thickness of about 0.005 inches to 0.40 inches and a surface hardness of about 60 Shore D or greater; and an outer cover layer formed from a thermoplastic polyurethane material and having a thickness of about 0.01 inches to 0.075 inches and a surface hardness of about 60 Shore D or less. The thermoplastic composition has a first melt flow index at 280° C. under a 10-kg load of less than about 35 g/10 min and a second melt flow index at 265° C. under a 5-kg load of less than about 10 g/10 min.

Abstract: Multi-piece golf balls having a solid core made of a foamed composition and a cover are provided. Preferably, the core is dual-layered having has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition containing mineral filler particulate, for example, nanoclay particles, is used to form the foam center. The concentration of clay particulate is preferably in a range of 0.1 to 60% by weight. The surrounding outer core layer may be made from non-foamed or foamed compositions. For example, polybutadiene rubber or highly neutralized olefin acid copolymers may be used in the outer core layer. The core layers have different hardness gradients and specific gravity values.

Abstract: Multi-piece golf balls containing a dual-layered core structure are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, and a surrounding outer core layer. The layers of the core structure may have different hardness gradients. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and alloys thereof preferably dispersed in a thermoplastic polymeric matrix. Different plasticizers such as fatty acid esters may be used. The outer core layer is preferably formed from a thermoset composition such as polybutadiene. The resulting ball has high resiliency and good spin.

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises at least three layers, including at least one thermoset layer and at least one thermoplastic layer. The innermost core layer is relatively small, having a diameter of from 0.50 inches to 1.30 inches.

Abstract: Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

Abstract: Golf balls having a multi-layered core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The foam inner core preferably includes a fully-foamed center region and a partially or completely-collapsed foam outer region. The hardness of the fully-foamed region is different than the hardness of the collapsed foam region. Non-foamed thermoset or thermoplastic materials such as polybutadiene rubbers or ethylene acid copolymer ionomer may be used to form the outer core layer. The ball further includes a cover that may be multi-layered. The foam cores have good resiliency.