Abstract: The present invention relates to optical fiber coating systems capable of providing a high degree of microbend protection to an optical fiber, and an optical fiber coated therewith. According to one embodiment of the invention, an optical fiber coating system includes a primary coating and a secondary coating, wherein when a ribbon having twelve large effective area optical fibers coated with the coating system is subjected to the ribbon optical performance test at a wavelength of 1550 nm, the average change in attenuation is about 0.020 dB/km or less.

Abstract: The invention includes a composition for an optical fiber coating. An inventive composition includes a non-thiol functional adhesion promoter and less than about 0.5 pph of a strength additive containing a thiol functional group. The invention further includes an optical fiber coated with the inventive composition. A second inventive composition includes a photo-polymerizable composition which contains an adhesion promoter and a non-silicon containing strength additive containing at least about one thiol functional group. A third inventive composition includes a photo-polymerizable composition which has a silane containing adhesion promoter and a strength additive containing at least about one halide functional group. The invention also includes an optical fiber coated with the inventive coating and methods of making an optical fiber including the inventive coating.

Abstract: A method of minimizing localized heating of, or minimizing signal losses across a source of loss in, an optical fiber used in transmission of a high power optical signal at an operating wavelength. These methods include the steps of: providing an optical fiber which comprises either (i) a coating characterized by an absorbance of less than about 4.5 dB/cm at the operating wavelength or (ii) a refractive index lower than the refractive index of a cladding layer of the optical fiber by more than about 3×10?3 at the operating wavelength, or (iii) both (i) and (ii); and transmitting a optical signal having a power greater than about 250 mW through the optical fiber, wherein the coating, cladding layer, or combination thereof are selected to minimize localized heating of the optical fiber or to result in a signal loss across a source of loss that is less than about 250 mW at the operating wavelength.

Abstract: The present invention provides optical fiber coating systems and coated optical fibers. According to one embodiment of the invention, a coated optical fiber includes an optical fiber having a core and a cladding; and a primary coating encapsulating the optical fiber, the primary coating having a Young's modulus of about 5 MPa or less, the primary coating being the cured reaction product of a primary curable composition having a gel time less than about 1.4 seconds at a UV intensity of 3.4 mW/cm2.

Abstract: Fiber optic articles, assemblies, and cables preserve optical performance by using optical waveguides having a core, a cladding, and a coating system according to the present invention. Moreover, the optical articles, assemblies, and cables of the present invention may achieve performance levels that were previously unattainable, for instance, the present invention contemplates acceptable optical performance for wavelengths such as 1625 nm and higher. Additionally, articles, assemblies, and/or cables of the present invention advantageously preserve optical performance, i.e., have relatively low delta attenuation, when subjected to manufacturing processes and/or environmental conditions such as temperature cycling. In other words, the articles, assemblies, and cables can withstand increased stress/strain before having significant attenuation.

Abstract: The present invention provides optical fiber coating systems and coated optical fibers. According to one embodiment of the invention, a coated optical fiber includes an optical fiber having a core and a cladding; and a primary coating encapsulating the optical fiber, the primary coating having a Young's modulus of about 5 MPa or less, the primary coating being the cured reaction product of a primary curable composition having a gel time less than about 1.4 seconds at a UV intensity of 3.4 mW/cm2.

Abstract: The present invention provides optical fiber coating systems and coated optical fibers having hydrophilic primary coatings. According to one embodiment of the invention, a coated optical fiber includes an optical fiber having a core and a cladding; a hydrophilic primary coating encapsulating the optical fiber, the primary coating having a Young's modulus less than about 2 MPa; and a secondary coating encapsulating the primary coating, wherein the primary coating exhibits substantially no water bubble formation and substantially no delamination when the coated optical fiber is soaked in water at 23° C. for 30 days.

Abstract: The present invention is directed to a radiation curable primary coating composition and an optical fiber with said coating. The primary coating preferably results in excellent mechanical and physical properties, and when coated on optical fibers in a reduction in micro-bending transmission losses over optical fibers with conventional coatings. In one embodiment of this invention, it relates to a coated optical fiber comprising an optical fiber and a radiation cured primary coating wherein the radiation cured primary coating on the optical fiber comprises an oligomer and wherein the oligomer is formed from a reaction comprising a polyol having “m” hydroxyl functional groups, wherein “n” hydroxyl groups of said polyol are terminated in forming the oligomer and “m” is greater than “n”.

Abstract: The present invention relates to a composition for coating optical fibers that includes an oligomeric component present in an amount of about 15 weight percent or less and a monomeric component present in an amount of about 75 weight percent or more, where the cured product of the composition has a Young's modulus of at least about 650 MPa. When the composition is substantially devoid of the oligomeric component, the monomeric component preferably includes two or more monomers. Also disclosed are the cured products of the compositions of the present invention, optical fibers that contain secondary coatings prepared from the compositions of the present invention, methods of making such optical fibers, as well as fiber optic ribbons containing a matrix prepared from the compositions of the present invention.

Abstract: The present invention relates to an optical fiber including a glass fiber and a primary coating encapsulating and in contact with the glass fiber, the primary coating being the cured product of a polyrnerizable composition which includes a monomer with a pendant hydroxyl functional group which can bond with a surface of the optical fiber and is present in an amount effective to promote adhesion. The present invention also relates to methods of making such optical fibers.

Abstract: The invention disclosed includes a coating composition for siliceous surfaces. The coating includes at least one component from the group consisting of poly(alkoxy)silane, poly(halo)silane, alkoxysilane, halosilane, and mixtures thereof and a catalyst compound which generates a proton to hydrolyze the component when exposed to radiation. Preferably, the catalyst is a photo-acid. The invention also includes a method of coating the optical fiber. The aforementioned coating is applied to an exterior surface of the fiber. A proton is generated to promote the hydrolysis of the component. The invention further includes a method of accelerating adhesion between the exterior surface of the article and the coating. The inventive coating is applied to the surface of the fiber and the coating is exposed to a radiation source.

Abstract: The invention includes a composition for an optical fiber coating. An inventive composition includes a non-thiol functional adhesion promoter and less than about 0.5 pph of a strength additive containing a thiol functional group. The invention further includes an optical fiber coated with the inventive composition. A second inventive composition includes a photo-polymerizable composition which contains an adhesion promoter and a non- silicon containing strength additive containing at least about one thiol functional group. A third inventive composition includes a photo-polymerizable composition which has a silane containing adhesion promoter and a strength additive containing at least about one halide functional group. The invention also includes an optical fiber coated with the inventive coating and methods of making an optical fiber including the inventive coating.

Abstract: The present invention relates to a composition for preparing optical fiber coatings, the composition including a polymerizable base composition, containing at least one monomer and optionally at least one oligomer, wherein the polymerizable base composition is substantially free of unsaturated epoxidized diene polymers, and a tackifier present in an amount effective to modify a time-sensitive rheological property of a polymerization product of the composition. Another aspect of the present invention relates to a method of modifying a time-sensitive rheological property of an optical fiber coating by introducing into a polymerizable composition a tackifier in an amount effective to modify a time-sensitive rheological property of the polymerization product of the polymerizable composition. Also disclosed are an optical fiber, a fiber optic ribbon, and a fiber bundle that contain coating(s) prepared from a composition of the present invention.

Abstract: The disclosed invention relates to a method of drying an optical fiber coating. The method includes blending a plurality of raw materials capable of forming an optical fiber coating and dehydrating the plurality. One embodiment of the method includes drying the optical fiber coating by passing a dehydrating medium over a top surface of a body of the plurality of materials. A second embodiment of the invention includes bubbling a dehydrating medium through the body of the plurality of raw materials. In a third embodiment of the invention, the plurality is dehydrated by reacting the water in the plurality with a dehydrating medium that includes a compound having a functional group that is capable of reacting with the water.

Abstract: The present invention is directed to a radiation curable primary coating composition and an optical fiber with said coating. The primary coating preferably results in excellent mechanical and physical properties, and when coated on optical fibers in a reduction in micro-bending transmission losses over optical fibers with conventional coatings. In one embodiment of this invention, it relates to a coated optical fiber comprising an optical fiber and a radiation cured primary coating wherein the radiation cured primary coating on the optical fiber comprises an oligomer and wherein the oligomer is formed from a reaction comprising a polyol having “m” hydroxyl functional groups, wherein “n” hydroxyl groups of said polyol are terminated in forming the oligomer and “m” is greater than “n”.

Abstract: The present invention relates to a coating for an optical fiber. The coating includes a monomer. The monomer includes an oxyglycidyl (meth)acrylate component. A coating with the monomeric component has exhibited an excellent polymerization rate. The present invention also relates to methods of making such optical fibers coated in accordance with the invention and the coated glass article.

Abstract: The invention disclosed includes a coating composition for siliceous surfaces. The coating includes at least one component from the group consisting of poly(alkoxy)silane, poly(halo)silane, alkoxysilane, halosilane, and mixtures thereof and a catalyst compound which generates a proton to hydrolyze the component when exposed to radiation. Preferably, the catalyst is a photo-acid. The invention also includes a method of coating the optical fiber. The aforementioned coating is applied to an exterior surface of the fiber. A proton is generated to promote the hydrolysis of the component. The invention further includes a method of accelerating adhesion between the exterior surface of the article and the coating. The inventive coating is applied to the surface of the fiber and the coating is exposed to a radiation source.

Abstract: The present invention relates to a composition for preparing optical fiber coatings, the composition including a polymerizable base composition, containing at least one monomer and optionally at least one oligomer, wherein the polymerizable base composition is substantially free of unsaturated epoxidized diene polymers, and a tackifier present in an amount effective to modify a time-sensitive rheological property of a polymerization product of the composition. Another aspect of the present invention relates to a method of modifying a time-sensitive theological property of an optical fiber coating by introducing into a polymerizable composition a tackifier in an amount effective to modify a time-sensitive rheological property of the polymerization product of the polymerizable composition. Also disclosed are an optical fiber, a fiber optic ribbon, and a fiber bundle that contain coating(s) prepared from a composition of the present invention.

Abstract: The present invention relates to a composition for coating optical fibers which contains an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, and an adhesion promoter which includes a compound containing a cyclic structure interposed between at least two reactive silanes which are independently an alkoxysilane or a halosilane. Another composition of the present invention includes an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, an adhesion promoter which includes a compound containing a reactive silane group, and a carrier. The present invention also relates to optical fibers and methods of making such optical fibers using the compositions of the present invention.

Abstract: The present invention relates to a composition for coating optical fibers which contains an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, and an adhesion promoter which includes a compound containing a cyclic structure interposed between at least two reactive silanes which are independently an alkoxysilane or a halosilane. Another composition of the present invention includes an oligomer capable of being polymerized, a monomer suitable to control the viscosity of the composition, an adhesion promoter which includes a compound containing a reactive silane group, and a carrier. The present invention also relates to optical fibers and methods of making such optical fibers using the compositions of the present invention.