Abstract: A pre-lithiation reaction chamber apparatus including a pre-lithiation reaction vessel which can prevent harmful effects caused by water that may be generated during pre-lithiation is provided. The pre-lithiation reaction vessel includes an electrolyte including a lithium salt, a negative electrode for a lithium secondary battery and a lithium ion-supplying member. Each of the negative electrode for the lithium secondary battery and the lithium ion-supplying member is at least partially in contact with the electrolyte. The pre-lithiation reaction chamber apparatus further includes a water-capturing vessel. The water-capturing vessel includes water-capturing powder, a container configured to receive the water-capturing powder, and a position-changing member configured to change a position of the water-capturing powder in the container.

Abstract: A prelithiated negative electrode, and a secondary battery including a prelithiated electrode, including a negative electrode current collector; and a negative electrode active material layer present on at least one surface of the negative electrode current collector. The negative electrode active material layer includes high-capacity artificial graphite having no carbon coating. The negative electrode active material layer is prelithiated, and the content of lithium intercalated to the prelithiated negative electrode active material layer is 3% to 5% based on the lithium content intercalated when the negative electrode is charged to 100%.

Abstract: A method of preparing a negative electrode for a lithium secondary battery, which includes forming a negative electrode mixture layer including a negative electrode active material on a negative electrode current collector, disposing lithium metal powder on at least a part of the negative electrode mixture layer, pressing the negative electrode mixture layer on which the lithium metal powder is disposed, wetting the pressed negative electrode mixture layer with a first electrolyte solution, and drying the wet negative electrode mixture layer. A battery including the negative electrode of the present invention has enhanced rapid charge/discharge characteristics and enhanced lifespan characteristics.

Abstract: A negative electrode active material including a core including silicon, and a coating layer disposed on at least a portion of a surface of the core and including a coating material, wherein the coating material includes at least one selected from the group consisting of LiaVbO2 and MgH2, wherein 0.5<a<1.5 and 0.5<b<1.5 is provided. Also, a negative electrode including the negative electrode active material and a lithium secondary battery including the negative electrode, are provided.

Abstract: A negative electrode for a lithium secondary battery and a lithium secondary battery including the negative electrode are disclosed. The negative electrode includes a negative electrode current collector, a first negative electrode active material layer present on the negative electrode current collector, and a second negative electrode active material layer present on the first negative electrode active material layer. The first negative electrode active material layer includes two or more kinds of first negative electrode active materials, and the second negative electrode active material layer includes a second negative electrode active material having swelling that is smaller than that of the first negative electrode active material layer. Therefore, the surface of the negative electrode does not exhibit deformation during pre-lithiation.

Abstract: A separator including: a porous polymer substrate having a plurality of pores; and a coating layer formed on at least one surface of the porous polymer substrate, and including a plurality of lithium-containing composite particles and a binder positioned on the whole or a part of the surface of the lithium-containing composite particles to connect and fix the lithium-containing composite particles with each other, wherein the lithium-containing composite particles includes a lithiated compound and a passivation film formed on the surface of the lithiated compound, and the passivation film includes a solid electrolyte interface (SEI). A lithium secondary battery including the separator and a method for manufacturing the lithium secondary battery are also provided.

Abstract: A method of manufacturing a negative electrode for a lithium secondary battery, the method includes forming a negative electrode active material layer on a negative electrode current collector to manufacture a negative electrode assembly, and pre-lithiating the negative electrode assembly. The pre-lithiating of the negative electrode assembly includes a first pre-lithiation step of performing pre-lithiation by impregnating the negative electrode assembly with a first pre-lithiation solution and a second pre-lithiation step of performing pre-lithiation by impregnating the negative electrode assembly with a second pre-lithiation solution after the first pre-lithiation step. The first pre-lithiation solution includes an ionizable first lithium salt, a first organic solvent, and a first additive. The second pre-lithiation solution includes an ionizable second lithium salt, a second organic solvent, and a second additive.

Abstract: A method of preparing a negative electrode which includes preparing a negative electrode structure including expanded natural graphite, impregnating the negative electrode structure with a pre-lithiation solution to form an impregnated negative electrode structure, and pre-lithiating the impregnated negative electrode structure by electrochemically charging the impregnated negative electrode structure to 10% to 20% of charge capacity of the negative electrode structure.

Abstract: A separator including: a porous polymer substrate having a plurality of pores; and a coating layer formed on at least one surface of the porous polymer substrate, and including a plurality of lithium-containing composite particles and a binder positioned on the whole or a part of the surface of the lithium-containing composite particles to connect and fix the lithium-containing composite particles with each other, wherein the lithium-containing composite particles includes a lithiated compound and a passivation film formed on the surface of the lithiated compound, and the passivation film includes a solid electrolyte interface (SEI). A lithium secondary battery including the separator and a method for manufacturing the lithium secondary battery are also provided.

Abstract: The present invention relates to a negative electrode for a secondary battery which comprises a negative electrode collector, a negative electrode active material layer formed on the negative electrode collector, and a lithium metal layer, wherein an adhesive layer is disposed between the negative electrode active material layer and the lithium metal layer, and the lithium metal layer comprises lithium and metal oxide in a weight ratio of 50:50 to 99:1.

Abstract: Disclosed is a method of manufacturing a secondary battery, the method including: manufacturing a pre-lithiation cell including a negative electrode and a lithium metal counter electrode and pre-lithiating the negative electrode by charging the pre-lithiation cell; separating the pre-lithiated negative electrode from the pre-lithiation cell and manufacturing an electrode assembly including the pre-lithiated negative electrode and a positive electrode; impregnating the electrode assembly with an electrolyte; activating the impregnated electrode assembly by performing a first charging the impregnated electrode assembly; removing gas generated in the activation; discharging the activated electrode assembly immediately after removing the gas; and performing a second charging on the discharged electrode assembly.

Abstract: A method of manufacturing a negative electrode wherein, in the pre-lithiation of a negative electrode structure including a negative electrode active material layer formed therein through electrochemical charging in a roll-to-roll manner, the negative electrode active material layer is divided into a central part and a side part. The charge current applied to the central part is higher than the charge current applied to the side part. In addition, in the method of manufacturing the negative electrode a pre-lithiation section is divided into a first section and a second section, the central part is electrochemically charged in the first section, the side part is electrochemically charged in the second section, and the central part and the side part are alternately electrochemically charged in one or more cycles.

Abstract: A method for pre-lithiation of a negative electrode including the steps of: interposing a separator between a lithium ion-supplying metal sheet and a negative electrode to prepare a simple cell; dipping the simple cell in an electrolyte for pre-lithiation; and disposing the simple cell dipped in the electrolyte for pre-lithiation between two polymer pads, and carrying out electrochemical charging, while pressurizing the outside of the two polymer pads, to perform pre-lithiation of the negative electrode. Each of the polymer pads has a thickness of 60% to 90% of a thickness of a corresponding jig of the pair of jigs. A pre-lithiated negative electrode and a lithium secondary battery including the pre-lithiated negative electrode are also disclosed.

Abstract: A method of manufacturing a negative electrode includes providing a negative electrode roll on which a negative electrode structure including a negative electrode current collector, a first negative electrode active material layer formed on one side of the negative electrode current collector, and a second negative electrode active material layer formed on the other side of the negative electrode current collector is wound, preparing a pre-lithiation bath including an impregnation section and a pre-lithiation section and containing a pre-lithiation solution, unwinding the negative electrode structure, moving the negative electrode structure to the impregnation section, and impregnating the negative electrode structure with the pre-lithiation solution; and pre-lithiating the negative electrode structure by moving the same from the impregnation section to the pre-lithiation section.

Abstract: A method for pre-lithiating a silicon oxide negative electrode for a secondary battery, specifically a method for pre-lithiation by immersing the silicon oxide negative electrode in an electrolytic solution for wetting, and by applying pressure while a lithium metal is in direct contact with the wetted silicon oxide negative electrode. The silicon oxide negative electrode for a secondary battery manufactured through pre-lithiation provided in the present disclosure has improved initial irreversibility, and a secondary battery manufactured using such a silicon oxide negative electrode for a secondary battery has excellent charge/discharge efficiency.

Abstract: The present invention relates to a secondary battery. The secondary battery according to the present invention may include an electrode assembly, an electrolyte, and a battery case configured to accommodate the electrode assembly and the electrolyte. The battery case may include a main body having accommodation space in which the electrode assembly and the electrolyte are accommodated, an additional electrolyte accommodation part having a storage space in which an additional electrolyte is accommodated, a connection part configured to form a moving passage through which the additional electrolyte is supplied from the addition electrolyte accommodation part to the main body, and an electrolyte impregnation member provided on the connection part and impregnated with the additional electrolyte.

Abstract: An apparatus for pre-lithiating a negative includes a pre-lithiation reactor sequentially divided into an impregnation section, a pre-lithiation section and an aging section, and accommodates a pre-lithiation solution in which a negative electrode structure is moved; a negative electrode roll arranged outside the pre-lithiation solution and on which the negative electrode structure before being moved is wound; a lithium metal counter electrode arranged in the pre-lithiation solution in the pre-lithiation section and is spaced apart from the negative electrode structure by a predetermined distance to face the negative electrode structure which is moved in the pre-lithiation solution; and a charge and discharge unit connected to the negative electrode structure and the lithium metal counter electrode, in which a separation distance between the lithium metal counter electrode and the negative electrode structure is in a range of 7 to 15 mm. A method for pre-lithiating the negative electrode is also provided.

Abstract: A negative electrode for a lithium secondary battery, in which a LiF layer comprising amorphous LiF in an amount of 30 mol % or more is formed on a negative electrode active material layer comprising a carbon-based active material, a lithium secondary battery comprising the same, and a preparation method thereof.

Abstract: A negative electrode pre-lithiation method comprising the steps of: manufacturing a negative electrode by forming, on a negative electrode current collector, a negative electrode active material layer comprising a negative electrode active material. Then, manufacturing a pre-lithiation cell, which comprises the negative electrode and a lithium metal counter electrode, and impregnating the pre-lithiation cell with a pre-lithiation solution; and charging the pre-lithiation cell with a constant voltage to form a pre-lithiated negative electrode. The pre-lithiation solution comprises 3 vol % to 30 vol % of an organic carbonate compound substituted with halogen.

Abstract: An apparatus for pre-lithiating a negative electrode includes a pre-lithiation reactor having a pre-lithiation solution accommodated therein, a high-pressure chamber surrounding the pre-lithiation reactor, wherein an internal air pressure of the high-pressure chamber is configured to exceed atmospheric pressure, at least one lithium metal counter electrode disposed in the pre-lithiation solution, the lithium metal counter electrode being disposed to face a negative electrode receivable in the pre-lithiation solution in a state that the lithium metal counter electrode is spaced apart from the negative electrode by a predetermined interval, and a charge and discharge unit being connectable to the negative electrode and the lithium metal counter electrode to provide a circuit.