Abstract: Methods for forming a dual-phase magnetic component from an initial component comprising a non-magnetic austenite composition are provided. The method may include: forming a coating on a portion of the surface of the initial component to form a masked area while leaving an unmasked area thereon. Thereafter the initial component may be heated to a treatment temperature such that nitrogen diffuses out of the unmasked area of the initial component to transform the non-magnetic austenite composition to a magnetic phase in the unmasked area. Thereafter, the initial component may be cooled from the treatment temperature to form a dual-phase magnetic component having a magnetic region corresponding to the unmasked area and a non-magnetic region corresponding to the masked area.

Abstract: A nickel-based braze alloy composition is described, including nickel, about 1 weight % to about 5 weight % boron (B); and about 1 weight % to about 20 weight % germanium (Ge). The composition is free of any silicon. Superalloy articles that contains a crack or other type of void or gap filled with the nickel-based braze alloy composition are also described, along with methods for filling such a gap. Related articles of manufacture and brazing processes to join metal components are also disclosed.

Abstract: A nickel-based braze alloy composition includes nickel, about 1 weight % to about 5 weight % boron (B); and about 1 weight % to about 20 weight % germanium (Ge). The composition is free of any silicon. Superalloy articles having a crack or other type of void or gap may be filled with the nickel-based braze alloy composition. Methods for filling such a gap are described.

Abstract: A composition includes, by weight percent: Cobalt (Co) between about 4.5 and about 7.0; Chromium (Cr) between about 10.2 and about 11.5; Molybdenum (Mo) between about 0.5 and about 2.5; Tungsten (W) between about 4.0 and about 5.5; Rhenium (Re) between about 0 and about 1.2; Aluminum (Al) between about 6.2 and about 6.8; Tantalum (Ta) between about 4.5 and about 6.0; Titanium (Ti) between about 0 and about 0.5; Hafnium (Hf) between about 0 and about 0.5; Carbon (C) between about 0 and about 0.2; Boron (B) between about 0 and about 0.02; and the balance Nickel (Ni), and other incidental impurities.

Abstract: A dual phase magnetic component, along with methods of its formation, is provided. The dual phase magnetic component may include an intermixed first region and second region formed from a single material, with the first region having a magnetic area and a diffused metal therein, and with the second region having a non-magnetic area. The second region generally has greater than 0.1 weight % of nitrogen.

Abstract: A dual phase magnetic component, along with methods of its formation, is provided. The dual phase magnetic component may include an intermixed first region and second region formed from a single material, with the first region having a magnetic area and a diffused metal therein, and with the second region having a non-magnetic area. The second region generally has greater than 0.1 weight % of nitrogen.

Abstract: Methods for forming a dual-phase magnetic component from an initial component comprising a non-magnetic austenite composition are provided. The method may include: forming a coating on a portion of the surface of the initial component to form a masked area while leaving an unmasked area thereon. Thereafter the initial component may be heated to a treatment temperature such that nitrogen diffuses out of the unmasked area of the initial component to transform the non-magnetic austenite composition to a magnetic phase in the unmasked area. Thereafter, the initial component may be cooled from the treatment temperature to form a dual-phase magnetic component having a magnetic region corresponding to the unmasked area and a non-magnetic region corresponding to the masked area.

Abstract: A dual phase magnetic component, along with methods of its formation, is provided. The dual phase magnetic component may include an intermixed first region and second region formed from a single material, with the first region having a magnetic area and a diffused metal therein, and with the second region having a non-magnetic area. The second region generally has greater than 0.1 weight % of nitrogen.

Abstract: A composition includes, by weight percent: Cobalt (Co) between about 4.5 and about 7.0; Chromium (Cr) between about 10.2 and about 11.5; Molybdenum (Mo) between about 0.5 and about 2.5; Tungsten (W) between about 4.0 and about 5.5; Rhenium (Re) between about 0 and about 1.2; Aluminum (Al) between about 6.2 and about 6.8; Tantalum (Ta) between about 4.5 and about 6.0; Titanium (Ti) between about 0 and about 0.5; Hafnium (Hf) between about 0 and about 0.5; Carbon (C) between about 0 and about 0.2; Boron (B) between about 0 and about 0.02; and the balance Nickel (Ni), and other incidental impurities.

Abstract: A method of forming titanium-based spherical metallic particles includes performing a hydride-dehydride process on a meltless metallic sponge to form a feedstock material including a metallic powder. The method further includes introducing the feedstock material into a microwave plasma discharge to form the titanium-based spherical metallic particles.

Abstract: A method of forming titanium-based spherical metallic particles includes contacting a feedstock material including a metal halide with a reductant in the presence of a microwave plasma discharge.

Abstract: In some embodiments, a gamma titanium aluminide alloy consists essentially of, in atomic percent, 38 to about 50% aluminum, 1 to about 6% niobium, 0.25 to about 2% tungsten, 0.01 to about 1.5% boron, up to about 1% carbon, optionally up to about 2% chromium, optionally up to about 2% vanadium, up to about 2% manganese, and the balance titanium and incidental impurities. In some embodiments, the gamma titanium aluminide alloy forms at least a portion of a gas turbine component. In some embodiments, a gamma titanium aluminide alloy, consists essentially of, in atomic percent, about 40 to about 50% aluminum, about 1 to about 5% niobium, about 0.3 to about 1% tungsten, about 0.1 to about 0.3% boron, up to about 0.1% carbon, up to about 2% chromium, up to about 2% vanadium, up to about 2% manganese, up to about 1% molybdenum, and the balance titanium and incidental impurities.

Abstract: In some embodiments, a gamma titanium aluminide alloy consists essentially of, in atomic percent, about 38 to about 50% aluminum, about 6% niobium, about 0.25 to about 2% tungsten, optionally up to about 1.5% boron, about 0.01 to about 1.0% carbon, optionally up to about 2% chromium, optionally up to about 2% vanadium, optionally up to about 2% manganese, and the balance titanium and incidental impurities. In some embodiments, the gamma titanium aluminide alloy forms at least a portion of a gas turbine component. In some embodiments, a gamma titanium aluminide alloy, consisting essentially of, in atomic percent, about 40 to about 50% aluminum, about 3 to about 5% niobium, about 0.5 to about 1.5% tungsten, about 0.01 to about 1.5% boron, about 0.01 to about 1.0% carbon, optionally up to about 2% chromium, optionally up to about 2% vanadium, optionally up to about 2% manganese, and the balance titanium and incidental impurities.

Abstract: A nickel-based braze alloy composition is described, including nickel, about 1 weight % to about 5 weight % boron (B); and about 1 weight % to about 20 weight % germanium (Ge). The composition is free of any silicon. Superalloy articles that contains a crack or other type of void or gap filled with the nickel-based braze alloy composition are also described, along with methods for filling such a gap. Related articles of manufacture and brazing processes to join metal components are also disclosed.

Abstract: Articles suitable for use in high temperature applications, such as turbomachinery components, and methods for making such articles, are provided. One embodiment is an article. The article comprises a material comprising a plurality of L12-structured gamma-prime phase precipitates distributed within a matrix phase at a concentration of at least 20% by volume, wherein the gamma-prime phase precipitates are less than 1 micrometer in size, and a plurality of A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The solvus temperature of the eta phase is higher than the solvus temperature of the gamma-prime phase. Moreover, the material has a median grain size less than 10 micrometers.

Abstract: A composite composition that includes an MCrAlX alloy and a nano-oxide ceramic is disclosed. In the formula, M includes nickel, cobalt, iron, or a combination thereof, and X includes yttrium, hafnium, or a combination thereof, from about 0.001 percent to about 2 percent by weight of the alloy. The amount of the nano-oxide ceramic is greater than about 40 percent, by volume of the composition. A protective covering that includes the composite composition is also disclosed. The protective covering can be attached to a tip portion of a blade with a braze material. A method for joining a protective covering to a tip portion of a blade, and a method for repair of a blade, are also provided.

Abstract: Rhenium-free nickel based alloys are provided. More particularly, the alloys comprise preferred levels and ratios of elements so as to achieve good high temperature strength of both gamma matrix phase and gamma prime precipitates, as well as good environmental resistance, without using rhenium. When cast and directionally solidified into single crystal form, the alloys exhibit creep and oxidation resistance substantially equivalent to or better than rhenium-bearing single-crystal alloys. Further, the alloys can be processed by directional solidification into articles in single crystal form or columnar structure comprising fine dendrite arm spacing, e.g., less than 400 ?m, if need be, so that further improvements in mechanical properties in the articles can be seen.

Abstract: A composite composition that includes an MCrAlX alloy and a nano-oxide ceramic is disclosed. In the formula, M includes nickel, cobalt, iron, or a combination thereof, and X includes yttrium, hafnium, or a combination thereof, from about 0.001 percent to about 2 percent by weight of the alloy. The amount of the nano-oxide ceramic is greater than about 40 percent, by volume of the composition. A protective covering that includes the composite composition is also disclosed. The protective covering can be attached to a tip portion of a blade with a braze material. A method for joining a protective covering to a tip portion of a blade, and a method for repair of a blade, are also provided.

Abstract: Articles suitable for use in high temperature applications, such as turbomachinery components, and methods for making such articles, are provided. One embodiment is an article. The article comprises a material comprising a plurality of L12-structured gamma-prime phase precipitates distributed within a matrix phase at a concentration of at least 20% by volume, wherein the gamma-prime phase precipitates are less than 1 micrometer in size, and a plurality of A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The solvus temperature of the eta phase is higher than the solvus temperature of the gamma-prime phase. Moreover, the material has a median grain size less than 10 micrometers.

Abstract: Articles that include a material that has L12-structured gamma-prime phase precipitates within a matrix phase at a concentration of at least 20% by volume are disclosed. The gamma-prime phase precipitates are less than 1 micrometer in size. The material also has A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The articles may be formed by mechanically working a workpiece that has at least about 40% nickel, about 1.5% to about 8% titanium, and about 1.5% to about 4.5% aluminum. The workpiece may be worked at a temperature below a solvus temperature of the eta phase; and then heat treated at a temperature sufficient to dissolve any gamma prime phase present in the workpiece but below the solvus temperature of the eta phase.