Abstract: A method for producing organic liquid fuels and other valuable products in which an organic compound is provided to an anode electrode having a metal oxide catalyst disposed on an anode side of an electrolyte membrane, thereby producing an organic liquid fuel and/or other valuable organic product and electrons on the anode side. The electrons are conducted to a cathode electrode disposed on a cathode side of the electrolyte membrane, thereby transforming water provided to the cathode side to H2 gas and hydroxide ions. The method is carried out at a temperature less than or equal to about 160° C., preferably at room temperature.

Abstract: A method of converting methane to methanol at low temperatures utilizes a reactor including an anode, a cathode, a membrane separator between the anode and cathode, a metal oxide catalyst at the anode and a hydrogen recovery catalyst at the cathode. The method can convert methane to methanol at as rate exceeding the theoretical Faradaic rate due to the contribution of an electrochemical reaction occurring in tandem with a Faradaic reaction.

Abstract: A method and system for cooling an internal space are provided. A laminate of a hydrophobic membrane and a hydrophilic membrane includes a superabsorbent polymer disposed on or encompassing the hydrophilic membrane. The superabsorbent polymer increases the wicking capacity of the hydrophilic membrane so that water from a source is distributed more rapidly across the hydrophilic membrane. The distributed water is evaporated from the hydrophilic membrane, causing evaporative cooling of the laminate and surrounding air stream(s). The cooled air stream(s) are used to cool the internal space.

Abstract: Carbon monoxide and oxygen gas can be produced from carbon dioxide by introducing a supply of CO2-containing gas to a CO2 permeable porous media. The CO2 permeates through the media to separate the CO2 from other species in the CO2-containing gas supply. An oxygen-deficient ferrite material, disposed on a surface of the CO2 permeable porous media, contacts with the separated CO2 at decomposition reaction conditions to produce CO and O2. Corresponding devices for treating exhaust gases from a CO2 exhaust gas-producing apparatus are also provided.

Abstract: A method for producing methanol from methane in which methane is provided to an anode electrode having a metal oxide catalyst disposed on an anode side of an electrolyte membrane, thereby producing methanol and electrons on the anode side. The electrons are conducted to a cathode electrode such as having an oxygen reduction catalyst disposed on a cathode side of the electrolyte membrane, thereby transforming oxygen and water provided to the cathode side to hydroxide ions.

Abstract: An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

Abstract: An apparatus for dehumidifying gas is provided which converts humid gas into dehumidified gas using a hydrophilic membrane that includes a superabsorbent polymer. A sub-dew point cooling tower, sub-dew point evaporative cooler and sub-dew point water harvesting system which utilize the apparatus for dehumidifying gas are also provided.

Abstract: A method for producing methanol from methane in which methane is provided to an anode electrode having a metal oxide catalyst disposed on an anode side of an electrolyte membrane, thereby producing methanol and electrons on the anode side. The electrons are conducted to a cathode electrode disposed on a cathode side of the electrolyte membrane, thereby transforming water provided to the cathode side to H2 gas and hydroxide ions. The method is carried out at a temperature less than or equal to about 160° C., preferably at room temperature.

Abstract: A method and system for cooling an internal space are provided. A laminate of a hydrophobic membrane and a hydrophilic membrane includes a superabsorbent polymer disposed on or encompassing the hydrophilic membrane. The superabsorbent polymer increases the wicking capacity of the hydrophilic membrane so that water from a source is distributed more rapidly across the hydrophilic membrane. The distributed water is evaporated from the hydrophilic membrane, causing evaporative cooling of the laminate and surrounding air stream(s). The cooled air stream(s) are used to cool the internal space.

Abstract: An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

Abstract: A bipolar ion exchange membrane suitable for use in ZnBr batteries, LiBr batteries, and electrolyzers. The membrane is produced by hot pressing or extruding a mixture of an anion exchange ionomer powder, a cation exchange ionomer powder, and a non-porous polymer powder.

Abstract: An apparatus for dehumidifying gas is provided which converts humid gas into dehumidified gas using a hydrophilic membrane that includes a superabsorbent polymer. A sub-dew point cooling tower, sub-dew point evaporative cooler and sub-dew point water harvesting system which utilize the apparatus for dehumidifying gas are also provided.

Abstract: A method of improving the vertical wicking properties of an inert foam substrate used in air conditioning units includes the step of coating the inert foam substrate with a hydrophilic material. The hydrophilic material can be a zeolite, a superabsorbent polymer, or a composite or combination thereof. An inert foam laminate for vertical wicking of a liquid is also provided.

Abstract: A method of converting methane to methanol at low temperatures utilizes a reactor including an anode, a cathode, a membrane separator between the anode and cathode, a metal oxide catalyst at the anode and a hydrogen recovery catalyst at the cathode. The method can convert methane to methanol at as rate exceeding the theoretical Faradaic rate due to the contribution of an electrochemical reaction occurring in tandem with a Faradaic reaction.

Abstract: An electrochemical device having a liquid electrolyte which includes a protic solvent, an anode electrode disposed in contact with the liquid electrolyte, and a cathode electrode disposed in contact with the liquid electrolyte. A membrane which interrupts the transport of ions between the electrodes at a predetermined temperature is disposed in the liquid electrolyte between the anode electrode and the cathode electrode. In this way, electrochemical devices such as batteries, fuel cells, electrolyzers, and sensors, which may overheat during use and cause a fire or explosion, are precluded from overheating.

Abstract: A method and system for regenerating used cooking oil in which the used cooking oil is introduced into a cooking oil regenerator, which includes an electrochemical device having a high temperature proton exchange membrane disposed between an anode electrode and a cathode electrode. A voltage is applied between the anode electrode and the cathode electrode using an external electricity source, producing regenerated cooking oil.

Abstract: A method for producing organic liquid fuels and other valuable products in which an organic compound is provided to an anode electrode having a metal oxide catalyst disposed on an anode side of an electrolyte membrane, thereby producing an organic liquid fuel and/or other valuable organic product and electrons on the anode side. The electrons are conducted to a cathode electrode disposed on a cathode side of the electrolyte membrane, thereby transforming water provided to the cathode side to H2 gas and hydroxide ions. The method is carried out at a temperature less than or equal to about 160° C., preferably at room temperature.

Abstract: A method for producing methanol from methane in which methane is provided to an anode electrode having a metal oxide catalyst disposed on an anode side of an electrolyte membrane, thereby producing methanol and electrons on the anode side. The electrons are conducted to a cathode electrode disposed on a cathode side of the electrolyte membrane, thereby transforming water provided to the cathode side to H2 gas and hydroxide ions. The method is carried out at a temperature less than or equal to about 160° C., preferably at room temperature.

Abstract: An electrochemical device having a liquid electrolyte which includes a protic solvent, an anode electrode disposed in contact with the liquid electrolyte, and a cathode electrode disposed in contact with the liquid electrolyte. A membrane which interrupts the transport of ions between the electrodes at a predetermined temperature is disposed in the liquid electrolyte between the anode electrode and the cathode electrode. In this way, electrochemical devices such as batteries, fuel cells, electrolyzers, and sensors, which may overheat during use and cause a fire or explosion, are precluded from overheating.

Abstract: An electrochemical device having a liquid electrolyte which includes a protic solvent, an anode electrode disposed in contact with the liquid electrolyte, and a cathode electrode disposed in contact with the liquid electrolyte. A membrane which interrupts the transport of ions between the electrodes at a predetermined temperature is disposed in the liquid electrolyte between the anode electrode and the cathode electrode. In this way, electrochemical devices such as batteries, fuel cells, electrolyzers, and sensors, which may overheat during use and cause a fire or explosion, are precluded from overheating.