Abstract: An ethylene oxide (EO) production process comprising (a) introducing a first reactant mixture (C2H6, O2) to a first reactor to produce a first effluent stream (C2H4, C2H6, O2); (b) introducing a second reactant mixture to a second reactor to produce a second effluent stream (EO, C2H4, C2H6, O2); wherein the second reactant mixture comprises at least a portion of first effluent stream; (c) separating the second effluent stream into an EO product stream (EO) and recycle stream (C2H4, C2H6, O2); wherein ethylene is not separated from recycle stream and/or first effluent stream; and (d) recycling a first portion of recycle stream to the first reactor, and a second portion of recycle stream to the second reactor; wherein recycle split ratio <0.6; and wherein recycle split ratio is defined as ratio of volumetric flowrate of first portion of recycle stream divided by the sum of volumetric flowrates of first portion and second portion of recycle stream.

Abstract: An ethylene oxide (EO) production process comprising (a) introducing a first reactant mixture (C2H6, C2H4, O2) to a first reactor to produce a first effluent stream (C2H4, C2H6, O2), wherein the mole fraction of ethylene in first effluent stream is greater than in first reactant mixture; wherein the first reactant mixture is characterized by a molar ratio of ethylene to ethane of ?1.3; (b) introducing the first effluent stream to a second reactor to produce a second effluent stream (EO, C2H4, C2H6, O2); (c) separating the second effluent stream into an EO product stream (EO) and recycle stream (C2H4, C2H6, O2); wherein ethylene is not separated from recycle stream and/or first effluent stream; and (d) recycling at least a portion of recycle stream to the first reactor, and a portion of recycle stream to the second reactor.

Abstract: An ethylene oxide (EO) production process comprising (a) introducing a first reactant mixture (C2H6, C2H4, O2) to a first reactor system to produce a first effluent stream (C2H4, C2H6, O2), wherein the mole fraction of ethylene in first effluent stream is greater than in first reactant mixture; wherein the first reactor system is characterized by a first reactor system operating temperature of 270° C.-320° C.; wherein the first reactor system comprises oxidative dehydrogenation (ODH) stage(s); (b) introducing the first effluent stream to a second reactor to produce a second effluent stream (EO, C2H4, C2H6, O2); (c) separating the second effluent stream into an EO product stream (EO) and recycle stream (C2H4, C2H6, O2); wherein ethylene is not separated from recycle stream and/or first effluent stream; (d) recycling at least a portion of recycle stream to the first reactor system, and a optionally portion of recycle stream to the second reactor.

Abstract: A tubular reactor for producing a product mixture in a tubular reactor where the tubular reactor comprises an internal catalytic insert with cup-shaped structures having orifices for forming fluid jets for impinging the fluid on the tube wall. Jet impingement is used to improve heat transfer between the fluid in the tube and the tube wall in a non-adiabatic reactor. The tubular reactor and method may be used for endothermic reactions such as steam methane reforming and for exothermic reactions such as methanation.

Abstract: A tubular reactor and method for producing a product mixture in a tubular reactor where the tubular reactor comprises an internal catalytic insert having orifices for forming fluid jets for impinging the fluid on the tube wall. Jet impingement is used to improve heat transfer between the fluid in the tube and the tube wall in a non-adiabatic reactor. The tubular reactor and method may be used for endothermic reactions such as steam methane reforming and for exothermic reactions such as methanation.

Abstract: A tubular reactor for producing a product mixture in a tubular reactor where the tubular reactor comprises an internal catalytic insert with cup-shaped structures having orifices for forming fluid jets for impinging the fluid on the tube wall. Jet impingement is used to improve heat transfer between the fluid in the tube and the tube wall in a non-adiabatic reactor. The tubular reactor and method may be used for endothermic reactions such as steam methane reforming and for exothermic reactions such as methanation.

Abstract: A method and a reactor made by a method for increasing heat transfer from a heat source outside a vessel to the fluid inside the vessel are characterized by expanding a structure within the vessel toward the inner vessel surface so as to decrease the spacing between the structure and the vessel wall. The structure may be any of the various so-called structured packings, for example, ceramic honeycombs, metal honeycombs, plate stacks, and the like. The structure may comprise catalyst. The reactor provides high activity, low pressure drop, and high heat transfer. The reactor may be especially suitable for steam hydrocarbon reforming.

Abstract: A tubular reactor and method for producing a product mixture in a tubular reactor where the tubular reactor comprises an internal catalytic insert having orifices for forming fluid jets for impinging the fluid on the tube wall. Jet impingement is used to improve heat transfer between the fluid in the tube and the tube wall in a non-adiabatic reactor. The tubular reactor and method may be used for endothermic reactions such as steam methane reforming and for exothermic reactions such as methanation.

Abstract: A process for generating synthesis gas wherein a reactant gas mixture comprising steam and a light hydrocarbon is introduced into a tubular reactor comprising a catalyzed structured packing at higher inlet mass rates than conventional tubular reactors containing random packing catalyst pellets or catalyzed structure packing.

Abstract: A process for generating synthesis gas wherein a reactant gas mixture comprising steam and a light hydrocarbon is introduced into a tubular reactor comprising a catalyzed structured packing at higher inlet mass rates than conventional tubular reactors containing random packing catalyst pellets or catalyzed structure packing.

Abstract: A method and a reactor made by a method for increasing heat transfer from a heat source outside a vessel to the fluid inside the vessel are characterized by expanding a structure within the vessel toward the inner vessel surface so as to decrease the spacing between the structure and the vessel wall. The structure may be any of the various so-called structured packings, for example, ceramic honeycombs, metal honeycombs, plate stacks, and the like. The structure may comprise catalyst. The reactor provides high activity, low pressure drop, and high heat transfer. The reactor may be especially suitable for steam hydrocarbon reforming.

Abstract: A method for removal of pollutants from a pulping process byproduct liquor, the method comprising injecting an oxygen-containing gas into said liquor and condensing the water vapor from the stripping gas so as to produce a condensate comprising pollutants. Also a method of controlling the flow rate and/or temperature of a pulping process byproduct liquor, the process comprising injecting an oxygen-containing gas into the liquor in a reactor, processing the liquor in a flash tank so as to create a cooled liquor and combining at a least a portion of the cooled liquor with new liquor as the new liquor enters, or while the new liquor is in, the reactor.

Abstract: This invention relates to process for carrying out gas-liquid reactions such as those employed in the hydrogenation or oxidation of organic compounds. In the catalytic reaction of a liquid reactant and a gaseous reactant to form a product, the improvement which comprises: pressurizing a liquid reactant and, then, introducing the resultant pressurized liquid reactant to a liquid motive gas ejector wherein it is mixed with the gaseous reactant. The mixture is passed to and reacted in a monolith catalytic reactor. The products are removed from the monolith catalytic reactor at a reduced pressure and, then introduced to a tank. The unreacted materials in the reaction product then are recirculated back to the ejector.

Abstract: This invention relates to apparatus suited for gas-liquid reactions such as those employed in the hydrogenation or oxidation of organic compounds.

Abstract: This invention relates to an improvement in a process for hydrogenating a nitroaromatic composition namely dinitrotoluene by contacting the dinitrotoluene with hydrogen in a reactor employing a monolith catalyst system. Broadly the improvement resides in the continuous, essentially solventless, adiabatic hydrogenation of dinitrotoluene to toluenediamine in a plug flow reactor system incorporating the monolith catalyst. The process generally comprises the steps:introducing a feedstock comprised of dinitrotoluene and reaction product components continuously into the reactor and said feedstock having less that 30% by weight of a solvent,carrying out the hydrogenation of dinitrotoluene to toluenediamine under adiabatic conditions; and,continuously removing hydrogenated reaction product from the reactor.