Patents by Inventor Ronald L. Shubkin

Ronald L. Shubkin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7053036
    Abstract: Disclosed is a composition comprised of n-propyl bromide and 1,1,1,3,3-pentafluorobutane. This invention also relates to cleaning solvent systems comprised of n-propyl bromide and 1,1,1,3,3-pentafluorobutane and methods for cleaning various solid substrates.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: May 30, 2006
    Assignee: Poly Systems USA, Inc.
    Inventors: Richard J. DeGroot, Ronald L. Shubkin, Dov Shellef
  • Publication number: 20040087465
    Abstract: Disclosed is a composition comprised of n-propyl bromide and 1,1,1,3,3-pentafluorobutane. This invention also relates to cleaning solvent systems comprised of n-propyl bromide and 1,1,1,3,3-pentafluorobutane and methods for cleaning various solid substrates.
    Type: Application
    Filed: October 30, 2002
    Publication date: May 6, 2004
    Inventors: Richard J. DeGroot, Ronald L. Shubkin, Dov Shellef
  • Publication number: 20040087455
    Abstract: A solvent system for depositing a coating material onto a solid substrate surface, which solvent system is comprised of at least two organic solvents wherein at least one of the solvents has a substantially different vapor pressure that at least one other solvent in the solvent system. This invention also relates to a method for depositing thin films on substrate surfaces using a solvent system comprised of a blend of at least two organic solvents having substantially different vapor pressures. In a preferred embodiment the solvent system is comprised of effective amounts of n-propyl bromide and 1,1,1,3,3-pentafluorobutane.
    Type: Application
    Filed: October 30, 2002
    Publication date: May 6, 2004
    Inventors: Richard J. DeGroot, Ronald L. Shubkin, Dov Shellef
  • Publication number: 20020052305
    Abstract: When certain weight ratios of certain flammable additive components (an ether and an epoxyalkane) are blended in n-propyl bromide, the components can actually function as flame retardants or flame suppressants when the resulting cleaning composition is used in aerosol applications. The proportions of the additives used are small; yet suitably effective stabilization against metallic corrosion is achieved even at mildly elevated temperatures.
    Type: Application
    Filed: February 23, 2001
    Publication date: May 2, 2002
    Inventors: Ronald L. Shubkin, Eric W. Liimatta
  • Patent number: 6369017
    Abstract: When certain weight ratios of certain flammable additive components (an ether and an epoxyalkane) are blended in n-propyl bromide, the components can actually function as flame retardants or flame suppressants when the resulting cleaning composition is used in aerosol applications. The proportions of the additives used are small; yet suitably effective stabilization against metallic corrosion is achieved even at mildly elevated temperatures.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: April 9, 2002
    Assignee: Albemarle Corporation
    Inventors: Ronald L. Shubkin, Eric W. Liimatta
  • Patent number: 6258770
    Abstract: When certain weight ratios of certain flammable additive components (an ether and an epoxyalkane) are blended in n-propyl bromide, the components can actually function as flame retardants or flame suppressants when the resulting cleaning composition is used in aerosol applications. The proportions of the additives used are small; yet suitably effective stabilization against metallic corrosion is achieved even at mildly elevated temperatures.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: July 10, 2001
    Assignee: Albemarle Corporation
    Inventors: Ronald L. Shubkin, Eric W. Liimatta
  • Patent number: 6165284
    Abstract: Silver tarnishing is inhibited when using ether stabilized, n-propyl bromide based cleaning compositions by including a saturated aliphatic alcohol in the compositions.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: December 26, 2000
    Assignee: Albemarle Corporation
    Inventor: Ronald L. Shubkin
  • Patent number: 6133221
    Abstract: A cleaning process suitable for both mild and aggressive applications employs non-flammable, non-corrosive and environmentally friendly, fluorinated hydrobromocarbon solvent based cleaning compositions.
    Type: Grant
    Filed: January 13, 1999
    Date of Patent: October 17, 2000
    Assignee: Albemarle Corporation
    Inventors: Phillip R. Beaver, James E. Boone, Dixie E. Goins, Eric W. Liimatta, David L. Shelton, Ronald L. Shubkin
  • Patent number: 6114293
    Abstract: A process for cleaning movie film, and especially cellulose acetate based polymer film, without causing film damage, comprises immersing the film into a cleaning solvent composition which comprises one or more halogenated hydrobromocarbons having from 1 to 3 carbons, from 1 to 3 bromine atoms and at least one chlorine or fluorine atom, such as 3-bromo-1,1,1-trifluoropropane, removing the film from the solvent and drying the film.
    Type: Grant
    Filed: January 13, 1999
    Date of Patent: September 5, 2000
    Assignee: Albemarle Corporation
    Inventors: Phillip R. Beaver, James E. Boone, Dixie E. Goins, Eric W. Liimatta, David L. Shelton, Ronald L. Shubkin
  • Patent number: 5990071
    Abstract: Silver tarnishing is inhibited when using ether stabilized, n-propyl bromide based cleaning compositions by including a small amount of an acetylenic compound in the compositions.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: November 23, 1999
    Assignee: Albemarle Corporation
    Inventor: Ronald L. Shubkin
  • Patent number: 5945574
    Abstract: The use of novel heterogeneous catalyst complexes as catalysts for oligomerizing alpha-olefins is disclosed. The complexes are formed from (i) a solid olefin polymer having a linear backbone and a plurality of pendant omega-hydroxyalkyl groups, (ii) an organomagnesium halide, and (iii) a boron trihalide, preferably BF.sub.3. The complexes can be recovered and reused repeatedly in batch-type operations and can be used for long periods of time in continuous or semi-continuous operations without replenishment of their boron trifluoride content.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: August 31, 1999
    Assignee: BP Amoco Corporation
    Inventors: Tze-Chiang Chung, Ruidong Ding, Ronald L. Shubkin
  • Patent number: 5811617
    Abstract: Alpha-olefin oligomer is prepared by contacting an alpha-olefin monomer which contains from about 8 to about 16 carbon atoms with a heterogeneous catalyst system formed from (i) a solid olefin polymer having a linear backbone and a plurality of pendant omega-hydroxyalkyl groups, and (ii) a boron trihalide, preferably BF.sub.3. The catalyst system is stable and very reactive at relatively high temperatures, and the solid polymer of the catalyst system can be recovered and reused repeatedly in batch-type operations and can be used for long periods of time in continuous or semi-continuous operations.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: September 22, 1998
    Assignee: Amoco Corporation
    Inventors: Ronald L. Shubkin, Tze-Chiang Chung, Ruidong Ding
  • Patent number: 5792277
    Abstract: Stabilized, n-propyl bromide containing cleaning solvent compositions and a cleaning process are provided. The cleaning solvent compositions include an alcohol selected from 1-propanol and 2-butanol, including mixtures thereof, as a co-solvent so as to form azeotropic or azeotropic-like mixtures which have no fire or flash points.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: August 11, 1998
    Assignee: Albemarle Corporation
    Inventors: Ronald L. Shubkin, Eric W. Liimatta
  • Patent number: 5250750
    Abstract: Heat transfer, lubricating, functional and/or insulating fluid compositions for use in apparatus such as electrical transformers contain up to 25 weight percent of one or more oil additives and a 1-octene and/or 1-decene dimer and/or a 1-octene and 1-decene co-dimer oil having improved low temperature properties which oil contains less than about 2.5 weight percent of, respectively, the 7-methylpentadecene, 9-methylnonadecene and, 7- and 9-methylheptadecene isomers. The dimers can be hydrogenated to provide the saturated counterparts of the isomers.
    Type: Grant
    Filed: September 8, 1992
    Date of Patent: October 5, 1993
    Assignee: Ethyl Corporation
    Inventors: Ronald L. Shubkin, Kevin J. Theriot
  • Patent number: 5171905
    Abstract: A 1-octene and/or 1-decene dimer and/or 1-octene/1-decene co-dimer product composition having improved low temperature properties contains less than about 2.5 weight percent of, respectively, the 7-methylpentadecene, 9-methylnonadecene isomers, or 7- and 9-methylheptadecene isomers.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: December 15, 1992
    Assignee: Ethyl Corporation
    Inventors: Kevin J. Theriot, Ronald L. Shubkin
  • Patent number: 5171918
    Abstract: Heat transfer, lubricating, functional and/or insulating fluid compositions for use in apparatus such as electrical transformers contain up to 25 weight percent of one or more oil additives and a 1-octene and/or 1-decene dimer and/or a 1-octene and 1-decene co-dimer oil having improved low temperature properties which oil contains less than about 2.5 weight percent of, respectively, the 7-methylpentadecene, 9-methylnonadecene and, 7- and 9-methylheptadecene isomers. The dimers can be hydrogenated to provide the saturated counterparts of the isomers.
    Type: Grant
    Filed: May 28, 1991
    Date of Patent: December 15, 1992
    Assignee: Ethyl Corporation
    Inventors: Ronald L. Shubkin, Kevin J. Theriot
  • Patent number: 4910355
    Abstract: Olefin oligomers having a lower pour point are obtained by forming a mixture of C.sub.8-18 olefins containing 50-90 weight percent .alpha.-olefins and 10-50 weight percent internal olefins and oligomerizing this mixture using a Friedel Crafts catalyst (e.g. BF.sub.3) and a promoter (e.g. n-butanol). The mixture of olefins can be formed from .alpha.-olefins (e.g. 1-decene) by subjecting the .alpha.-olefins to isomerization until 10-50 weight percent of the olefins are internal olefins.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: March 20, 1990
    Assignee: Ethyl Corporation
    Inventors: Ronald L. Shubkin, Gerhard O. Kuehnhanss
  • Patent number: 4725681
    Abstract: An ethanolamine, preferably diethanolamine, is converted to triethylenediamine or 1,4-bis(2-hydroxyethyl)piperazine, or both by pyrolysis using a B-subgroup metal oxide such as titanium dioxide or zirconium dioxide, as catalyst. In addition it has also been discovered that 1,4-bis(2-hydroxyethyl)piperazine and N-(2-hydroxyethyl)piperazine can be converted in high yields and conversions into triethylenediamine by pyrolysis using the same type of catalyst. When using an ethanolamine as the feedstock and a Group IV-B metal oxide as the catalyst, the process usually results in the coproduction of triethylenediamine and 1,4-bis(2-hydroxyethyl)piperazine, and the latter can be recovered and used as a raw material for the production of additional triethylenediamine, as by recycle to the same reactor or as feedstock to an additional pyrolysis reactor.
    Type: Grant
    Filed: August 19, 1985
    Date of Patent: February 16, 1988
    Assignee: Ethyl Corporation
    Inventors: Ronald L. Shubkin, Duane C. Hargis
  • Patent number: 4724247
    Abstract: An aromatic diphosphite as a antioxidant for organic materials. The aromatic diphosphite has the formula: ##STR1## wherein each R is independently selected from the group consisting of hydrogen and methyl; and R.sup.1, R.sup.2 and R.sup.3 are each independently selected from the group consisting of hydrogen and straight chain and branched alkyl groups having from 1 to about 18 carbon atoms with the proviso that at least two of said R.sup.1, R.sup.2, and R.sup.3 are alkyl groups having at least three carbon atoms.
    Type: Grant
    Filed: July 18, 1986
    Date of Patent: February 9, 1988
    Assignee: Ethyl Corporation
    Inventors: Lester P. J. Burton, Kestutis A. Keblys, Ronald L. Shubkin
  • Patent number: 4532368
    Abstract: A process for making a mixture of meta- and para-alkylphenols by contacting a mixture of phenol, ortho-alkylphenol and an alkylating agent (e.g. olefins or lower alcohols) with a zeolite having a silica:alumina ratio of at least 12:1 under alkylating conditions to obtain a mixture of ortho-, meta- and para-alkylphenols and then separating at least part of the ortho-alkylphenol which is recycled to a subsequent alkylation process carried out in the same manner.
    Type: Grant
    Filed: February 1, 1984
    Date of Patent: July 30, 1985
    Assignee: Ethyl Corporation
    Inventors: Barry J. Swanson, Ronald L. Shubkin