Abstract: The present invention is an assembly layer for a flexible device. The assembly layer is derived from precursors that include about 0 to about 50 wt % C1-C9 alkyl(meth)acrylate, about 40 to about 99 wt % C10-C24 (meth)acrylate, about 0 to about 30 wt % hydroxyl(meth)acrylate, about 0 to about 10 wt % of a non-hydroxy functional polar monomer, and about 0 to about 5 wt % crosslinker.

Abstract: A core-sheath filament including a crosslinkable adhesive core that can be cured using ultraviolet or visible light radiation. These crosslinkable adhesive core compositions can provide very high bond strength and are capable of replacing traditional mechanical fasteners in many industrial applications. Core-sheath filaments including such crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions contain pendant aromatic ketone groups or pendant (meth)acryloyl groups that, upon exposure to ultraviolet radiation, result in the formation of crosslinks within the polymeric material. The crosslinked compositions can function as pressure-sensitive adhesives.

Abstract: A core-sheath filament having a non-tacky sheath and a hot-melt processable adhesive core, the sheath exhibiting a melt flow index of less than 15 grams per 10 minutes, is provided. Methods of making the core-sheath filament and methods of using the core-sheath filament to print a hot-melt processable adhesive onto a primer-treated substrate surface to provide a structural bond are described.

Abstract: A core-sheath filament having a pressure-sensitive adhesive core and a non-tacky thermoplastic sheath that surrounds the core is provided. The pressure-sensitive adhesive core includes a) a silicone-containing block copolymer having multiple poly-diorganosiloxane segments plus b) a silicone tackifying resin. Additionally, methods of making the core-sheath filament and methods of using the core-sheath filament to print a pressure-sensitive adhesive are described.

Abstract: A core-sheath filament having a) a core that is a thermally conductive pressure-sensitive adhesive particles and b) a non-tacky, thermoplastic sheath is provided. The thermally conductive pressure-sensitive adhesive in the core includes a (meth)acrylate-based polymeric material and thermally conductive particles. Additionally, methods of making the core-sheath filament and methods of using the core-sheath filament to print a thermally conductive pressure-sensitive adhesive are described.

Abstract: An adhesive article comprising first and second tacky latent adhesive layers disposed on respective first and second opposed major surfaces of a substrate. Each of the first and second tacky latent adhesive layers independently comprises at least one polymerizable component, and a redox initiator system comprising a transition metal complex that participates in a redox cycle, an oxidizing agent, and a blocked reducing agent represented by the formula ((I). Each of R1 and R2 are independently H, an alkyl, an aryl, or RPhoto5 with the proviso that at least one of R1 and R2 is RPhoto. RPhoto represents a photoremovable group. Each of R3 and R4 independently represents H, an alkyl group, or an aryl group comprising a monovalent ester, ether, urethane, or carbonate group. Methods of making and using the adhesive articles are also disclosed.

Abstract: The present invention is an assembly layer for a flexible device. Within a temperature range of between about ?30° C. to about 90° C., the assembly layer has a shear storage modulus at a frequency of 1 Hz that does not exceed about 2 MPa, a shear creep compliance (J) of at least about 6×10?6 1/Pa measured at 5 seconds with an applied shear stress between about 50 kPa and about 500 kPa, and a strain recovery of at least about 50% at at least one point of applied shear stress within the range of about 5 kPa to about 500 kPa within about 1 minute after removing the applied shear stress. The assembly layer includes at least one of a polyisoprene, a polybutadiene, an olefin block copolymer, a polyisobutylene, and high alkyl polyolefin.

Abstract: Crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions, which include two (meth)acrylate polymers, are used to form the crosslinked compositions upon exposure to ultraviolet radiation. The crosslinkable and crosslinked compositions are free or substantially free of tackifiers. The crosslinked compositions can function as pressure-sensitive adhesives. The crosslinkable compositions are well suited for use with hot melt processing methods.

Abstract: An adhesive article including: a flexible backing; a first cushion layer permanently bonded to a first surface of the flexible backing, wherein the first cushion layer: has an average thickness of at least 10 micrometers; and includes an acrylate pressure-sensitive adhesive having a Fox Tg of up to ?30° C., wherein the acrylate pressure-sensitive adhesive includes a (meth)acrylate copolymer; and a first continuous shell layer adjacent the first cushion layer, wherein: the first continuous shell layer has an average thickness of up to 25 micrometers; the ratio of the first cushion layer average thickness to the first shell layer average thickness is at least 2:1; the first continuous shell layer includes an adhesive having a Fox Tg of ?20° C. to +50° C.; and the first continuous shell layer adhesive includes a copolymer having a weight average molecular weight of at least 100,000 Daltons.

Abstract: An adhesive article comprising first and second tacky latent adhesive layers disposed on respective first and second opposed major surfaces of a substrate. Each of the first and second tacky latent adhesive layers independently comprises at least one polymerizable component, and a redox initiator system comprising a transition metal complex that participates in a redox cycle, an oxidizing agent, and a blocked reducing agent represented by the formula ((I). Each of R1 and R2 are independently H, an alkyl, an aryl, or RPhoto5 with the proviso that at least one of R1 and R2 is RPhoto. RPhoto represents a photoremovable group. Each of R3 and R4 independently represents H, an alkyl group, or an aryl group comprising a monovalent ester, ether, urethane, or carbonate group. Methods of making and using the adhesive articles are also disclosed.

Abstract: Modified adhesive layers are prepared by contacting an adhesive layer to a modified microstructured release liner. The modified release liner has a release layer surface with a set of microstructured depressions and a discontinuous pattern of ink material located on the surface of the release layer. A portion of the discontinuous pattern of ink material overlaps with and is located within some of the depressions. The ink material comprises a non-adhesive but adhesively transferrable material, or an adhesive material. Upon removal of the adhesive from the release liner, the ink material transfers to the adhesive surface.

Abstract: Curable adhesive compositions are provided that can be cured using ultraviolet or visible light radiation. These curable adhesive compositions, which contain a curable (meth)acrylate copolymer, have a creep compliance that is less than 5(10?4) inverse Pascals at 25° C., a creep compliance that is greater than 1(10?3) inverse Pascals at 70° C., and a shear storage modulus greater than 40 kiloPascals when measured at 25° C. at a frequency of 1 radian/second.

Abstract: Optically clear adhesive compositions contain an elastomeric polymer and a low molecular weight polymeric additive. The elastomeric polymer and the low molecular weight polymeric additive form an acid-base interaction. The refractive index of the adhesive composition is higher than the refractive index of the elastomeric polymer. The adhesive composition may also contain additional domains of liquids, polymers, additives or particles that have a higher refractive index than the elastomeric polymer.

Abstract: Curable adhesive compositions are provided that can be cured using ultraviolet or visible light radiation. These curable adhesive compositions, which contain a curable (meth)acrylate copolymer, have a creep compliance that is less than 5(10?4) inverse Pascals at 25° C., a creep compliance that is greater than 1(10?3) inverse Pascals at 70° C., and a shear storage modulus greater than 40 kiloPascals when measured at 25° C. at a frequency of 1 radian/second.

Abstract: An adhesive article including: a flexible backing; a first cushion layer permanently bonded to a first surface of the flexible backing, wherein the first cushion layer: has an average thickness of at least 10 micrometers; and includes an acrylate pressure-sensitive adhesive having a Fox Tg of up to ?30° C., wherein the acrylate pressure-sensitive adhesive includes a (meth)acrylate copolymer; and a first continuous shell layer adjacent the first cushion layer, wherein: the first continuous shell layer has an average thickness of up to 25 micrometers; the ratio of the first cushion layer average thickness to the first shell layer average thickness is at least 2:1; the first continuous shell layer includes an adhesive having a Fox Tg of ?20° C. to +50° C.; and the first continuous shell layer adhesive includes a copolymer having a weight average molecular weight of at least 100,000 Daltons.

Abstract: Polymerizable compositions comprising a redox initiator system is disclosed. The redox initiators comprises a photolabile reducing agent, that photolyzes and initiates the redox cycle. Dental compositions comprising dental resins and the photolabile redox initiator system are also described.

Abstract: The present invention is an assembly layer for a flexible device. Within a temperature range of between about ?30° C. to about 90° C., the assembly layer has a shear storage modulus at a frequency of 1 Hz that does not exceed about 2 MPa, a shear creep compliance (J) of at least about 6×10?6 1 /Pa measured at 5 seconds with an applied shear stress between about 50 kPa and about 500 kPa, and a strain recovery of at least about 50% at at least one point of applied shear stress within the range of about 5 kPa to about 500 kPa within about 1 minute after removing the applied shear stress. The assembly layer includes at least one of a polyisoprene, a polybutadiene, an olefin block copolymer, a polyisobutylene, and high alkyl polyolefin.

Abstract: Pressure-sensitive adhesive compositions are described comprising polymerized units of (meth)acrylate monomer. Also described are articles comprising such pressure-sensitive adhesive composition.

Abstract: An adhesive article including: a flexible backing; a first cushion layer permanently bonded to a first surface of the flexible backing, wherein the first cushion layer: has an average thickness of at least 10 micrometers; and includes an acrylate pressure-sensitive adhesive having a Fox Tg of up to ?30° C., wherein the acrylate pressure-sensitive adhesive includes a (meth)acrylate copolymer; and a first discontinuous shell layer adjacent the first cushion layer, wherein: the first discontinuous shell layer has an average thickness of up to 25 micrometers; the ratio of the first cushion layer average thickness to the first shell layer average thickness is at least 2:1; the first discontinuous shell layer includes an adhesive having a Fox Tg of +10° C. to +50° C.; and the first discontinuous shell layer adhesive includes a copolymer having a weight average molecular weight of at least 100,000 Daltons.

Abstract: Polymerizable compositions comprising a redox initiator system is disclosed. The redox initiator system comprises a photolabile transition metal complex that photolyzes and initiates the redox cycle. Dental compositions comprising dental resins and the photolabile redox initiator system are also described.