Abstract: Embodiments of this disclosure are directed to isohexide-dioxalates compounds of formula (I), and polymerization processes that utilize diols, oxalic acid, and compounds according to formula (I): Embodiments of this disclosure also include polyoxalates compounds of formula (II), polymerization processes for the production of polymers having a general structure according to formula (II):

Abstract: The present invention discloses a homogeneous, single site catalyst of formula (I) and a process for preparation thereof using a ligand. The present invention further discloses a process for preparation of linear polyethylene of high molecular weight and degree of crystallinity by using the homogeneous, single site catalyst of formula I.

Abstract: The present invention relates to isomerizing hydroformylation of plant oils to feedstock chemicals and monomers. More particularly, the present invention relates to compound of formula (I) and process for preparation thereof using isomerizing functionalization of cashew nut shell liquid (CNSL).

Abstract: The present invention provides highly efficient process for the preparation of enantiomerically enriched Sitagliptin of Formula (Ia). More particularly, a direct rhodium catalyzed asymmetric hydrogenation in the presence of bis-phosphine chiral ligand has been developed to yield enantiopure Sitagliptin product with the highest enantiomeric excess of 85-99.9%.

Abstract: The present invention disclosed a novel heterogeneous catalytic system (precatalyst), process for the preparation and use thereof for the synthesis of highly crystalline, disentangled ultra high molecular weight polyethylene (UHMWPE).

Abstract: The present invention discloses an isohexide-dioxalates compound of formula (I), a process for preparation and use thereof. The present invention further discloses a polyoxalates compound of formula (II), a process for preparation and use thereof.

Abstract: A one-step process for hydroformylation of olefins can include iron-catalyzed hydroformylation of olefins. The process can result in the conversion of olefin in the range of 40 to 99%. A reaction mixture includes iron precursor, ligand, substrate and solvent. The reaction mixture can be pressurized with syngas (CO/H2) under constant stirring to obtain a desired aldehyde compound. The ligand can be a monodentate ligand of a phosphines or a phosphite, and the iron precursor can be [HFe(CO)4]?.

Abstract: The present invention relates to a self assembled catalyst. More particularly, the present invention relates to a self-assembled catalyst of formula (I) comprising supramolecular phosphine and carboxylate ligands, process for preparation thereof and use of said catalyst of formula (I) in olefin polymerization.

Abstract: The present invention disclosed a novel heterogeneous catalytic system (precatalyst), process for the preparation and use thereof for the synthesis of highly crystalline, disentangled ultra high molecular weight polyethylene (UHMWPE).

Abstract: The present invention relates to isomerizing hydroformylation of plant oils to feedstock chemicals and monomers. More particularly, the present invention relates to compound of formula (I) and process for preparation thereof using isomerizing functionalization of cashew nut shell liquid (CNSL).

Abstract: The present invention relates to isomerizing hydroformylation of plant oils to feedstock chemicals and monomers. More particularly, the present invention relates to compound of formula (I) and process for preparation thereof using isomerizing functionalization of cashew nut shell liquid (CNSL).

Abstract: A one-step process for hydroformylation of olefins can include iron-catalyzed hydroformylation of olefins. The process can result in the conversion of olefin in the range of 40 to 99%. A reaction mixture includes iron precursor, ligand, substrate and solvent. The reaction mixture can be pressurized with syngas (CO/H2) under constant stirring to obtain a desired aldehyde compound. The ligand can be a monodentate ligand of a phosphines or a phosphite, and the iron precursor can be [HFe(CO)4]?.

Abstract: The present invention relates to novel polymerization catalysts. More particularly, the present invention relates to a novel catalysts for the preparation of ultra high molecular weight polyethylene (UHMWPE) and process for preparation thereof. The present invention further relates to a process for the preparation of disentangled ultra high molecular weight polyethylene (dis-UHM-WPE).

Abstract: The present invention relates to isomerizing hydroformylation of plant oils to feedstock chemicals and monomers. More particularly, the present invention relates to compound of formula (I) and process for preparation thereof using isomerizing functionalization of cashew nut shell liquid (CNSL).

Abstract: The present invention relates to a self assembled catalyst. More particularly, the present invention relates to a self-assembled catalyst of formula (I) comprising supramolecular phosphine and carboxylate ligands, process for preparation thereof and use of said catalyst of formula (I) in olefin polymerization.

Abstract: The present invention discloses nitrile ligated transition metal-phosphinobenzene-sulfonate complex of formula (I) as catalyst for insertion-copolymerization of mono and bis functionalized vinyl monomers with ethylene or other olefins. In particular, the present invention discloses nitrile ligated metal-phosphinobenzene-sulfonate complex of formula (I) as catalyst for insertion-copolymerization of mono and bis functionalized vinyl monomers with ethylene and or other olefins and to the process for preparation thereof. The invention further discloses a process for the insertion-(co)polymerization of mono and bis functionalized vinyl monomers with olefms catalyzed by the catalyst of formula (I).

Abstract: The present invention relates to novel polymerization catalysts. More particularly, the present invention relates to a novel catalysts for the preparation of ultra high molecular weight polyethylene (UHMWPE) and process for preparation thereof. The present invention further relates to a process for the preparation of disentangled ultra high molecular weight polyethylene (dis-UHMWPE).

Abstract: The present invention discloses nitrile ligated transition metal-phosphinobenzene-sulfonate complex of formula (I) as catalyst for insertion-copolymerization of mono and bis functionalized vinyl monomers with ethylene or other olefins. In particular, the present invention discloses nitrile ligated metal-phosphinobenzene-sulfonate complex of formula (I) as catalyst for insertion-copolymerization of mono and bis functionalized vinyl monomers with ethylene and or other olefins and to the process for preparation thereof. The invention further discloses a process for the insertion-(co)polymerization of mono and bis functionalized vinyl monomers with olefms catalyzed by the catalyst of formula (I).

Abstract: Potentially degradable isohexide based compounds and their polymers, derived from renewable resources, are described. Degradable isohexide-based monomers and polymers obtained from renewable resources are also described. Finally, processes for synthesizing such degradable polymers via copolymerization of the isohexide-based monomers and long chain diols are disclosed.

Abstract: The present invention discloses isohexide based compounds and their polymers which are derived from renewable resources and are potentially degradable. Also disclosed herein is the synthesis of isohexide based monomers and their polymers from renewable resources which are potentially degradable. Further, the present invention disclose a process for the synthesis of isohexide based copolymers via copolymerization of isohexide based monomers and long chain diols, which are degradable.