Abstract: A stackable unitized fuel cell system includes a cooling capability. A unitized fuel cell system includes a unitized fuel cell assembly having a first flow field plate, a second flow field plate, and a membrane electrode assembly (MEA) provided between the first and second flow field plates. In one configuration, a cooling structure is separable with respect to the unitized fuel cell assembly. In another configuration, the cooling structure is integral to the unitized fuel cell assembly. A retention arrangement is provided on one or both of the unitized fuel cell assembly and cooling structure. The retention arrangement is configured to facilitate mating engagement between the unitized fuel cell assembly, the cooling structure, and adjacent unitized fuel cell systems of a fuel cell stack.

Abstract: A method of forming a supported catalyst, the method comprising forming a colloidal suspension of platinum-iron catalyst nanoparticles in a solvent, depositing at least a portion of the catalyst nanoparticles onto support particles, and removing at least a portion of the iron from the deposited catalyst nanoparticles.

Abstract: Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1–C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6–C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.

Abstract: A unitized fuel cell assembly includes a first flow field plate, a second flow field plate, and a membrane electrode assembly (MEA) provided between the first and second flow field plates. A hard stop arrangement, in one configuration, is provided between the first and second flow field plates. The hard stop arrangement is dimensioned to limit compressive forces imparted to the MEA upon establishment of contact between the first and second flow field plates under pressure. A sealing arrangement is provided between the first and second flow field plates and peripheral to the MEA. The unitized fuel cell assembly is configured as a stand-alone fuel cell unit that can be used alone or in a stack of fuel cell units.

Abstract: Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.

Abstract: A stackable unitized fuel cell system includes a cooling capability. A unitized fuel cell system includes a unitized fuel cell assembly having a first flow field plate, a second flow field plate, and a membrane electrode assembly (MEA) provided between the first and second flow field plates. In one configuration, a cooling structure is separable with respect to the unitized fuel cell assembly. In another configuration, the cooling structure is integral to the unitized fuel cell assembly. A retention arrangement is provided on one or both of the unitized fuel cell assembly and cooling structure. The retention arrangement is configured to facilitate mating engagement between the unitized fuel cell assembly, the cooling structure, and adjacent unitized fuel cell systems of a fuel cell stack.

Abstract: A unitized fuel cell assembly includes a first flow field plate, a second flow field plate, and a membrane electrode assembly (MEA) provided between the first and second flow field plates. A hard stop arrangement, in one configuration, is provided between the first and second flow field plates. The hard stop arrangement is dimensioned to limit compressive forces imparted to the MEA upon establishment of contact between the first and second flow field plates under pressure. A sealing arrangement is provided between the first and second flow field plates and peripheral to the MEA. The unitized fuel cell assembly is configured as a stand-alone fuel cell unit that can be used alone or in a stack of fuel cell units.

Abstract: This invention relates to high molecular weight perfluorocyclobutane polymers and methods of polymerizing trifluorovinyl monomers to form high molecular weight perfluorocyclobutane polymers in the presence of a catalyst or initiator.

Abstract: Disclosed are sulfonated aromatic perfluorocyclobutane polymers meeting a condition selected from: a) the equivalent weight of the polymer is 5000 or less, and b) the proton conductivity of the polymer at 25° C. is 0.

Abstract: Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.

Abstract: The present invention provides a method of making 3-layer membrane electrode assemblies (MEAs) involving a direct transfer of the catalyst to the polymer electrolyte membrane as a decal in protonated form (acid form) at low temperature, particularly by use of a microstructured transfer medium or a flame-treated silicone-containing transfer medium.

Abstract: Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.

Abstract: This invention relates to high molecular weight perfluorocyclobutane polymers and methods of polymerizing trifluorovinyl monomers to form high molecular weight perfluorocyclobutane polymers in the presence of a catalyst or initiator.

Abstract: Hybrid membrane electrode assemblies (MEAs) are presented, having an anode comprising a dense distribution of catalyst that may be borne on small, high-aspect ratio supports, such as nanostructured elements, and a cathode comprising a less dense distribution of catalyst that may be borne on lower-aspect ratio supports, such as carbon particle supported catalyst.

Abstract: A method is provided for making crosslinked acidic polymers useful as ion conductive membranes, such as crosslinked sulfonated polyether ketones, sulfonated polysulfones, sulfonated polystyrenes, and other acidic polymers, by crosslinking with a species which generates an acidic functionality. The crosslinker preferably binds to acid functions by conversion of acid groups to imide functionality, which, due to the acidity of the N-H bonds therein, compensate for the acidity lost by the occupation of the acid groups and thus preserve membrane conductivity while contributing to membrane strength and resistance to swelling.