Patents by Inventor Shinji Ohtomo

Shinji Ohtomo has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11926779
    Abstract: A liquid crystal polyester comprising a repeating unit (A1) represented by the formula (A1) and a repeating unit (A2) represented by the formula (A2). A molar ratio (phenolic hydroxyl groups derived from the repeating unit (A2)/phenolic hydroxyl groups derived from the repeating unit (A1)) is 1 or lower, as calculated by 1H-NMR. A ratio [repeating unit (A2)/repeating unit (A1)] is 1.2 or larger. The number of the repeating unit (A1) is 20% or more and the number of the repeating unit (A2) is 58% or more based on 100% of a total number of all repeating units of the liquid crystal polyester. A flow starting temperature of the liquid crystal polyester is 250° C. or more. —O—Ar11—CO—??(A1) —O—Ar12—CO—??(A2) Ar11 represents a phenylene group and Ar12 represents a naphthylene group. A hydrogen atom is optionally substituted.
    Type: Grant
    Filed: March 9, 2023
    Date of Patent: March 12, 2024
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shinji Ohtomo, Shohei Azami, Monami Tosa, Nozomi Masui
  • Patent number: 11879041
    Abstract: Provided is a film including a thermoplastic resin, in which a relative permittivity of the film at a frequency of 1 GHz is 3 or less, a dielectric loss tangent of the film at a frequency of 1 GHz is 0.005 or less, and a molecular orientation (MOR) value of the film, which is measured by a microwave orientation meter, is in a range of 1 to 1.1.
    Type: Grant
    Filed: February 13, 2020
    Date of Patent: January 23, 2024
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shohei Azami, Shinji Ohtomo, Toyonari Ito
  • Patent number: 11773226
    Abstract: Provided is a film including a thermoplastic resin, in which a relative permittivity of the film at a frequency of 1 GHz is 3 or less, a dielectric loss tangent of the film at a frequency of 1 GHz is 0.005 or less, and a molecular orientation (MOR) value of the film, which is measured by a microwave orientation meter, is in a range of 1 to 1.1.
    Type: Grant
    Filed: February 13, 2020
    Date of Patent: October 3, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shohei Azami, Shinji Ohtomo, Toyonari Ito
  • Publication number: 20230295513
    Abstract: A liquid crystal polyester comprising a repeating unit (A1) represented by the formula (A1) and a repeating unit (A2) represented by the formula (A2). A molar ratio (phenolic hydroxyl groups derived from the repeating unit (A2)/phenolic hydroxyl groups derived from the repeating unit (A1)) is 1 or lower, as calculated by 1H-NMR. A ratio [repeating unit (A2)/repeating unit (A1)] is 1.2 or larger. The number of the repeating unit (A1) is 20% or more and the number of the repeating unit (A2) is 58% or more based on 100% of a total number of all repeating units of the liquid crystal polyester. A flow starting temperature of the liquid crystal polyester is 250° C. or more. —O—Ar11—CO—??(A1) —O—Ar12—CO—??(A2) Ar11 represents a phenylene group and Ar12 represents a naphthylene group. A hydrogen atom is optionally substituted.
    Type: Application
    Filed: March 9, 2023
    Publication date: September 21, 2023
    Inventors: Shinji OHTOMO, Shohei AZAMI, Monami TOSA, Nozomi MASUI
  • Publication number: 20230295512
    Abstract: A liquid crystal polyester comprising a repeating unit derived from an aromatic hydroxycarboxylic acid. The content of the repeating unit derived from an aromatic hydroxycarboxylic acid is 80% or more based on 100% of a total number of all repeating units of the liquid crystal polyester. The repeating unit derived from an aromatic hydroxycarboxylic acid comprises a repeating unit (A1) represented by the formula (A1) and a repeating unit (A2) represented by the formula (A2). A ratio [repeating unit (A2)/repeating unit (A1)] is 1.2 or larger. A molar ratio [phenolic hydroxyl groups/(the phenolic hydroxyl groups+acyl groups)] is 0.3 or lower, as calculated by 1H-NMR. —O—Ar11—CO—??(A1) —O—Ar12—CO—??(A1) Ar11 represents a phenylene group and Ar12 represents a naphthylene group. A hydrogen atom is optionally substituted.
    Type: Application
    Filed: March 9, 2023
    Publication date: September 21, 2023
    Inventors: Shinji OHTOMO, Shohei AZAMI, Monami TOSA, Nozomi MASUI
  • Publication number: 20230257911
    Abstract: Provided is a liquid crystal polyester fiber comprising a liquid crystal polyester, wherein a maximum value of a crystallite size of 20×10?10 m or larger. The maximum value is obtained by D=K·?/? cos ? (wherein D represents a crystallite size, ? represents a wavelength of the measurement X-ray, ? represents a half-value width (radian), ? represents a diffraction angle, and K represents a Scherrer constant (0.9)) based on a diffraction peak on a 110 plane of an X-ray diffraction spectrum measured by a wide angle X-ray diffraction method using X-ray having a wavelength of 1×10?10 m.
    Type: Application
    Filed: June 15, 2021
    Publication date: August 17, 2023
    Inventors: Shinji OHTOMO, Toshihiko NISHIDA
  • Publication number: 20230069551
    Abstract: What is provided is a method for producing a liquid crystalline polyester, the method including reacting an aromatic diol (A), an aromatic hydroxycarboxylic acid (B), and a naphthalenedicarboxylic acid (C) to obtain a liquid crystalline polyester, in which the naphthalenedicarboxylic acid (C) is a naphthalenedicarboxylic acid powder including 90% by mass or more of naphthalenedicarboxylic acid particles (C1) having a particle size of less than 150 ?m as measured by the dry sieving test method of JIS K 0069 (1992).
    Type: Application
    Filed: December 8, 2020
    Publication date: March 2, 2023
    Inventors: Shinji OHTOMO, Hiromi YAMANISHI
  • Publication number: 20220153937
    Abstract: Provided is a film including a thermoplastic resin, in which a relative permittivity of the film at a frequency of 1 GHz is 3 or less, a dielectric loss tangent of the film at a frequency of 1 GHz is 0.005 or less, and a molecular orientation (MOR) value of the film, which is measured by a microwave orientation meter, is in a range of 1 to 1.1.
    Type: Application
    Filed: February 13, 2020
    Publication date: May 19, 2022
    Inventors: Shohei AZAMI, Shinji OHTOMO, Toyonari ITO
  • Publication number: 20220089899
    Abstract: Provided is a liquid crystal polyester powder including a liquid crystal polyester having a number average molecular weight of 10000 or less, in which an average particle diameter of the liquid crystal polyester powder is 0.5 to 20 ?m.
    Type: Application
    Filed: February 13, 2020
    Publication date: March 24, 2022
    Inventors: Shohei AZAMI, Shinji OHTOMO, Toyonari ITO
  • Patent number: 11230628
    Abstract: A resin microparticle production method includes a step of pulverizing resin particles having a thermoplastic resin as a forming material and having a BET specific surface area of equal to or more than 5 m2/g using an impact type pulverizer.
    Type: Grant
    Filed: December 25, 2017
    Date of Patent: January 25, 2022
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Gouda, Toshiaki Sugimura, Shinji Ohtomo
  • Publication number: 20210355317
    Abstract: An aromatic polyester having a repeating unit represented by formula (1) shown below and a terminal structural unit represented by formula (1e) shown below, wherein the proportion of the terminal structural unit per unit mass of the aromatic polyester is not more than 50 ?mol/g. —O—Ar1—CO—??(1) —O—Ar1—CO—OH??(1e) (In the formulas, Ar1 represents a 1,4-phenylene group, a 2,6-naphthylene group or a 4,4?-biphenylylene group. The hydrogen atoms that exist in the groups represented by Ar1 may each be independently substituted with a halogen atom, an alkyl group or an aryl group.
    Type: Application
    Filed: November 18, 2019
    Publication date: November 18, 2021
    Inventor: Shinji OHTOMO
  • Patent number: 10927225
    Abstract: Aromatic polyether microparticles contain a plurality of particles containing an aromatic polyether in which a content of the particles having a particle diameter equal to or smaller than 50 ?m to a total volume of the aromatic polyether microparticles is equal to or higher than 50% by volume. The aromatic polyether microparticles contain phenolic hydroxyl groups in a content equal to or greater than 80 ?mol/g.
    Type: Grant
    Filed: September 14, 2017
    Date of Patent: February 23, 2021
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shinji Ohtomo, Yoshio Shoda
  • Publication number: 20210024687
    Abstract: An aromatic liquid crystal polyester containing repeating structural units represented by formulas (A1), (B), (C) and (D) shown below. —O—Ar1—CO—??(A1) —CO—Ar2—CO—??(B) —O—Ar3—O—??(C) —O—Ar4—O—??(D) (In the formulas, Ar1 represents a 2,6-naphthalene group, Art represents at least one group selected from the group consisting of a 2,6-naphthalenediyl group, 1,4-phe vlene group, 1,3-phenvIene group and 4,4?-biphenylene group, Ar3 represents at least one group selected from the group consisting of a 2, mphthalenediyl group, 1,6-naphthalenediyl group and 1,5-naphthalenediyl group, Ar4 represents at least one group selected from the group consisting of a 2,6-naphthalenediyl group, 1,4-phenylene group, 1,3-phenylene group and 4,4?-hiphenylene group, and each of the groups represented by Ar1, Ar3 or Ar4 may have a halogen atom, an alkyl group of 1 to 10 carbon atoms Of alt aryl group of 6 to 20 carbon atoms as a substituent.
    Type: Application
    Filed: March 25, 2019
    Publication date: January 28, 2021
    Inventors: Shinji OHTOMO, Masanobu MATSUBARA
  • Patent number: 10899888
    Abstract: A thermoplastic aromatic polysulfone is obtained by polymerizing a dihalogeno compound (A) and a dihydric phenol (B). The ratio (Mw/Mn) between a number average molecular weight (Mn) and a weight average molecular weight (Mw) is at least 1.91, and the number average molecular weight (Mn) is at least 6,000 and less than 14,000, In (A) and (B), each of X and X? independently represents a halogen atom; each of R1, R2, R3 and R4 independently represents an alkyl group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms; each of n1, n2, n3 and n4 independently represents an integer of 0 to 4; and when n1, n2, n3 or n4 is an integer of 2 to 4, a plurality of R1, R2, R3 or R4 groups may be the same or different from each other.
    Type: Grant
    Filed: February 2, 2017
    Date of Patent: January 26, 2021
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shinji Ohtomo, Masanobu Matsubara
  • Patent number: 10870755
    Abstract: The present invention relates to a method for producing thermoplastic aromatic polysulfone resin, in which a polymerization reaction is performed in an organic solvent by using compound (A), a dihalogeno compound represented by Formula (I), compound (B), a divalent phenol represented by Formula (II), and compound (C), an alkali metal carbonate, at a charging molar ratio satisfying the following Formulae (1) to (3): (1) 0.900<(A)/(B)<0.990; (2) {(A)/(B)}?0.02<(C)/(B)<{(A)/(B)}+0.01; and (3) (C)/(B)<1.00, In Formulae (I) and (II), R1 to R4 represent an alkyl group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms, X and X? represent a halogen atom, Y represents one or more groups selected from the group consisting of —SO2—, —C(CH3)2—, —CH2—, —O— and —CO—, or a single bond, and n1, n2, n3 and n4 represent an integer of 0 to 4.
    Type: Grant
    Filed: September 14, 2016
    Date of Patent: December 22, 2020
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Tomokazu Yasunaga, Shinji Ohtomo, Toshiaki Sugimura
  • Patent number: 10851207
    Abstract: A thermoplastic aromatic polysulfone is obtained by polymerizing a dihalogeno compound (A) and a dihydric phenol (B). The ratio (Mw/Mn) between a number average molecular weight (Mn) and a weight average molecular weight (Mw) is at least 1.80 and less than 1.90, and the number average molecular weight (Mn) is at least 6,000 and less than 14,000. In (A) and (B), each of X and X? independently represents a halogen atom; each of R1, R2, R3 and R4 independently represents an alkyl group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms; each of n1, n2, n3 and n4 independently represents an integer of 0 to 4; and when n1, n2, n3 or n4 is an integer of 2 to 4, a plurality of R1, R2, R3 or R4 groups may be the same or different from each other.
    Type: Grant
    Filed: February 2, 2017
    Date of Patent: December 1, 2020
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shinji Ohtomo, Masanobu Matsubara
  • Publication number: 20190345295
    Abstract: A resin microparticle production method includes a step of pulverizing resin particles having a thermoplastic resin as a forming material and having a BET specific surface area of equal to or more than 5 m2/g using an impact type pulverizer
    Type: Application
    Filed: December 25, 2017
    Publication date: November 14, 2019
    Inventors: Kenji GOUDA, Toshiaki SUGIMURA, Shinji OHTOMO
  • Publication number: 20190270855
    Abstract: Aromatic polyether microparticles contain a plurality of particles containing an aromatic polyether in which a content of the particles having a particle diameter equal to or smaller than 50 ?m to a total volume of the aromatic polyether microparticles is equal to or higher than 50% by volume. The aromatic polyether microparticles contain phenolic hydroxyl groups in a content equal to or greater than 80 ?mol/g.
    Type: Application
    Filed: September 14, 2017
    Publication date: September 5, 2019
    Inventors: Shinji OHTOMO, Yoshio SHODA
  • Patent number: 10400069
    Abstract: An aromatic polysulfone produced by polymerizing a dihalogeno compound represented by general formula (A) shown below, and a dihydric phenol represented by general formula (B) shown below, the aromatic polysulfone having a value (Mw/Mn) for the ratio between the weight average molecular weight (Mw) and the number average molecular weight (Mn) of less than 1.8, and having a number average molecular weight (Mn) of at least 6,000 but less than 14,000. (In the formula, each of X and X? independently represents a halogen atom; each of R1, R2, R3 and R4 independently represents an alkyl group having a carbon number of 1 to 4 or an alkoxy group having a carbon number of 1 to 4; each of n1, n2, n3 and n4 independently represents an integer of 0 to 4; and when n1, n2, n3 or n4 is an integer of 2 to 4, the plurality of R1, R2, R3 or R4 groups may be the same as, or different from, each other).
    Type: Grant
    Filed: March 15, 2016
    Date of Patent: September 3, 2019
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Shinji Ohtomo, Masanobu Matsubara
  • Publication number: 20190071542
    Abstract: A thermoplastic aromatic polysulfone is obtained by polymerizing a dihalogeno compound (A) and a dihydric phenol (B). The ratio (Mw/Mn) between a number average molecular weight (Mn) and a weight average molecular weight (Mw) is at least 1.91, and the number average molecular weight (Mn) is at least 6,000 and less than 14,000, In (A) and (B), each of X and X? independently represents a halogen atom; each of R1, R2, R3 and R4 independently represents an alkyl group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms; each of n1, n2, n3 and n4 independently represents an integer of 0 to 4; and when n1, n2, n3 or n4 is an integer of 2 to 4, a plurality of R1, R2, R3 or R4 groups may be the same or different from each other.
    Type: Application
    Filed: February 2, 2017
    Publication date: March 7, 2019
    Inventors: Shinji OHTOMO, Masanobu MATSUBARA