Abstract: The invention pertains to a method for manufacturing a three-dimensional object with an additive manufacturing system, such as an extrusion-based additive manufacturing system, a selective laser sintering system, and/or an electrophotography-based additive manufacturing system, comprising providing a support material comprising more than 50% wt. of a semi-crystalline polyamide [polyamide (A)] having a melting point, as determined according to ASTM D3418, of at least 250° C. and possessing a water absorption at saturation, by immersion in water at 23° C., of at least 2% wt.

Abstract: A process for preparing particles of polyphenylene sulfide polymer (PPS), based on the use of a polyester polymer (PE) comprising units from a dicarboxylic acid component and a diol component, wherein at least 2 mol. % of the diol component is a poly(alkylene glycol). The process comprises the melt-blending of the PPS with the PE, the cooling the blend and the recovery of the particles by dissolution of the PE into water. The present invention relates to PPS particles obtained therefrom and to the use of these particles in SLS 3D printing, coatings and toughening of thermoset resins.

Abstract: The present invention relates to a process for manufacturing a three-dimensional (3D) article, part or composite material, from a powdered material (M) comprising a polyamide (PA) presenting 4,4?-diaminodicyclohexylmethane moieties, as well as to such powdered material (M). The present invention also relates to the 3D article, part or composite material obtainable from such process, as well as the use of the article, part or composite materials in oil and gas applications, automotive applications, electric and electronic applications, aerospace, medical and consumer goods.

Abstract: The present invention relates to functionalized poly(aryl ether sulfones) polymers. The invention further relates to polymer compositions including the functionalized poly(aryl ether sulfone) polymers. Still further, the invention relates to lithographic methods to form three-dimensional (3D) objects that incorporate the aforementioned polymer compositions.

Abstract: Described here are blocky PEEK copolymers and corresponding synthesis methods. It was surprisingly found that synthesis of blocky PEEK copolymers in a non-solvent environment with respect to PEEK produced blocky PEEK copolymers with high degrees of functionalization and crystallinity. The blocky PEEK copolymers had an increased blocky structure, relative to corresponding PEEK copolymer synthesized with other known methods. Moreover, membranes formed from the blocky PEEK polymers are particularly desirable in fuel cell applications. For example, the membranes formed from the blocky PEEK polymers had surprisingly large ion conductivities as well as significantly improved chemical and thermal resistance, at least in part, to the improved functionalization and crystallinity.

Abstract: The present invention relates to a process for preparing fine particles of an aromatic copolyester, the process comprising the melt-blending of the aromatic copolyester with a polyester polymer (PE), the cooling the blend and the recovery of the particles by dissolution of the PE into water. The present invention also relates to aromatic copolyester particles obtained therefrom and to the use of these particles in to make coatings or films.

Abstract: Described herein are polymer compositions (PC) including a polyamide (PA) and a poly(arylene sulfide) (PASP). The polyamide (PA) is a semi-aromatic polyamide derived from the polycondensation of an aliphatic diamine, a bis(aminoalkyl)cyclohexane, terephthalic acid, and, optionally, a cyclohexanedicarboxylic acid. It was surprisingly discovered that semi-aromatic polyamides derived from the cycloaliphatic diamine bis(aminoalkyl)cyclohexane or the specific combination of the cycloaliphatic diamine bis(aminoalkyl)cyclohexane and the cycloaliphatic dicarboxylic acid cyclohexanedicarboxylic acid provided for polymer compositions (PC) having improved retention of mechanical properties (e.g. tensile modulus and tensile strength) after aging in aqueous polyol solutions. It was also surprisingly discovered that incorporation of a nucleating agent in the polymer composition (PC) provided for significantly improved tensile strength retention after aging.

Abstract: The present invention relates to a polymer composition (C) comprising at least one polyamide (P1), and from 1 to 50 wt. %, based on the total weight of (C), of at least one functionalized polymer (P2), wherein P2 is a poly(aryl ether sulfone) (PAES) having at least one functional group (SO3?), (Mp+)1/p in which Mp+ is a metal cation of p valence. The present invention also relates to articles incorporating the polymer composition (C) and the use of functionalized polymer (P2) as a compatibilizer in the polymer composition (C) comprising two immiscible polymers.

Abstract: A polymer composition includes a poly(para-phenylene sulfide) (PPS), at least one poly(aryl ether sulfone) (PAES), and at least one alkali metal carbonate. Preferably, the polymer composition is free or substantially free of solvent. A method includes melt mixing a poly(para-phenylene sulfide) (PPS), at least one poly(aryl ether sulfone) (PAES), and at least one alkali metal carbonate.

Abstract: Described herein are polymer compositions (PC) including a polyamide (PA) and a reactive impact modifier. As explained in detail below, the polyamide (PA) is a semi-aromatic polyamide derived from the polycondensation of an aliphatic diamine, a bis(aminoalkyl)cyclohexane, terephthalic acid, and, optionally, a cyclohexanedicarboxylic acid. It was surprisingly discovered that semi-aromatic polyamides derived from the cycloaliphatic diamine bis(aminoalkyl)cyclohexane or the specific combination of the cycloaliphatic diamine bis(aminoalkyl)cyclohexane and the cycloaliphatic dicarboxylic acid cyclohexanedicarboxylic acid provided for polymer compositions (PC) having improved retention of mechanical properties (e.g. tensile strength and flexural strength) after aging in aqueous solutions, relative to analogous polyamides free of the bis(aminoalkyl)cyclohexane and the cyclohexanedicarboxylic acid.

Abstract: The invention relates to a process for preparing polymeric particles, based on the use of a polyester polymer (PE) comprising units from a dicarboxylic acid component and a diol component, wherein at least 2 mol. % of the diol component is a poly(alkylene glycol). The process comprises the melt-blending of the aromatic polymer (P) with the PE, the cooling the blend and the recovery of the particles by dissolution of the PE into water. The present invention relates to polymeric particles obtained therefrom and to the use of these particles in SLS 3D printing, coatings and toughening of thermoset resins.

Abstract: Described herein are electrical articles comprising a polyamide (PA). As explained in detail below, the polyamide (PA) is a semi-aromatic polyamide derived from the polycondensation of an aliphatic diamine, terephthalic acid, and a bis(aminoalkyl)cyclohexane or a cyclohexanedicarboxylic acid. It was surprisingly discovered that incorporation of the cycloaliphatic diamine bis(aminoalkyl)cyclohexane or the cycloaliphatic dicarboxylic acid cyclohexanedicarboxylic acid into the polyamide provided for polymer compositions (PC) having significantly improved comparative tracking index (“CTI”) retention after heat aging, relative to analogous polyamides derived from only the aliphatic diamine and terephthalic acid. Due at least in part to the improved CTI retention, the polyamides (PA) can be desirably incorporated into articles that, during use, are exposed to elevated temperatures and benefit from high CTI performance.

Abstract: The present invention relates to a poly(arylene sulfide) (PAS) copolymer (P) comprising: at least one block of poly(arylene sulfide) (PAS) having a weight-average molecular weight (Mw) of at least 40,000 g/mol as determined by gel permeation chromatography, and at least one block of polyorganosiloxane (POS) having a weight-average molecular weight (Mw) of at most 5,000 g/mol as determined by gel permeation chromatography, wherein the weight ratio of PAS:POS is from 95:5 to 99.5:0.5.

Abstract: A method for manufacturing a three-dimensional (3D) object with an additive manufacturing system, comprising a step consisting in printing layers of the 3D object from the part material comprising a polymeric component comprising, based on the total weight of the polymeric component: from 5 to 95 wt. % of at least one polymer (P1) comprising at least 50 mol. % of recurring units (R1) consisting of an arylene group comprising at least one benzene ring, each recurring unit (R1) being bound to each other through C—C bonds, wherein the recurring units (R1) are such that, based on the total number of moles of recurring units (R1):less than 90 mol. % are rigid rod-forming arylene units (R1-a), and at least 10 mol. % are kink-forming arylene units (R1-b), and from 5 to 95 wt. % of at least one polymer (P2), having a glass transition temperature (Tg) between 140° C. and 265° C., and no melting peak, as measured by differential scanning calorimetry (DSC) according to ASTM D3418.

Abstract: The present invention relates to a powdered material (M) containing at least one poly(arylene sulfide) (PAS) polymer, comprising recurring units p, q and r according of formula (I), (II) and (III): wherein np, nq and nr are respectively the mole % of each recurring units p, q and r; recurring units p, q and r are arranged in blocks, in alternation or randomly; 1%?(nq+nr)/(np+nq+nr)?12%; nq is ?0% and nr is ?0%; j is zero or an integer varying between 1 and 4; R1 is selected from the group consisting of halogen atoms, C1-C12 alkyl groups, C7-C24 alkylaryl groups, C7-C24 aralkyl groups, C6-C24 arylene groups, C1-C12 alkoxy groups, and C6-C18 aryloxy groups.

Abstract: Methods of cross-linking or chain extending a polymeric material including a silane-modified poly(arylene ether) polymer (Si-PAE) in a shaped article include heating the shaped article from a temperature T1 to a temperature T2>T1, while maintaining the temperature at which the shaped article is heated within a specified range based on the increasing Tg of the polymeric material during the heating. Shaped articles cross-linked or chain extended by the methods are also described.

Abstract: Poly(aryl ether sulfones) (PAES) polymers (P1) which are functionalized with reactive functional groups on at least one end of the PAES polymer, a process for preparing the PAES polymers (P1), a process for preparing block copolymers (P2) using the functionalized poly(aryl ether sulfones) (PAES) polymers (P1) and the block copolymers (P2) obtainable by such process

Abstract: The present invention relates to poly(aryl ether) polymers which can for example be used in lithographic processes for the photofabrication of three-dimensional (3D) articles. The invention further relates to compositions including these poly(aryl ether) polymers. Still further, the invention relates to lithographic methods to form 3D articles or objects that incorporate the aforementioned polymer compositions.

Abstract: The present invention relates to polyetherimide polymers which can for example be used in lithographic processes for the photofabrication of three-dimensional (3D) articles. The invention further relates to compositions including these polyetherimide polymers. Still further, the invention relates to lithographic methods to form 3D articles or objects that incorporate the aforementioned polymer compositions.

Abstract: Described herein are poly(arylene sulfide) (“PAS”) polymers (PASP) including recurring units formed from selected dihalofluorene monomers. Surprisingly, at relative low dihalofluorene monomer concentrations, the PAS polymers (PASP) have significantly increased glass transition temperatures (“Tg”) and impact performance, relative to analogous PAS homopolymers and PAS polymers (PASP) including recurring units formed from 4,4?-dibromobiphenyl (“DBBP”). Simultaneously, the PAS polymers (PASP) also retain high elastic modulus. Furthermore, the PAS polymers (PASP) are free of recurring units formed from polyhalogenated biphenyls (e.g. DBBP and polychlorinated biphenyls) and, therefore, are not currently subject to restrictive governmental regulation.