Abstract: The object of the present invention is to provide a decorative film excellent in moldability and tensile strength; and a method for producing a three-dimensionally molded article with a decorative film. The decorative film of the present invention is used for decorating a three-dimensionally molded article. It is a decorative film comprising at least a substrate film layer and a clear layer, wherein the clear layer is made of a fluorinated polymer comprising units based on a fluoroolefin, units based on a monomer having no crosslinkable group, which is at least one member selected from the group consisting of a vinyl ether, a vinyl ester, an allyl ether, an allyl ester and a (meth)acrylic acid ester, and units having a crosslinkable group; and the content of the units based on a fluoroolefin is from 20 to 70 mol % to all units which the fluorinated polymer comprises.

Abstract: To provide a fluorinated coating material capable of forming a coating film excellent in water repellency and substrate adhesion. Further, to provide a method for producing the coating material, a coated article and its production method. A fluorinated coating material comprising a fluorinated polymer having the following units F, the following units 1 and the following units 2: units F: at least one type of units selected from the group consisting of units based on CF3—CH?CHF and units based on CF3—CF?CH2; units 1: at least one type of units selected from the group consisting of units having a carboxy group, units based on allyl alcohol and units based on a hydroxyalkyl allyl ether; units 2: at least one type of units selected from the group consisting of units based on a vinyl ether, units based on a vinyl ester, units based on an allyl ether (excluding a hydroxyalkyl allyl ether), units based on an allyl ester and units based on a (meth)acrylic acid ester.

Abstract: A powder coating material which has excellent blocking resistance and can form coating films excellent in water repellency is provided. The powder coating material of the present invention comprises a fluorinated polymer comprising from 20 to 80 mol % of units based on at least one species selected from the group consisting of CF3—CH?CHF and CF3—CF?CH2, from 18 to 60 mol % of units based on a monomer represented by the formula X1—Z1 (wherein X1 is a specific monovalent polymerizable group, and Z1 is a specific alkyl group, a specific cycloalkyl group or a specific aryl group) and units having a crosslinkable group.

Abstract: The object of the present invention is to provide a decorative film excellent in moldability and tensile strength; and a method for producing a three-dimensionally molded article with a decorative film. The decorative film of the present invention is used for decorating a three-dimensionally molded article. It is a decorative film comprising at least a substrate film layer and a clear layer, wherein the clear layer is made of a fluorinated polymer comprising units based on a fluoroolefin, units based on a monomer having no crosslinkable group, which is at least one member selected from the group consisting of a vinyl ether, a vinyl ester, an allyl ether, an allyl ester and a (meth)acrylic acid ester, and units having a crosslinkable group; and the content of the units based on a fluoroolefin is from 20 to 70 mol % to all units which the fluorinated polymer comprises.

Abstract: A powder coating material which has excellent blocking resistance and can form coating films excellent in water repellency is provided. The powder coating material of the present invention comprises a fluorinated polymer comprising from 20 to 80 mol % of units based on at least one species selected from the group consisting of CF3—CH?CHF and CF3—CF?CH2, from 18 to 60 mol % of units based on a monomer represented by the formula X1—Z1 (wherein X1 is a specific monovalent polymerizable group, and Z1 is a specific alkyl group, a specific cycloalkyl group or a specific aryl group) and units having a crosslinkable group.

Abstract: To provide a fluorinated coating material capable of forming a coating film excellent in water repellency and substrate adhesion. Further, to provide a method for producing the coating material, a coated article and its production method. A fluorinated coating material comprising a fluorinated polymer having the following units F, the following units 1 and the following units 2: units F: at least one type of units selected from the group consisting of units based on CF3—CH?CHF and units based on CF3—CF?CH2; units 1: at least one type of units selected from the group consisting of units having a carboxy group, units based on allyl alcohol and units based on a hydroxyalkyl allyl ether; units 2: at least one type of units selected from the group consisting of units based on a vinyl ether, units based on a vinyl ester, units based on an allyl ether (excluding a hydroxyalkyl allyl ether), units based on an allyl ester and units based on a (meth)acrylic acid ester.

Abstract: A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoroolefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.

Abstract: An aqueous coating composition which has a low content of an organic solvent, whereby a burden on an environment is small; in which an increase of the molecular weight, gelation, etc. are suppressed; which performs excellent storage stability and provides a coating film having good water permeability/water which composition is obtained by dispersing a fluorocopolymer (A) obtained by solution polymerization in an aqueous medium, and which comprises a repeating unit (1) of fluoroolefin, a repeating unit (2) of a vinyl or allyl monomer, a repeating unit (3) of a vinyl or allyl monomer having a hydroxyl group bonded thereto, and a unit (4) of a vinyl or allyl monomer having a carboxylate group bonded thereto, and which comprises a fluorocopolymer (A) wherein a proportion of the repeating unit (4) is from 0.4 mol % to less than 4 mol % based on the total repeating units, and an aqueous medium, wherein an amount of an organic solvent contained in the composition is from 0 to 1 mass %.

Abstract: A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer comprising from 40 to 60 mol % of a fluoro-olefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.

Abstract: To provide an aqueous coating composition which has a low content of an organic solvent, whereby a burden on an environment is small; in which an increase of the molecular weight, gelation, etc. are suppressed; which performs excellent storage stability and provides a coating film having good water permeability/water resistance. An aqueous coating composition which is a composition obtained by dispersing a fluorocopolymer (A) obtained by a solution polymerization method, in an aqueous medium, and which comprises a repeating unit (1) of fluoroolefin, a repeating unit (2) of a vinyl monomer or an allyl monomer, a repeating unit (3) of a vinyl monomer having a hydroxyl group bonded thereto or of an allyl monomer having a hydroxyl group bonded thereto, and a unit (4) of a vinyl monomer having a carboxylate group bonded thereto or of an allyl monomer, and which comprises a fluorocopolymer (A) wherein a proportion of the repeating unit (4) is from 0.

Abstract: A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoroolefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.

Abstract: To provide an aqueous coating composition which has a low content of an organic solvent, whereby a burden on an environment is small; in which an increase of the molecular weight, gelation, etc. are suppressed; which performs excellent storage stability and provides a coating film having good water permeability/water resistance. An aqueous coating composition which is a composition obtained by dispersing a fluorocopolymer (A) obtained by a solution polymerization method, in an aqueous medium, and which comprises a repeating unit (1) of fluoroolefin, a repeating unit (2) of a vinyl monomer or an allyl monomer, a repeating unit (3) of a vinyl monomer having a hydroxyl group bonded thereto or of an allyl monomer having a hydroxyl group bonded thereto, and a unit (4) of a vinyl monomer having a carboxylate group bonded thereto or of an allyl monomer, and which comprises a fluorocopolymer (A) wherein a proportion of the repeating unit (4) is from 0.

Abstract: A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoro-olefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.