Abstract: In a grain-oriented electrical steel sheet, comprising magnetic domains refined by a plurality of linear grooves in a surface of a steel sheet, each of the linear grooves is provided on its floor with a plurality of recessed parts aligned in a direction in which the linear groove extends, at a predetermined interval p (?m), and the recessed part is made to have a predetermined depth d (?m). In this way, it is possible to provide a grain-oriented electrical steel sheet having further improved iron loss properties while having reduced magnetic flux density reduction.

Abstract: Provided are coated metal, the metal having improved properties due to a novel coating, a coating-forming treatment solution for forming the novel coating, and a method for producing the coated metal that has the novel coating. The coated metal includes metal and a coating formed on the metal. The coating includes Si, P, and O, and at least one selected from the group consisting of Mg, Ca, Ba, Sr, Zn, Al, and Mn. The coating includes a compound having a Na Super Ionic Conductor-type (NASICON-type) crystal structure represented by a general formula MIMIV2(MVO4)3.

Abstract: Provided is an annealing separator with which a grain-oriented electrical steel sheet having a forsterite film with excellent appearance uniformity and adhesion can be obtained. The annealing separator for grain-oriented electrical steel sheet comprises: magnesia that contains 0.05 mass % or more and 0.20 mass % or less of B, a phosphate in 0.1 parts by mass or more and 1.0 part by mass or less in terms of P per 100 parts by mass of the magnesia, and titanium oxide in 1.0 part by mass or more and 10.0 parts by mass or less per 100 parts by mass of the magnesia where the titanium oxide contains one or more types of alkali metals in a total amount of 0.050 mass % or more and 1.0 mass % or less, where an amount of P adsorbed on per 1 g of the titanium oxide is 1.0×10?4 g or less.

Abstract: Provided is an annealing separator with which a grain-oriented electrical steel sheet having a forsterite film with excellent appearance uniformity and adhesion can be obtained. The annealing separator for grain-oriented electrical steel sheet comprises: magnesia that contains 0.05 mass % or more and 0.20 mass % or less of B and 0.01 mass % or more and 0.10 mass % or less of P, and titanium oxide in 1.0 part by mass or more and 10.0 parts by mass or less per 100 parts by mass of the magnesia where the titanium oxide contains one or more types of alkali metals in a total amount of 0.0050 mass % or more and 0.50 mass % or less, where an amount of P adsorbed on per 1 g of the titanium oxide is 1.5×10?4 g or more and 1.0×10?3 g or less.

Abstract: A treatment agent for chromium-free insulating coating formation suitable for forming an insulating coating on a surface of a grain-oriented electrical steel sheet. The treatment agent includes components (A), (B), (C), and (D). The component (B) is contained in an amount of 50 to 150 parts by mass on a SiO2 solid basis, and the component (C) is contained in an amount of 5.0 parts by mass or more on an elemental metal basis, the amounts being based on 100 parts by mass, on a solid basis, of the component (A). The component (D) is contained in an amount that a molar ratio of M2+ and M3+, each being a metal element in the treatment agent for chromium-free insulating coating formation, to a phosphorus element P satisfies a specified relationship, and the treatment agent for chromium-free insulating coating formation has a pH of less than 4.5.

Abstract: Provided is a method for nitriding a grain-oriented electrical steel sheet which is very useful in obtaining excellent magnetic properties with no variation, that enables generating glow discharge between positive electrodes and negative electrodes disposed in a nitriding zone and irradiating the generated plasma to a strip to perform appropriate nitriding.

Abstract: Provided are: a grain-oriented electrical steel sheet that has an excellent magnetic property and coating adhesiveness after stress relief annealing; and a production method therefor. This grain-oriented electrical steel sheet has: a steel sheet; a metal coating which contains a metal element and which is disposed on the steel sheet; a coating layer A which is a ceramic coating having an oxide content of less than 30 mass % and which is disposed on the metal coating; and a coating layer B which is an insulating tensile coating containing an oxide and which is disposed on the coating layer A, wherein the metal coating has a thickness of 1.0-10.0 nm, and in the metal element, the atomic radius ratio represented by formula (1) is at least 10%, when the atomic radius of iron is defined as RFe and the atomic radius of the metal element as RA. (|RFe?RA|/RFe)×100.

Abstract: An insulating coating treatment liquid for forming a chromium-free insulating coating on a surface of a grain-oriented electrical steel sheet, the insulating coating treatment liquid including at least one phosphate salt selected from phosphate salts of any of Mg, Ca, Ba, Sr, Zn, Al, and Mn and including colloidal silica and particles of a metal-element-containing compound. A content of the colloidal silica in terms of SiO2, on a solids basis, is 50 to 120 parts by mass, and a content of the particles of a metal-element-containing compound in terms of elemental metal is 5 to 60 parts by mass, per 100 parts by mass of the at least one phosphate salt, and the insulating coating treatment liquid has a thixotropic index (TI) of 1.00 or greater and 10.00 or less.

Abstract: A production method for a treatment solution for forming an insulating coating. The method includes mixing a solution A containing, on a PO43? basis, 0.20 mol/L or more and 10 mol/L or less of at least one of (i) phosphoric acid and (ii) a phosphate salt, and containing, on a metal basis, less than 0.50 mol/L of one or more particulate metal compounds, and a solution B containing, on a metal basis, 0.50 mol/L or more and 20.0 mol/L or less of the one or more particulate metal compounds, and containing, on a PO43? basis, less than 0.20 mol/L of at least one of (i) phosphoric acid and (ii) a phosphate salt, and stirring with a turbine stator-type high-speed stirrer such that a peripheral speed of a turbine reaches 10 m/s or more within 60 seconds after starting the mixing of the solution A and the solution B.

Abstract: Provided are: an oriented electromagnetic steel sheet with outstanding coating adhesion and magnetic properties after stress relief annealing; and a method for manufacturing the oriented electromagnetic steel sheet. The oriented electromagnetic steel sheet comprises: a steel sheet; a non-oxide ceramic coating disposed on the steel sheet and containing a non-oxide; and an insulating tensile coating disposed on the non-oxide ceramic coating and containing an oxide. The thickness of the non-oxide ceramic coating is 0.020-0.400 ?m. The thickness of the insulating tensile coating is at least 1.0 ?m. The chromium content on the steel plate side of the non-oxide ceramic coating is less than 25 atomic %, and the chromium content on the insulating tensile coating side of the non-oxide ceramic coating is at least 25 atomic %.

Abstract: An electrical steel sheet having an insulating coating is provided. The electrical steel sheet is capable of reducing dielectric loss in a transformer in a case where the electrical steel sheet is used in a transformer core. An electrical steel sheet having an insulating coating, the insulating coating being disposed on at least one of surfaces of the electrical steel sheet, the insulating coating having a relative dielectric constant at 1000 Hz of less than or equal to 15.0 and a dielectric loss tangent at 1000 Hz of less than or equal to 20.0.

Abstract: Provided are an insulation-coated oriented magnetic steel sheet having an insulating coat with excellent heat resistance; and a method for manufacturing the same. This insulation-coated oriented magnetic steel sheet has an oriented magnetic steel sheet, and an insulating coat arranged on the surface of the oriented magnetic steel sheet, the insulating coat containing Si, P, O, and Cr, and at least one element selected from the group consisting of Mg, Ca, Ba, Sr, Zn, Al, and Mn. The XPS spectrum of the outermost surface of the insulating coat has peaks observed at Cr2p1/2 and Cr2p3/2.

Abstract: Provided are: a grain-oriented electrical steel sheet that has excellent coating adhesiveness and an excellent magnetic property after stress relief annealing; and a production method for therefor. The grain-oriented electrical steel sheet has: a steel sheet; a coating layer A which is a ceramic coating having an oxide content of less than 30 mass % and which is disposed on the steel sheet; and a coating layer B which is an insulating tensile coating containing an oxide and which is disposed on the coating layer A. When a Gaussian fitting is performed on a 31P-NMR spectrum of the coating layer B within the range of 0 to ?60 ppm, the proportion of a peak area of ?17 to ?33 ppm to the total peak area is 30% or more.

Abstract: Provided are an insulating-coated oriented magnetic steel sheet having an insulating coating of excellent heat resistance, and a method for manufacturing the same. This insulating-coated oriented magnetic steel sheet has an oriented magnetic steel sheet, and an insulating coating arranged on the surface of the oriented magnetic steel sheet. The insulating coating contains Si, P, and O, and at least one element selected from the group consisting of Mg, Ca, Ba, Sr, Zn, Al, and Mn, the K-absorption edge of the P in the insulating coating having an XAFS spectrum that exhibits three absorption peaks from 2156 eV to 2180 eV.

Abstract: In the present invention, film forming performed under reduced pressure conditions on the surface of a grain-oriented electromagnetic steel sheet which is passed through the inside of a film forming chamber after finish-annealing. A plurality of stages of inlet-side reduced pressure chambers arranged on the inlet side of the film forming chamber have an internal pressure which becomes closer to the internal pressure of the film forming chamber as the inlet side reduced pressure chambers approach the film forming chamber. A plurality of stages of outlet-side reduced pressure chambers arranged on the outlet side of the film forming chamber save an internal pressure which becomes closer to atmospheric pressure as the outlet-side reduced pressure chambers are distanced from the film forming chamber.

Abstract: An insulating coating-attached electrical steel sheet has, on at least one surface, an insulating coating including an insulating tensile coating layer A. A tension applied to the steel sheet by an insulating tensile coating layer having a coating weight of M/2 from a surface of the insulating tensile coating layer A is 0.80×?A or more, where M is a weight of the insulating tensile coating layer A, and ?A is the tension applied to the steel sheet by the insulating tensile coating layer A. The insulating coating-attached electrical steel sheet has excellent adhesion of the insulating coating. A method for manufacturing the insulating coating-attached electrical steel sheet is also provided.

Abstract: A grain oriented electrical steel sheet comprising a grain oriented electrical steel sheet having a surface and a forsterite film formed on the surface of the steel sheet, wherein a total area percentage of defective parts scattered on the forsterite film is less than 1.5% relative to a surface area of the forsterite film when viewed from above the surface, and methods for evaluating a grain oriented electrical steel sheet comprising a grain oriented electrical steel sheet having a surface and a forsterite film formed on the surface of the steel sheet.

Abstract: Provided are: an oriented electrical steel sheet having a high tension applied to a steel sheet and excellent adhesion to a film; and a method for producing the same. This oriented electrical steel sheet includes: a steel sheet; a film A containing a crystalline material disposed on the steel sheet; and a film B containing a vitreous material disposed on the film A, wherein an element profile, which is obtained by using a high-frequency glow discharge light-emission surface analysis method, in the direction from the film B to the steel sheet satisfies formulae (1) and (2). 0.35?(tA/tFe/2)?0.75 . . . (1), 0.25?(tA/2/tFe/2)?1.00 . . . (2), where tA represents the peak time of an alkali metal element profile, tA/2 represents the half time of an alkali metal.

Abstract: A grain oriented electrical steel sheet comprising a grain oriented electrical steel sheet having a surface and a forsterite film formed on the surface of the steel sheet, wherein a total area percentage of defective parts scattered on the forsterite film is less than 1.5% relative to a surface area of the forsterite film when viewed from above the surface, and methods for evaluating a grain oriented electrical steel sheet comprising a grain oriented electrical steel sheet having a surface and a forsterite film formed on the surface of the steel sheet.

Abstract: A grain-oriented electromagnetic steel sheet exhibits excellent magnetic characteristics and excellent coating film adhesion after strain relieving annealing. The grain-oriented electromagnetic steel sheet includes: a steel sheet; a coating film layer A that is a ceramic coating film which is formed on the steel sheet and has an oxide content of less than 30% by mass; and a coating film layer B that is an insulating tension coating film which is arranged on the coating film layer A and contains an oxide. The binding energy of the 1s orbital of oxygen in the coating film layer B is higher than 530 eV; and tension applied to the steel sheet by the coating film layer B per a thickness of 1.0 ?m of the coating film layer B is 4.0 MPa/?m or more.