Abstract: A metal-supported catalyst, a battery electrode, and a battery. The metal-supported catalyst includes: a carbon carrier; and catalyst metal particles supported on the carbon carrier, wherein a ratio of number-average particle diameter of catalyst metal particles to average pore diameter of metal-supported catalyst is 0.70 or more and 1.30 or less, wherein, at relative pressure of a nitrogen adsorption isotherm of metal-supported catalyst within a range of 0.4 or more and 0.6 or less, maximum value of a ratio of a nitrogen adsorption amount of a desorption-side isotherm to a nitrogen adsorption amount of an adsorption-side isotherm is 1.05 or less, and wherein proportion of number of the catalyst metal particles each supported at a position having a depth of 20 nm or more from an outer surface of the carbon carrier to a total number of the catalyst metal particles supported on the carbon carrier is 11% or more.

Abstract: A metal-supported catalyst, a battery electrode, and a battery each having both excellent catalytic activity and durability. The metal-supported catalyst is a metal-supported catalyst including: a carbon carrier; and catalyst metal particles supported on the carbon carrier, wherein the metal-supported catalyst has a carbon structure that exhibits a half width at half maximum of 53.0 cm?1 or less of a D band having a peak top in a vicinity of 1,340 cm?1 in a Raman spectrum obtained by Raman spectroscopy, and wherein the metal-supported catalyst includes the catalyst metal particles that are partially buried in a pore inner surface of the carbon carrier.

Abstract: A cathode of a battery including an electrolyte membrane, containing a first layer which contains 0.3 mg/cm2 or more and 9.0 mg/cm2 or less of a carbon catalyst; and a second layer which is arranged between the electrolyte membrane and the first layer in the battery, and which contains 0.002 mg/cm2 or more and 0.190 mg/cm2 or less of platinum. The carbon catalyst has a ratio of a mesopore volume to a total pore volume of 30% or more.

Abstract: A metal-supported catalyst, a battery electrode, and a battery, each having both excellent catalytic activity and durability. The metal-supported catalyst includes: a carbon carrier; and platinum particles serving as catalyst metal particles supported on the carbon carrier, wherein the platinum particles contain pure platinum particles and platinum alloy particles, wherein a proportion of a weight of the pure platinum particles to a sum of the weight of the pure platinum particles and a weight of the platinum alloy particles is 15% or more and 61% or less, and wherein a ratio of a proportion of a nitrogen atom content to a carbon atom content measured by elemental analysis using a combustion method, to a proportion of a nitrogen atom content to a carbon atom content measured by X-ray photoelectron spectroscopy, is 1.05 or more.

Abstract: A carbon catalyst has a carbon structure with a crystallite size Lc falling within 0.90 nm or more and 1.20 nm or less calculated through use of a Bragg angle of a diffraction peak fbroad at a diffraction angle 2? of 24.0°±4.0° obtained by separating a diffraction peak in the vicinity of a diffraction angle 2? of 26° in an X-ray diffraction pattern obtained by powder X-ray diffraction using a CuK? ray, and a carbon dioxide desorption amount from 650° C. to 1,200° C. of 97 ?mol/g or less, a total of a carbon monoxide desorption amount and a carbon dioxide desorption amount from 650° C. to 1,200° C. of 647 ?mol/g or less, or a carbon monoxide desorption amount from 650° C. to 1,200° C. of 549 ?mol/g or less in a temperature programmed desorption method including measuring a carbon dioxide desorption amount from 25° C. to 1,200° C.

Abstract: A cathode of a battery including an electrolyte membrane, containing a first layer which contains 0.3 mg/cm2 or more and 9.0 mg/cm2 or less of a carbon catalyst; and a second layer which is arranged between the electrolyte membrane and the first layer in the battery, and which contains 0.002 mg/cm2 or more and 0.190 mg/cm2 or less of platinum. The carbon catalyst has a ratio of a mesopore volume to a total pore volume of 30% or more.

Abstract: A metal-supported catalyst, battery electrode, and battery, each having excellent catalytic activity and durability. The metal-supported catalyst includes: a carbon carrier; and catalyst metal particles supported thereon, wherein, in a photoelectron spectrum obtained by X-ray photoelectron spectroscopy, the catalyst exhibits, as a peak derived from a is orbital of a nitrogen atom, a peak to be separated into peaks of first to sixth nitrogen atoms having peak tops in the following respective ranges: (1) 398.6±0.2 eV; (2) 399.5±0.3 eV; (3) 400.5±0.2 eV; (4) 401.3±0.3 eV; (5) 403.4±0.4 eV; and (6) 404.5±0.5 eV, wherein a ratio of a peak area of the second nitrogen atoms to a total peak area of the nitrogen atoms of the (1) to (6) is 0.03 or more, and wherein a ratio of a concentration of the second nitrogen atoms to a concentration of carbon atoms measured by the X-ray photoelectron spectroscopy is 0.0005 or more.

Abstract: A metal-supported catalyst, a battery electrode, and a battery, each having both excellent catalytic activity and durability. The metal-supported catalyst includes: a carbon carrier; and catalyst metal particles each containing a noble metal supported on the carbon carrier, wherein a volume of first pores each having a diameter of 0.5 nm or more and 2.0 nm or less per unit weight of the carbon carrier is 0.20 (cm3/g-carrier) or more, wherein a volume of second pores each having a diameter of more than 2.0 nm and 4.0 nm or less per unit weight of the carbon carrier is 0.20 (cm3/g-carrier) or more, and wherein a ratio of a content (wt %) of the noble metal measured by X-ray photoelectron spectroscopy, to a content (wt %) of the noble metal measured by inductively coupled plasma mass spectrometry, is 0.35 or more and 0.75 or less.

Abstract: Provided are a carbon catalyst, an electrode, and a battery that exhibit excellent activity. A carbon catalyst according to one embodiment of the present invention has a carbon structure in which area ratios of three peaks fbroad, fmiddle, and fnarrow obtained by separating a peak in the vicinity of a diffraction angle of 26° in an X-ray diffraction pattern obtained by powder X-ray diffraction satisfy the following conditions (a) to (c): (a) fbroad: 75% or more and 96% or less; (b) fmiddle: 3.2% or more and 15% or less; and (c) fnarrow: 0.4% or more and 15% or less.

Abstract: A cathode, a membrane electrode assembly, and a battery, each has excellent durability. The cathode is a cathode of a battery including an electrolyte membrane, the cathode including: a first layer which contains 0.3 mg/cm2 or more and 9.0 mg/cm2 or less of a carbon catalyst; and a second layer which is arranged between the electrolyte membrane and the first layer in the battery, and which contains 0.002 mg/cm2 or more and 0.190 mg/cm2 or less of platinum.

Abstract: A carbon catalyst has a carbon structure with a crystallite size Lc falling within 0.90 nm or more and 1.20 nm or less calculated through use of a Bragg angle of a diffraction peak fbroad at a diffraction angle 2? of 24.0°±4.0° obtained by separating a diffraction peak in the vicinity of a diffraction angle 2? of 26° in an X-ray diffraction pattern obtained by powder X-ray diffraction using a CuK? ray, and a carbon dioxide desorption amount from 650° C. to 1,200° C. of 97 ?mol/g or less, a total of a carbon monoxide desorption amount and a carbon dioxide desorption amount from 650° C. to 1,200° C. of 647 ?mol/g or less, or a carbon monoxide desorption amount from 650° C. to 1,200° C. of 549 ?mol/g or less in a temperature programmed desorption method including measuring a carbon dioxide desorption amount from 25° C. to 1,200° C.

Abstract: A carbon catalyst has: a carbon structure that exhibits a nitrogen desorption temperature range from 800° C.-1,000° C. of 0.75×10?5 mol/g or more or a nitrogen desorption amount in the range from 600° C. to 1,000° C. of 1.20×10?5 mol/g or more in a temperature programmed desorption method including measuring nitrogen desorption amount temperature range from 600° C.-1,000° C.; a carbon structure exhibits a zeta potential isoelectric point of pH 9.2 or more; or a carbon structure exhibits a ratio of an intensity of a first nitrogen peak within a range of a binding energy of 398.0±1.0 eV, to an intensity of a second nitrogen peak having a peak top within a range of a binding energy of 400.5±1.0 eV, of 0.620 or more, the first and second nitrogen peaks obtained by separating a peak derived from a 1s orbital of a nitrogen atom in a photoelectron spectrum obtained by X-ray photoelectron spectroscopy.

Abstract: A battery cathode, a composition for a catalyst layer of a battery cathode, and a battery, each achieves excellent performance while using a non-platinum catalyst. The battery cathode includes a catalyst layer, wherein the catalyst layer contains a non-platinum catalyst, has a thickness of 15 ?m or more, and has a conductance per 1 cm2 of an electrode area of more than 100 S and less than 350 S.

Abstract: A carbon catalyst, a battery electrode, and a battery each having excellent catalytic activity and excellent durability. The carbon catalyst includes iron, exhibits a weight reduction ratio in the temperature range from 200° C. to 1,200° C. of 12.0 wt % or less measured by thermogravimetric analysis in a nitrogen atmosphere, and has a carbon structure that exhibits, in X-ray absorption fine structure analysis of a K absorption edge of the iron, the following (a) and/or (b): (a) a ratio of a normalized absorbance at 7,130 eV to a normalized absorbance at 7,110 eV is 7.0 or more; and (b) a ratio of a normalized absorbance at 7,135 eV to a normalized absorbance at 7,110 eV is 7.0 or more.

Abstract: A cathode, a membrane electrode assembly, and a battery, each has excellent durability. The cathode is a cathode of a battery including an electrolyte membrane, the cathode including: a first layer which contains 0.3 mg/cm2 or more and 9.0 mg/cm2 or less of a carbon catalyst; and a second layer which is arranged between the electrolyte membrane and the first layer in the battery, and which contains 0.002 mg/cm2 or more and 0.190 mg/cm2 or less of platinum.

Abstract: A battery electrode, a composition for a catalyst layer of a battery electrode, and a battery having excellent characteristics at low cost. The battery electrode includes a catalyst layer containing a non-platinum catalyst and platinum particles not being carried on the non-platinum catalyst, wherein a content of the platinum particles per unit area of the battery electrode is 0.0010 mg/cm2 or more and 0.1200 mg/cm2 or less.

Abstract: A method for improving the performance and/or stability of non-precious metal catalysts in fuel cells and other electrochemical devices. Improved membrane electrode assemblies (MEAs) and fuel cells containing the same are provided. Such MEAs include a catalyst layer made up of at least two sub-layers containing ionomers of differing equivalent weights. The sub-layers may optionally contain mixtures of ionomers. Also provided are methods of making and using the described devices.

Abstract: An electrode for redox flow batteries is produced using a carbon catalyst for redox flow battery electrodes, wherein a ratio of the number of oxygen atoms to the number of carbon atoms (O/C ratio) is 0.05 to 0.20 as measured by surface analysis using X-ray photoelectron spectroscopy.

Abstract: An electrode for redox flow batteries is produced using a carbon catalyst for redox flow battery electrodes, the carbon catalyst being a particulate carbon catalyst and consisting of carbonaceous particles having a specific surface area of 800 to 2000 m2/g and an average particle size of 100 to 1000 nm.

Abstract: A carbon catalyst, a battery electrode, and a battery each having excellent catalytic activity and excellent durability. The carbon catalyst includes iron, exhibits a weight reduction ratio in the temperature range from 200° C. to 1,200° C. of 12.0 wt % or less measured by thermogravimetric analysis in a nitrogen atmosphere, and has a carbon structure that exhibits, in X-ray absorption fine structure analysis of a K absorption edge of the iron, the following (a) and/or (b): (a) a ratio of a normalized absorbance at 7,130 eV to a normalized absorbance at 7,110 eV is 7.0 or more; and (b) a ratio of a normalized absorbance at 7,135 eV to a normalized absorbance at 7,110 eV is 7.0 or more.