Abstract: Embodiments herein relate to a method of making roll formed objects of a bulk solidifying amorphous alloy comprising a metal alloy, and articles thereof. The roll forming includes forming a portion of the bulk solidifying amorphous alloy at a temperature greater than a glass transition temperature (Tg) of the metal alloy. The roll forming is done such that a time-temperature profile of the portion during the roll forming does not traverse through a region bounding a crystalline region of the metal alloy in a time-temperature-transformation (TTT) diagram of the metal alloy.

Abstract: Described herein is a method of producing an alloy. The method includes pouring a stream of molten mixture of component elements of the alloy, separating the stream into discrete pieces, solidifying the discrete pieces by cooling before the discrete pieces contact any liquid or solid. Also described herein is another method of producing an alloy. This method includes pouring and solidifying a stream of molten mixture of component elements of the alloy into a rod or pulling a rod from a molten mixture of component elements of the alloy, before the rod contacts any liquid or solid, separating the rod into discrete pieces. An apparatus suitable for carrying out the methods above can include a container from which the molten stream is poured or the solid rod extends, one or more coil, conductive plates, a laser source, or an electron beam source arranged around the molten stream or the solid rod and configured to separate the molten stream or the solid rod into discrete pieces.

Abstract: Disclosed are systems and methods for mechanically reducing an amount of the skull material in a finished, molded part formed from amorphous alloy using an injection molding system. Skull material of molten amorphous alloy can be captured in a trap before molding such material. A cavity can be provided in the injection molding system to trap the skull material. For example, the cavity can be provided in the mold, the tip of the plunger rod, or in the transfer sleeve. Alternatively, mixing of molten amorphous alloy can be induced so that skull material is reduced before molding. A plunger and/or its tip can be used to induce mixing (e.g., systematic movement of plunger rod, or a shape of its tip). By minimizing the amount of skull material in the finished, molded part, the quality of the part is increased.

Abstract: Described herein are methods of constructing a three-dimensional part using metallic glass alloys, layer by layer, as well as metallic glass-forming materials designed for use therewith. In certain embodiments, a layer of metallic glass-forming powder or a sheet of metallic glass material is deposited to selected positions and then fused to a layer below by suitable methods such as laser heating or electron beam heating. The deposition and fusing are then repeated as need to construct the part, layer by layer. One or more sections or layers of non-metallic glass material can be included as needed to form composite parts. In one embodiment, the metallic glass-forming powder is a homogenous atomized powder.

Abstract: An induction shield is configured to substantially reduce emissions emitted from an induction heat source (e.g., coil) during use. The shield is positioned adjacent to a vessel (e.g., in an injection system) having a melting portion configured to receive meltable material to be melted therein and an induction heat source positioned adjacent the vessel configured to melt the meltable material received in the melting portion of the vessel. The shield may include a tube configuration configured to flow liquid therein to absorb heat emitted from the heat source. The tube configuration can comprise a single tube or multiple tubes. The shield can be positioned adjacent the induction source in a helical manner, for example, or at ends of the vessel. The shield can be used during melting of amorphous alloy and for forming a part.

Abstract: A housing for a portable electronic device is disclosed. The housing is composed of yttria-sensitized zirconia. Yttria-sensitized zirconia has from about 1.5 to about 2.5 mole percent yttria, and more typically about 2 mole percent yttria, and most typically 2 mole percent yttria, in zirconia. Yttria-sensitized zirconia is both tough and able to limit the formation and propagation of micro-cracks. Methods for manufacturing yttria-sensitized zirconia composed housings are also disclosed.

Abstract: Methods of forming a bulk metallic glass disclosed. The methods include packing a metallic glass-forming alloy powder to form a green body; heating the green body to a temperature between the glass transition temperature and the melting point of the metallic glass-forming alloy to form a heated green body; and cooling the heated green body to a temperature below the glass transition temperature of the metallic glass-forming alloy to form the bulk metallic glass. The methods of forming a bulk metallic glass also include packing one or more layers of an amorphous foil to form a green body; heating the green body to a temperature between the glass transition temperature and the melting point of the metallic glass-forming alloy to form a heated green body; and cooling the heated green body to a temperature below the glass transition temperature of the metallic glass-forming alloy to form the bulk metallic glass.

Abstract: Pressure sensing systems comprising bulk-solidifying amorphous alloys and pressure-sensitive switches containing bulk-solidifying amorphous alloys. The bulk-solidifying amorphous alloys are capable of repeated deformation upon application of pressure, and change their electrical resistivity upon deformation, thereby enabling measurement of the change in resistivity and consequently, measuring the deformation and amount of pressure applied.

Abstract: A method of manufacturing a housing of an electronic device includes applying a mask to a portion of a ceramic green body to define a masked portion and an unmasked portion, applying a pigment to the ceramic green body to color the unmasked portion, and sintering the ceramic green body to remove the mask and form a ceramic housing. The ceramic housing may comprise a first portion corresponding to the masked portion and having a first color, and a second portion corresponding to the unmasked portion and having a second color different from the first color.

Abstract: The disclosure provides nickel free Zr—Cu—Al metallic glass-forming alloys and metallic glasses comprising at least of Pt, Pd, and Co where the atomic fraction of Zr ranges from 50 to 70, the atomic fraction of Cu ranges from 15 to 45, the atomic fraction of Al ranges from 5 to 15, and the combined atomic fraction of Pt, Pd, and Co ranges from 1 to 10.

Abstract: A method of manufacturing a housing of an electronic device includes determining a sintering profile configured to produce a selected color at a selected depth within a wall of the housing, sintering a ceramic housing precursor in accordance with the determined sintering profile, thereby forming the housing, and removing material from the housing up to the selected depth.

Abstract: One embodiment provides a composition, the composition comprising: an alloy that is at least partially amorphous and is represented by a chemical formula: (Zr, Ti)aMbNcSnd, wherein: M is at least one transition metal element; N is Al, Be, or both; a, b, c, and d each independently represents an atomic percentage; and a is from about 30 to 70, b is from about 25 to 60, c is from about 5 to 30, and d is from about 0.1 to 5.

Abstract: A metallic glass part is provided. The metallic glass part includes an alloy core and a metallic glass shell surrounding the alloy core. The alloy core provides compressive force on the metallic glass shell at an interface between the alloy core and the metallic glass shell.

Abstract: Various embodiments provide apparatus and methods for melting materials and for containing the molten materials within melt zone during melting. Exemplary apparatus may include a vessel configured to receive a material for melting therein; a load induction coil positioned adjacent to the vessel to melt the material therein; and a containment induction coil positioned in line with the load induction coil. The material in the vessel can be heated by operating the load induction coil at a first RF frequency to form a molten material. The containment induction coil can be operated at a second RF frequency to contain the molten material within the load induction coil. Once the desired temperature is achieved and maintained for the molten material, operation of the containment induction coil can be stopped and the molten material can be ejected from the vessel into a mold through an ejection path.

Abstract: In some embodiments, processes for testing for structural flaws in sapphire parts such as display cover plates used in the manufacturing of electronic devices are disclosed. A process may include transmitting a destructive acoustic signal onto a sapphire part, and determining whether the sapphire part failed in response to the destructive signal. The destructive acoustic signal may include a Rayleigh acoustic wave, wherein the destructive acoustic signal breaks the sapphire part if the sapphire part has a surface flaw larger than a specified size. In this manner, only sapphire parts that can withstand the destructive acoustic signal are used in manufacturing of the electronic device.

Abstract: Exemplary embodiments described herein relate to methods and apparatus for forming a coating layer at least partially on surface of a BMG article formed of bulk solidifying amorphous alloys. In embodiments, the coating layer may be formed in situ during formation of a BMG article and/or post formation of a BMG article. The coating layer may provide the BMG article with surface hardness, wear resistance, surface activity, corrosion resistance, etc.

Abstract: Various embodiments provide methods and apparatus for forming bulk metallic glass (BMG) articles using a mold having a stationary mold part and a movable mold part paired to form a mold cavity. A molten material can be injected to fill the mold cavity. The molten material can then be cooled into a BMG article at a desired cooling rate. While injecting and/or cooling the molten material, the movement of the movable mold part can be controlled, such that a thermal contact between the molten material and the mold can be maintained. BMG articles can be formed without forming an underfilled part. Additional structural features can be imparted in the BMG article during formation. At least a portion of the formed BMG article can have an aspect ratio (first dimension/second dimension) of at least 10 or less than 0.1.

Abstract: Disclosed is an apparatus comprising at least one gate and a vessel, the gate being configured to move between a first position to restrict entry into an ejection path of the vessel and contain a material in a meltable form within the vessel during melting of the material, and a second position to allow movement of the material in a molten form through the ejection path. The gate can move linearly or rotate between its first and second positions, for example. The apparatus is configured to melt the material and the at least one gate is configured to allow the apparatus to be maintained under vacuum during the melting of the material. Melting can be performed using an induction source. The apparatus may also include a mold configured to receive molten material and for molding a molded part, such as a bulk amorphous alloy part.

Abstract: Methods of altering the surface of a metallic glass are provided. The methods include blasting and oxidation of a metallic glass surface, blasting a metallic glass surface using multiple shot media sizes, and thermal spray blasting a metallic glass surface with controlled cooling.

Abstract: The disclosure is directed to methods of forming glassy alloys. A glassy alloy is cold rolled at a temperature less than Tg of the glassy alloy to form a flattened glassy alloy. Then, the cold rolled glassy alloy is thermoplastically formed at a temperature above Tg of the glassy alloy. In certain embodiments, the flattened glassy alloy may have one or more shear bands and/or micro-cracks, and the thermoplastic forming may heal the shear bands and/or micro-cracks. The resulting glassy alloy may thereby have reduced or eliminated shear bands and/or micro-cracks.